• Title/Summary/Keyword: Solid surface

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A Study on the Combustion Characteristic in Hybrid Rocket Motor using PE/$LN_2O$ (PE/$LN_2O$ 하이브리드 로켓 모터의 연소특성에 관한 연구)

  • Kim, Gi-Hun;Lee, Jung-Pyo;Kim, Soo-Jong;Cho, Jung-Tae;Kim, Hak-Chul;Woo, Kyoung-Jin;Sung, Hong-Gye;Moon, Hee-Jang;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.233-236
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    • 2009
  • In this study, the characteristic of the hybrid rocket motor with $LN_2O$(Liquid Nitrous oxide) was investigated experimentally. HDPE(High Density PolyEthlene) was used as fuel with different sized single port. When used $LN_2O$, combustion efficiency is lower than using $GN_2O$(Gas Nitrous oxide), because of completeness of vaporization of droplet and mixing. And regression rate was changed by different oxidizer phase. This behavior was considered that flame temperature and combustion of solid fuel front/end surface.

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Cu Through-Via Formation using Open Via-hole Filling with Electrodeposition (열린 비아 Hole의 전기도금 Filling을 이용한 Cu 관통비아 형성공정)

  • Kim, Jae-Hwan;Park, Dae-Woong;Kim, Min-Young;Oh, Tae Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.117-123
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    • 2014
  • Cu through-vias, which can be used as thermal vias or vertical interconnects, were formed using bottom-up electrodeposition filling as well as top-down electrodeposition filling into open via-holes and their microstructures were observed. Solid Cu through-vias without voids could be successfully formed by bottom-up filling as well as top-down filling with direct-current electrodeposition. While chemical-mechanical polishing (CMP) to remove the overplated Cu layer was needed on both top and bottom surfaces of the specimen processed by top-down filling method, the bottomup process has an advantage that such CMP was necessary only on the top surface of the sample.

Performance Evaluation of a Time-domain Gauss-Newton Full-waveform Inversion Method (시간영역 Gauss-Newton 전체파형 역해석 기법의 성능평가)

  • Kang, Jun Won;Pakravan, Alireza
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.4
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    • pp.223-231
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    • 2013
  • This paper presents a time-domain Gauss-Newton full-waveform inversion method for the material profile reconstruction in heterogeneous semi-infinite solid media. To implement the inverse problem in a finite computational domain, perfectly-matchedlayers( PMLs) are introduced as wave-absorbing boundaries within which the domain's wave velocity profile is to be reconstructed. The inverse problem is formulated in a partial-differential-equations(PDE)-constrained optimization framework, where a least-squares misfit between measured and calculated surface responses is minimized under the constraint of PML-endowed wave equations. A Gauss-Newton-Krylov optimization algorithm is utilized to iteratively update the unknown wave velocity profile with the aid of a specialized regularization scheme. Through a series of one-dimensional examples, the solution of the Gauss-Newton inversion was close enough to the target profile, and showed superior convergence behavior with reduced wall-clock time of implementation compared to a conventional inversion using Fletcher-Reeves optimization algorithm.

Occurrence of butyltin compounds in marine environment of Gwangyang Bay, Korea

  • Park, Hee-Gu;Kim, Sang-Soo;Moon, Hyo-Bang;Gu, Bon-Kyu
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.793-800
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    • 2002
  • Butyltin (BT) compounds were measured in seawater, sediment, sediment core, settling solids, and plankton from Gwangyang Bay in 2001, Tributyltin (TBT) was detected in seawater from 1 out of the 7 seawater sampling sites and in sediment from 18 out of the 35 sediment sampling sites. The highest concentration of TBT was found in the sediment from the site near Yeosu Harbor (53 ng Sn/g dry wt), acting as the point source for TBT The mean concentrations of TBT were in the order of plankton> settling solids> sediment. The degradation indexes ([DBT]+[MBT]/[TBT]) for the plankton were less than 1, indicating the possibility of recent inputs of TBT. The indexes for the sediment and settling solids ranged from 1.14 to 8.73. The composition of the BT compounds found in the settling solids was similar to that found in the sediment. The vertical profile of the total BT compounds in the sediment was characterized by an abrupt decline from the surface. However, no butyltin compounds appeared below a depth of 10 cm, corresponding to the 1980s. Accordingly, the current results demonstrated that the levels of all butyltin species in the environment of Gwangyang Bay were relatively lower than those in other polluted coastal areas. The vertical profile also suggested a fairly recent history for the down-core.

The biological effects of fibrin-binding synthetic oligopeptides derived from fibronectin on osteoblast-like cells

  • Kim, Yun-Jeong;Park, Yoon-Jeong;Lee, Yong-Moo;Rhyu, In-Chul;Ku, Young
    • Journal of Periodontal and Implant Science
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    • v.42 no.4
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    • pp.113-118
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    • 2012
  • Purpose: The aim of this study was to investigate the effects of synthetic fibronectin (FN) fragments, including fibrin binding sites from amino-terminal FN fragments containing type I repeats 1 to 5, on osteoblast-like cell activity. Methods: Oligopeptides ranging from 9 to 20 amino acids, designated FF1, FF3, and FF5, were synthesized by a solid-phase peptide synthesizing system, and we investigated the effects of these peptides on cell attachment and extent of mineralization using confocal microscopy, 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide assays, and Alizarin red S staining. Results: FF3 and FF5 peptides increased the number of attached human osteoblastic cells, and FF3 administration led to prominent cell spreading. Mineralization was increased in FF3 and FF5 compared to FF1 and the untreated control. Conclusions: Taken together, it can be concluded that the fibrin-binding oligopeptides FF3 and FF5 enhanced cell attachment and mineralization on osteoblast-like cells. These results indicate that FF3 and FF5 have the potential to increase osteoblast-like cell activity. Performing an in vivo study may provide further possibilities for surface modification of biomimetic peptides to enhance osteogenesis, thus improving the regeneration of destroyed alveolar bone.

Fluoride single crystals for UV/VUV nonlinear optical applications

  • Shimamura Kiyoshi;Villora Encarnacion G.;Muramatsu Kenichi;Kitamura Kenji;Ichinose Noboru
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.4
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    • pp.133-140
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    • 2006
  • The growth characteristics and properties of large size $SrAlF_5$ single crystals are described and compared with those of $BaMgF_4$. Transmission spectra in the vacuum ultraviolet wavelength region indicate a high transparency of $SrAlF_5$ (about 90% without considering surface reflection loses) down to 150 nm, on contrast to the optical loses observed for $BaMgF_4$. The ferroelectric character of $SrAlF_5$ is evidenced by the reversal of the spontaneous polarization in a hysteresis loop. The higher potential of $SrAlF_5$ in comparison with $BaMgF_4$ for the realization of all-solid-state lasers in the ultraviolet wavelength region by the quasi-phase matching (QPM) technique is pointed out. $SrAlF_5$, besides a higher grade of transparency, shows a nonlinear effective coefficient similar to that of quartz and uniaxial nature, on contrast to the one order smaller nonlinear coefficient and biaxial character of $BaMgF_4$. The refractive index of $SrAlF_5$ from the ultraviolet to the near-infrared wavelength region is measured by the minimum deviation method. The Sellmeier and Cauchy coefficients are obtained from the fits to the curves of the ordinary and extraordinary refractive indices, and the grating period for the first order QPM is estimated as a function of the wavelength. The poling periodicity for 193 nm SHG from 386 nm is $4{\mu}m$.

Effects of Cobalt Protective Coating Prepared by DC Electroplating on Ferritic Stainless Steel for SOFC Interconnect (직류 전기도금을 이용한 고체산화물 연료전지 금속연결재용 페라이트계 스테인리스 스틸의 코발트 보호막 코팅 효과)

  • Hong, Jong-Eun;Lim, Tak-Hyung;Song, Rak-Hyun;Lee, Seung-Bok;Shin, Dong-Ryul;Yoo, Young-Sung;Lee, Dok-Yol
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.2
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    • pp.116-124
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    • 2009
  • We investigated the influences of cobalt coating deposited by DC electroplating on the ferritic stainless steel, STS 430, as a protective layer on a metallic interconnect for SOFC applications. Cobalt coated STS 430 revealed a uniform and denser-packing oxide surface and a reduced growth rate of $Cr_2O_3$ scales after oxidation at $800^{\circ}C$in air. Cobalt coating layer was oxidized to $CoCo_2O_4$ and Co containing mixed oxide spinels such as $Co_2CrO_4$, $CoCr_2O_4$, and $CoCrFeO_4$. The area specific resistance value of Co coated sample was $0.020\;{\Omega}cm^2$ lower than that of uncoated at $800^{\circ}C$ in air during 500 h. After 1000 h oxidation, cobalt oxide coating layer suppressed chromium outward diffusion.

A Synthesis of Mullite and Cordierite Ceramics by Solution-Polymerzation Route Based on PVA (PVA를 이용한 Solution-Polymerzation 합성법에 의한 Mullite, Cordierite 세라믹스의 합성)

  • 이용석;이병하
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.151-157
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    • 2004
  • Because of the excellent thermal and chemical properties of mullite and cordierite as the stable oxide ceramic materials, they were widely used from engineering materials to electronic materials. Notwithstanding of their high demands, mullite was synthesised because it is not existed in nature. It is also difficult to produce cordierite of fine powder with high purity due to the narrow range of synthetic temperature. Mullite was synthesised by solid state reaction. However, synthesized mullite has been inhomogeneous. Because of the facts, various synthetic methods have been studied so far including sol-gel method. The purpose of this study is to synthesis mullite and cordierite of fine powder with high purity at the lower temperature by solution-polymerization route using PVA as a polymer carrier, which is an economical method by using low cost materials. As a result, mullite and cordierite were produced with mono crystal phase at 1200$^{\circ}C$ and 1250$^{\circ}C$, respectively, and their surface area over 20 ㎡/g.

Protective Coatings for Application of Fe-l6Cr Ferritic Alloy as an Interconnector in SOFCs (고체산화물 연료전지용 금속접속자로의 적용을 위한 Fe-16Cr 페라이트 합금의 내산화막 코팅)

  • 이용진;김상우;김긍호;이종호;안진호
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.139-145
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    • 2003
  • We studied oxidation behaviors of anti-oxidative Y-Cr oxide coated sol on ferritic steel for application of the Fe-Cr alloys as interconnectors of planar-type Solid Oxide Fuel Cells(SOFCs). In coated$YCrO_3$on the ferritic steel, the phases of $YCrO_3$,$Cr_2O_3$and $Mn_{1.5}Cr_{1.5}O_4$on the coated surface were detected, but iron base scales were not observed after oxidation at 80$0^{\circ}C$ for 40 h. The Mn-Cr oxide scales were grown with oxidation by diffusing components in the ferritic steel from inner. The Log(ASR/T) value that expresses electrical resistance of coated$YCrO_3$on the ferritic steel was -4.57~$-4.70{omega}cm^2K^{-1}$, lower in comparison with the one of the uncoated ferritic steel,$-3.99{omega}cm^2K^{-1}$. This indicates the applicability of Fe-l6Cr alloy as interconnector materials for SOFCs.

Characteristics on EL Properties and Phase Transformation Caused by Artificial Defects on the ZnS:Cu Blue Phosphor for ACPEL (ACPEL용 ZnS:Cu 청색 형광체의 인위적 결함 형성에 따른 결정 상 변화 및 EL 특성)

  • 이명진;전애경;이지영;윤기현
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.406-409
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    • 2004
  • A blue phosphor(ZnS:Cu) is manufactured by solid state reaction for ACPEL(AC powder EL). The effect of artificial defect on phosphor surface on the ZnO phase conversion and resulting luminescence have been studied. It was found that ZnS:Cu could converse to cubic phase more easily due to the formation of artificial defect on 1st fired phosphor by ball-milling process, resulting in improvement of luminescence of phosphor phosphors under the driven EL condition. We found out an optimized ball-mill condition through considering effect of each ball-mill conditions such as milling time and milling rpm on defect. Also we determined relationship between emission luminescence and phase of phosphor based on analyses of crystal structures of phosphors. A significant improvement above 30% was observed in electroluminescence by the artificial defect on ZnS:Cu phosphors compared to non-treated phosphors.