• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2011년도 춘계학술발표대회
• /
• pp.241.1-241.1
• /
• 2011

Numerous possible applications for $ZrO_2$ nanotubes exist such as for catalyst support structures, for sensing or for applications as a solid state electrolyte. Especially, because of a large specific surface area, high efficiency for solid oxide fuel cell (SOFC) application at low temperature can be expected for nanotublar structures in even small size. A zirconium precursor, Tetrakis (ethylmethylamino) zirconium, TEMAZr and $H_2O$ oxidant were used to deposit$ZrO_2$ thin films on an anodized aluminum oxide (AAO) templates having sub-100nm cylindrical pores by atomic layer deposition (ALD) in the temperature range of 150~250$^{\circ}C$. The crystalline structures of as-prepared and post-annealed $ZrO_2$ nanotubes were characterized by x-ray diffraction and high-resolution transmission electron microscopy. The as-prepared samples at $150^{\circ}C$ and $200^{\circ}C$ were showed amorphous, whereas a mixed phase of tetragonal, monoclinic and amorphous polymorph was observed at $250^{\circ}C$. In the bulk, zirconia remains monoclinic phase up to $1,175^{\circ}C$, however, $ZrO_2$ nanotubes were showed tetragonal phase upon post thermal treatments merely at $400^{\circ}C$. This trend may be indicative of high-curvature surfaces of nanotubes and thereby the presence of intrinsic compressive strain. The amount of amorphous structures in the mixed phase as well as as-grown $ZrO_2$ nanotubes were also gradually decreased by subsequent heat treatment.

• 한국환경과학회지
• /
• 제16권12호
• /
• pp.1431-1437
• /
• 2007

Cobalt titanates($CoTiO_x$), such as $CoTiO_3$ and $Co_2TiO_4$, have been synthesized via a solid-state reaction and characterized using X-ray diffraction(XRD) and X-ray photoelectron spectroscopic(XPS) measurement techniques, prior to being used for continuous wet trichloroethylene(TCE) oxidation at $36^{\circ}C$, to support our earlier chemical structure model for Co species in 5 wt% $CoO_x/TiO_2$(fresh) and(spent) catalysts. Each XRD pattern for the synthesized $CoTiO_3$ and $Co_2TiO_4$ was very close to those obtained from the respective standard XRD data files. The two $CoTiO_x$ samples gave Co 2p XPS spectra consisting of very strong main peaks for Co $2p_{3/2}$ and $2p_{1/2}$ with corresponding satellite structures at higher binding energies. The Co $2p_{3/2}$ main structure appeared at 781.3 eV for the $CoTiO_3$, and it was indicated at 781.1 eV with the $Co_2TiO_4$. Not only could these binding energy values be very similar to that exhibited for the 5 wt% $CoO_x/TiO_2$(fresh), but the spin-orbit splitting(${\Delta}E$) had also no noticeable difference between the cobalt titanates and a sample of the fresh catalyst. Neither of all the $CoTiO_x$ samples were active for the wet TCE oxidation, as expected, but a sample of pure $Co_3O_4$ had a good activity for this reaction. The earlier proposed model for the surface $CoO_x$ species existing with the fresh and spent catalysts is very consistent with the XPS characterization and activity measurements for the cobalt titanates.

• 항공우주기술
• /
• 제3권2호
• /
• pp.56-64
• /
• 2004

본 연구에서는 소형위성발사체의 고체모터 가동노즐용 추력벡터제어 구동장치를 제어하기 위한 컴퓨터 하드웨어 설계에 관한 내용을 기술하였다. 구동장치 제어 컴퓨터는 관성항법장치로부터 제어명령을 받아 작동기를 구동하는 장치로, 발사체 내외의 다른 장비들과 통신을 하는 기능도 갖추고 있다. 구동장치 제어 컴퓨터는 고속의 제어 알고리즘 연산에 적합하도록 디지털 시그널 프로세서를 주 프로세서로 채택하여 KSR-III의 아나로그 제어기와 비교할 때 안정성과 신뢰성, 유연성을 더 갖추도록 설계하였다. 설계된 제어 컴퓨터는 여기 프로그램 개발용 타겟 보드 제작을 거쳐 1차 시제품으로 개발되었다. 여기에서는 최상위단계의 설계 요구조건과 하드웨어 구성, 지상지원장비에 대해서도 기술하였다.

• Steel and Composite Structures
• /
• 제24권5호
• /
• pp.549-559
• /
• 2017

As few multi-tower single-box multi-cell cable-stayed bridges with corrugated steel webs have been built, analysis is mostly achieved by combining single-girder model, beam grillage model and solid model in support of the design. However, such analysis methods usually suffer from major limitations in terms of the engineering applications: single-girder model fails to account for spatial effect such as shear lag effect of the box girder and the relevant effective girder width and eccentric load coefficient; owing to the approximation in the principle equivalence, the plane grillage model cannot accurately capture shear stress distribution and local stress state in both top and bottom flange of composite box girder; and solid model is difficult to be practically combined with the overall calculation. The usual effective width method fails to provide a uniform and accurate "effective length" (and the codes fail to provide a unified design approach at those circumstance) considering different shear lag effects resulting from dead load, prestress and cable tension in the construction. Therefore, a novel spatial grid model has been developed to account for shear lag effect. The theoretical principle of the proposed spatial grid model has been elaborated along with the relevant illustrations of modeling parameters of composite box girder with corrugated steel webs. Then typical transverse and longitudinal shear lag coefficient distribution pattern at the side-span and mid-span key cross sections have been analyzed and summarized to provide reference for similar bridges. The effectiveness and accuracy of spatial grid analysis methods has been finally validated through a practical cable-stayed bridge.

• 한국세라믹학회지
• /
• 제42권12호
• /
• pp.827-832
• /
• 2005

In this study, thin electrolyte layer was prepared by 8YSZ ($8mol\%$ Yttria-Stabilized Zirconia) slurry dip and sol coating onto the porous anode support in order to reduce ohmic resistance. 8YSZ polymeric sol was prepared from inorganic salt of nitrate and XRF results of xerogel powder exhibited similar results $(99.2\pm1wt\%)$ compared with standard sample (TZ-8YS, Tosoh Co.). The dense and thin YSZ film with $1{\mu}m$ thickness was synthesized by coating of 0.7M YSZ sol followed by heat-treatment at $600^{\circ}C$ for 1 h. Thin film electrolyte sintered at $1400^{\circ}C$ showed no gas leakage at the differential pressure condition of 3 atm.

• Bulletin of the Korean Chemical Society
• /
• 제28권8호
• /
• pp.1265-1272
• /
• 2007

A solid acid catalyst, NiSO4/CeO2-ZrO2 was prepared simply by promoting ZrO2 with CeO2 and supporting nickel sulfate on CeO2-ZrO2. The support of NiSO4 on ZrO2 shifted the phase transition of ZrO2 from amorphous to tetragonal to higher temperatures because of the interaction between NiSO4 and ZrO2. The surface area of 10-NiSO4/1-CeO2-ZrO2 promoted with CeO2 and calcined at 600 oC was very high (83 m2/g) compared to that of unpromoted 10-NiSO4/ZrO2 (45 m2/g). This high surface area of 10-NiSO4/1-CeO2-ZrO2 was due to the promoting effect of CeO2 which makes zirconia a stable tetragonal phase as confirmed by XRD. The role of CeO2 was to form a thermally stable solid solution with zirconia and consequently to give high surface area and acidity of the sample, and high thermal stability of the surface sulfate species. 10-NiSO4/1- CeO2-ZrO2 containing 1 mol% CeO2 and 10 wt% NiSO4, and calcined at 600 oC exhibited maximum catalytic activities for both reactions, 2-propanol dehydration and cumene dealkylation.

• The Journal of Advanced Prosthodontics
• /
• 제12권2호
• /
• pp.67-74
• /
• 2020

PURPOSE. This study evaluated the influence of prosthesis weight and number of implants on the bone tissue microstrain. MATERIALS AND METHODS. Fifteen (15) fixed full-arch implant-supported prosthesis designs were created using a modeling software with different numbers of implants (4, 6, or 8) and prosthesis weights (10, 15, 20, 40, or 60 g). Each solid was imported to the computer aided engineering software and tetrahedral elements formed the mesh. The material properties were assigned to each solid with isotropic and homogeneous behavior. The friction coefficient was set as 0.3 between all the metallic interfaces, 0.65 for the cortical bone-implant interface, and 0.77 for the cancellous bone-implant interface. The standard earth gravity was defined along the Z-axis and the bone was fixed. The resulting equivalent strain was assumed as failure criteria. RESULTS. The prosthesis weight was related to the bone strain. The more implants installed, the less the amount of strain generated in the bone. The most critical situation was the use of a 60 g prosthesis supported by 4 implants with the largest calculated magnitude of 39.9 mm/mm, thereby suggesting that there was no group able to induce bone remodeling simply due to the prosthesis weight. CONCLUSION. Heavier prostheses under the effect of gravity force are related to more strain being generated around the implants. Installing more implants to support the prosthesis enables attenuating the effects observed in the bone. The simulated prostheses were not able to generate harmful values of peri-implant bone strain.

• 디지털융복합연구
• /
• 제13권1호
• /
• pp.495-502
• /
• 2015

청소년들의 건강한 자아정체성 형성을 목적으로 하는 "(가제) SAVE ME, LOVE ME" 라는 심리 기능성게임 시나리오의 주제는 조건 없는 사랑(무조건적인 사랑)을 자원으로 딜레마들을 해결하는 과정에 의한 내부적 승인 획득이다. 1인칭 시점 액션게임으로 청소년의 일상적인 삶의 딜레마를 다루는 이 게임의 특징은 청소년들이 받는 여러 심리적 스트레스를 치료하기 위해 종교 지혜 내러티브 중 기독교 예수의 '돌아온 탕자' 비유의 모티브를 사용한 것이다. 게임의 기획 의도는 다양한 스테이지 별로 청소년들의 건강한 자아정체성을 해치는 위협요인들의 상징을 배치, 여러 캐릭터가 제공하는 이야기들이나 몬스터를 파괴하는 등의 액션을 통해 긍정적인 자아상 확립을 돕는 것이다. 게임의 장르는 모바일 게임을, 게임 형식으로는 다양한 형식의 인터랙션이 가능한 액션 게임을 채택하였다.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
• /
• pp.131-136
• /
• 2017

고체 로켓추진기관을 이용한 자연공동형 수중운동체를 수중주행 시험하였다. 수중운동체의 속도 및 주행거리를 측정하고, 수중운동체 표면에 압력센서를 설치하여 초공동이 발달됨에 따라 표면 압력이 어떻게 변화하는지를 조사하였으며, 수중카메라를 설치하여 시험시 수중운동체에 초공동이 발생하여 진행하는 과정을 기록하였으며, 이를 이차원 비점성 이론해석법에 근거한 CNU-SuperCT 프로그램을 사용하여 계산한 시뮬레이션 결과와 비교하였다. CNU-SuperCT 프로그램은 수중운동체의 조종면을 포함하지 않고 계산한 것을 고려하면, 시뮬레이션 결과와 측정결과가 잘 맞는다고 판단되며, 수중촬영결과도 이와 동일한 결과를 보인다.

• 한국식품영양과학회지
• /
• 제26권1호
• /
• pp.81-86
• /
• 1997

대추를 이용한 가공제품의 하나로서 분무건조에 의한 분말음료의 개발을 시도하였다. 대추 추출액은 그 자체로는 모든 농도 범위에서 분무건조 하기가 불가능하였고 건조보조제의 첨가에 의해서 분말음료로의 제조가공이 가능하였다 대추 추출액은 26。Bx 농도까지 농축시키고 알맞은 건조보조제를 첨가하여 최종농도를 30。Bx로 조정하여 분무 건조시켰다 첨가되는 건조보조제의 양은 대추 추출액과 건조보조제의 비율이고 형물 기준으로 1:1정도까지 흔합했을때 건조가 용이하고 얻어지는 제품의 품질이 양호하였다. maltose, 농축유, gum arabic, dextrin등의 건조보조제를 검토한 결과 maltose와 gum arabic을 흔합하여 사용할 때 제품의 관능적 특성이 가장 우수하였다. 대추 추출시의 효소처리는 수율을 13~39% 향상시 킬 수 있었다. 그렇지만 효소처리가 분말대추음료의 관능적인 특성에 부정적인 영향을 나타내었으며 추출수율 향상을 위해 사용되어진다면 품질열화가 적은 pectinase의 0.5% 처리가 가장 바람직한 것으로 나타났다.