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Effects of Polymerization and Spinning Conditions on Mechanical Properties of PAN Precursor Fibers

  • Qin, Qi-Feng;Dai, Yong-Qiang;Yi, Kai;Zhang, Li;Ryu, Seung-Kon;Jin, Ri-Guang
    • Carbon letters
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    • v.11 no.3
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    • pp.176-183
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    • 2010
  • PAN precursor fibers were produced via wet-spinning process, and effects of polymerization and spinning processes, especially the stretching process, were investigated on mechanical properties and micro-morphologies of precursor fibers. An increase in molecular weight, dope solid and densification and a decrease in surface defects were possible by controlling polymerization temperature, the number of heating rollers for densification and the jet stretch ratio, which improved the mechanical properties of precursor fibers. The curves for strength, modulus, tensile power and diameter as a function of stretch ratio can be divided into three stages: steady change area, little change area and sudden change area. With the increase of stretch ratio, the fiber diameter became smaller, the degree of crystallization increased and the structure of precursor fibers became compact and homogeneous, which resulted in the increase of strength, modulus and tensile power of precursor fibers. Empirical relationship between fiber strength and stretch ratio was studied by using the sub-cluster statistical theory. It was successfully predicted when the strengths were 0.8 GPa and 1.0 GPa under a certain technical condition, the corresponding stretch ratio of the fiber were 11.16 and 12.83 respectively.

Phase sequence in Codeposition and Solid State Reaction of Co-Si System and Low Temperature Epitaxial Growth of $CoSi_2$ Layer (Co-Si계의 동시증착과 고상반응시 상전이 및 $CoSi_2$ 층의 저온정합성장)

  • 박상욱;심재엽;지응준;최정동;곽준섭;백홍구
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.439-454
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    • 1993
  • The phase sequence of codeposited Co-Si alloy and Co/si multilayer thin film was investigated by differential scanning calormetry(DSC) and X-ray diffraction (XRD) analysis, The phase sequence in codeposition and codeposited amorphous Co-Si alloy thin film were CoSilongrightarrow Co2Si and those in Co/Si multilayer thin film were CoSilongrightarrowCo2Silongrightarrow and CoSilongrightarrowCo2Si longrightarrowCoSilongrightarrowCoSi2 with the atomic concentration ration of Co to Si layer being 2:1 and 1:2 respectively. The observed phase sequence was analyzed by the effectvie heat of formatin . The phase determining factor (PDF) considering structural facotr in addition to the effectvie heat of formation was used to explain the difference in the first crystalline phase between codeposition, codeposited amorphous Co-Si alloy thin film and Co/Si multilayer thin film. The crystallinity of Co-silicide deposited by multitarget bias cosputter deposition (MBCD) wasinvestigated as a funcion of deposition temperature and substrate bias voltage by transmission electron microscopy (TEM) and epitaxial CoSi2 layer was grown at $200^{\circ}C$ . Parameters, Ear, $\alpha$(As), were calculate dto quantitatively explain the low temperature epitaxial grpwth of CoSi2 layer. The phase sequence and crystallinity had a stronger dependence on the substrate bias voltage than on the deposition temperature due to the collisional daxcade mixing, in-situ cleannin g, and increase in the number of nucleation sites by ion bombardment of growing surface.

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Analysis of Sinkhole Formation over Abandoned Mine using Active-Passive-Active Finite Elements (폐광지역에서의 싱크홀 발생 규명을 위한 Active-Passive-Active 유한요소 기법 연구)

  • Deb Debasis;Shin Hee-Soon;Choi Sung O.
    • Tunnel and Underground Space
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    • v.14 no.6 s.53
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    • pp.411-422
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    • 2004
  • Sinkhole subsidence occurs over abandoned mine workings and can be detrimental to human lives, damage to properties and other surface structures. In this study, simulation of sinkhole development process is performed using special finite element procedure. Especially, creation of mine voids due to roof falls and generation of goaf from broken rocks are simulated using active-passive-active finite elements. An active or solid element can be made passive or void once the tensile failure criterion is satisfied in the specified sinkhole formation zone. Upon completion of sinkhole development process, these passive elements in again be made active to simulate goal region. Several finite element models are analyzed to evaluate the relationships between sinkhole formation with width of gallery. depth of mine, roof condition and bulking factor of roof rocks. This study demonstrates that the concept of passive elements in numerical analysis can be used effectively for analyzing sinkhole formation or roof fall phenomenon in general.

Effects of laminated structure and fiber coating on tensile strength of radiation shielding sheet (방사선 차폐시트의 적층 구조와 섬유 코팅의 융합적인 현상이 인장강도에 미치는 영향)

  • Kim, Seon-Chil
    • Journal of the Korea Convergence Society
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    • v.11 no.6
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    • pp.83-88
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    • 2020
  • Recently, radiation shielding sheets made of eco-friendly materials have been widely used in medical institutions. The shielding sheet is processed into a solid form by thermoforming by mixing a shielding material with a polymer material. The base is resin-based and has a limit in tensile strength, and for this purpose, fibers such as non-woven fabrics are used on the surface. The shielding sheet process technology has a problem in that the tensile strength rapidly decreases when the content of the shielding material is increased to increase the shielding performance. In order to improve this, this study intends to compare and evaluate the method of laminating and coating the fibers in the sheet process. In comparison of the three types of sheets, there was no difference in shielding performance between the fiber-coated sheet and the compression sheet, but there was a large difference in tensile strength.

Dewatering and Settling Characteristics of Digested Sludge from the Anaerobic Sequencing Batch Reactor for Treatment of Nightsoil (혐기성 연속회분식 공정을 이용한 분뇨처리시 소화슬러지의 침강 및 탈수특성)

  • Lee, Jun-Geol;Jang, Duk;Heo, Jun-Mu;Son, Boo-Soon;Jang, Bong-Ki;Park, Jong-An
    • Journal of Environmental Science International
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    • v.7 no.6
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    • pp.867-873
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    • 1998
  • Laboratory study was conducted to provide basic data for operating anaerobic sequencing batch reactor(ASBR) process for treatment of nightsoil. The experiments were concerned with digestion characteristics, settleabiltity and dewaterability of digested sludge in ASBR system. Completely-mixed dally-fed control reactor without solid-liquid separation step was also operated to evaluate the baseline performance since the nature of nightsoil was changed with time. In all case, gas production from the ASBR shows 1.3 to 1.44 times higher than that from control, in spite of almost similar trend in organics removal. During thickening period, remarkable decrease in surface settling velocity was observed at the ASBRs compared with the control. In case of the ASBR run, flotation of mixed digested sludge was not occurred. Also, ultimate thickened volume of ASBRs increased 1.2~1.5 times compared with control. Dewaterability of digested sludge without conditioning decreased when the completely-mixed daily-fed reactor for ASBR run was converted to the ASBR. However, improvement of dewaterability of digested sludge from the ASBRs was observed as a result of addition of FeCl$_3$ to digested sludge for conditioning.

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A Theoretical Study on the Colloid-facilitated Radionuclide Transport with Decay Chain in the Fractured Rock (균열암반에서 방사성 붕괴사슬과 콜로이드를 동반한 방사성 핵종의 이동에 관한 이론적 연구)

  • 박진백;황용수;강철형
    • Tunnel and Underground Space
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    • v.13 no.1
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    • pp.20-32
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    • 2003
  • To understand the behavior of migration of contaminants in a fractured porous medium is a key to assure the overall safety of a potential radwaste repository. The feasible retention mechanism of contaminant transport in a tinctured medium are sorption of contaminants on solid surface and matrix diffusion of contaminants from a fracture into an adjacent porous medium. The acceleration mechanisms are the migration of contaminants in the form of pseudo-colloids and the limit of a volume f3r matrix diffusion. In this paper, the effects of these two acceleration mechanisms are studied mathematically, then semi-analytically computed by the application of the Talbot theorem and verified. Results indicate that the acceleration processes cannot be neglected in the modeling of contaminant transport in a fractured porous medium.

A Study on the Vibration Isolation Effect of Wave Barrier in Frozen Soils (동결지반 내 방진벽의 차진성능에 관한 연구)

  • Heo, Yeong
    • Tunnel and Underground Space
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    • v.11 no.4
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    • pp.362-367
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    • 2001
  • The stiff top layer in a soil profile, which can happen in winter, may change the isolation effect of the wave barrier. The research scope of this paper is the investigation of the propagation of surface waves in layered soil with a stiff layer on its top, and the isolation effect of the solid stiff wave barrier. The investigations have been performed numerically by the Boundary-Element Method as a two-dimensional problem. A strip foundation vibrated harmonically in vertical direction was considered as the vibration source. Three soil profiles, a homogeneous half-space, two profiles with different thickness of stiff top layer, with two different types of wave barriers were investigated. The profiles with a stiff top layer show considerable reductions of the amplitude of the vibration in comparison to the homogeneous soil profile. The layered soil profiles with a stiff top layer do not show wave propagation velocities as high as they are expected from the material properties. Furthermore the vibration amplitudes in a frozen soil are much smaller with distance than in a non-frozen soil.

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Compatibility of the Recycled Linerboard Made in Acid Sizing System under Neutral or Alkaline Papermaking Conditions (산성 사이징된 재활용 섬유와 중성 사이징의 상용성)

  • Seo, Man Seok;Lee, Kyong Ho;Lee, Hak Lae
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.56-60
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    • 2016
  • Neutral or alkaline papermaking provides many advantages in paper strength and processing conditions. It also provides the opportunity of using calcium carbonate fillers in papermaking. These diverse advantages have made almost all paper machines of printing and writing papers run under neutral and alkaline conditions. On the other hand, linerboard machines, which use recycled papers as a raw material, are running under acid conditions using a rosin sizing system. Because the recycled raw materials used by the linerboard industry contain significant amounts of alkaline papers, the linerboard industry has an interest in the possibility of using the neutral or alkaline papermaking opportunity. In this study, the compatibility of the recycled linerboards under neutral or alkaline papermaking conditions was examined by recycling them under various pH conditions. The sizing degree of the papers recycled under neutral or alkaline was significantly lower than that of acid formed papers indicating that during the neutral or alkaline recycling process the rosin sized papers lost their sizing efficiency. Recycling of acid formed linerboards under neutral or alkaline conditions increased the amount of foam, and the foam contained substantial amount of solid materials derived from the acid sizing systems. Use of cationic polyelectrolytes including PEI and poly-DADMAC improved the sizing degree of the recycled papers under neutral and alkaline conditions. PEI decreased the foam generation as well while poly-DADMAC did not show any reducing effect of the foam. These results suggest that PEI forms coordinate bonds with rosin acid and precipitate them onto the surface of recycled fibers, while the reaction products between poly-DADMAC and rosin acid ions still remain water soluble under neutral or alkaline conditions.

Transport of Colloids and Contaminant in Riverbank Filtration (강변여과에서 콜로이드 물질과 오염물의 거동에 관한 연구)

  • Lee Sang-Il;Kim Dae-Hwan;Lee Sang-Sin;You Sang-Yeon
    • Journal of Korea Water Resources Association
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    • v.39 no.6 s.167
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    • pp.511-520
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    • 2006
  • Riverbank filtration is a natural process, using alluvial aquifers to remove contaminants and pathogens in river water for the production of drinking water. In Korea, most of the drinking water is supplied by surface water in-take. However, maintaining the quality of the drinking water becomes more and more difficult due to the increase of contamination. In riverbank filtration, the understanding of contaminant transport is an important task for the production of high quality drinking water and for the maintenance of facilities. In this paper, the transport behavior of hydrophobic organic contaminants is investigated when contaminants coexist with dissolved organic matter (DOM) and bacteria. In the developed model, the aquifer is thought of as a four phase system: two mobile colloidal phases, an aqueous phase, and a stationary solid matrix phase. The model equations are solved numerically for various situations. Results indicate that the presence of colloidal matters can enhance the mobility of contaminant significantly and that partitioning coefficients play an important role in the process.

Metallic Structure of Iron Relics of Chosun Dynasty Excavated from Gangsun Tower, Chengpyeong Temple (청평사 강선루 출토 조선시대 철제유물의 금속조직에 대하여)

  • Kim, S. K.;Lee, C. H.
    • Journal of Conservation Science
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    • v.17 s.17
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    • pp.57-64
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    • 2005
  • In the course of examining the micro structure of Iron chisel and Iron arrowhead, a relics of the 16th or 17th of Chosun Dynasty unearthed at near Gangsun-tower, Chengpyeong temple. Collected un-eroded samples from the relics were looked into the metallic structure through optical metallography. Non-metallic inclusions were-analysed by SEM and EDS. The micro structure examination and SEM-SDS analysis revealed that Iron chisel and Iron arrowhead had been produced from the sponge iron close to pure iron made by low temperature reducing in a solid and then the surface carbon content was increased by carburizing treatment. It was also found that Iron chisel had been hardened through the repetitive processes of quench hardening and heat treatment, after increasing carbon content to a certain level. Up to now, there have been a number of studies in the domestic academia which were studied mainly on the structure of metallic relics in the period of the Three Kingdoms or before. Although this research was limited in type and number of the relics, it turned out to be interesting in that it revealed the 16th or 17th century way of processing iron, even in fragments. It is thought to be fruitful that iron had been made even in the Chosun Dynasty from the sponge iron.

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