• Korean Journal of Veterinary Service
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• v.27 no.1
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• pp.17-29
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• 2004

A multiresidual analysis was performed to determine 12 sulfonamides(sulfacetamide, sulfadiazine, sulfisomidine, sulfathiazole, sulfapyridine, sulfamerazine, sulfamethazine, sulfamonomethoxine, sulfisoxazole, sulfamethoxazole, sulfaquinoxaline, and sulfadimethoxine) in beef and pork simultaneously. The multiresidual analysis for the sulfonamides currently used was able to analyze 5 kinds of sulfonamides at the same time. The method of this 12 sulfonamides multiresidual analysis in this study was matrix solid-phase dispersion(MSPD) by high performance liquid chromatography (HPLC) and liquid chromatography mass spectrometry (LC/MS). The recovery rate of the materials was measured by MSPD method with 3 different extraction solvents; Dichloromethane, DCM: Ethylacetate(3:1), DCM:EA(9:1). Also, samples (84 beef and 205 pork samples) which were positive by EEC-4 plate test from 2001 to 2003 were tested to investigate the kinds of sulfonamides using HPLC. The results from the study were as follows; 1. The recovery rate of the materials was measured by MSPD method with 3 different extraction solvents; Dichloromethane, DCM:Ethylacetate(3:1), DCM:EA(9:1). The method of extraction solvent with DCM:ethyl acetate(9:1) was the most excellent(87.7∼99.3%) in separation and reappearance. 2. In the LC/MS analysis. of sulfonamides, signal to noise ratio was showed relatively high in the positive mode and special ion in the quality analysis was determined via [M+H]$\^$+/ and m/z 156. A spectrum of sulfonamides was showed from all 12 sulfonamides. 3. The samples positive by the EEC-4 plate, a screening test method, were categorized by sulfonamides through Charm II and confirmed the kinds of sulfonamides through HPLC. 1) Among 84 beef samples positive by EEC-4 plate, 20 samples were positive by Charm II and identified as 7 sulfamethazine, 9 sulfadimethoxine, 1 sulfamonomethoxine and 3 unknown status. 2) Among 205 pork samples positive by EEC-4 plate, 42 samples were positive by Charm II and identified as 19 sulfamethazine, 1 sulfadimethoxine, 4 sulfamonomethoxine and 5 unknown status.

• Nuclear Engineering and Technology
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• v.52 no.7
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• pp.1517-1523
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• 2020

The widely used medical isotope technetium-99 m (^99mTc) is a daughter of Molybdenum-99 (⁹⁹Mo), which is mainly produced using dedicated research reactors from the nuclear fission of uranium-235 (²³⁵U). ^99mTc has been used for several decades, which covers about 80% of the all the nuclear diagnostics procedures. Recently, the instability of the supply has become an important topic throughout the international radioisotope communities. The aging of major ⁹⁹Mo production reactors has also caused frequent shutdowns. It has triggered movements to establish new research reactors for ⁹⁹Mo production, as well as the development of various ⁹⁹Mo production technologies. In this context, a new research reactor project was launched in 2012 in Korea. At the same time, the development of fission-based ⁹⁹Mo production process was initiated by Korea Atomic Energy Research Institute (KAERI) in 2012 in order to be implemented by the new research reactor. The KAERI process is based on the caustic dissolution of plate-type LEU (low enriched uranium) dispersion targets, followed by the separation and purification using a series of columns. The development of proper waste treatment technologies for the gaseous, liquid, and solid radioactive wastes also took place. The first stage of this process development was completed in 2018. In this paper, the results of the hot test production of fission ⁹⁹Mo using HANARO, KAERI's 30 MW research reactor, was described.

• Journal of the Korea Institute of Military Science and Technology
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• v.1 no.1
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• pp.227-237
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• 1998

HgCdTe Is the most versatile material for the developing infrared devices. Not like III-V compound semiconductors or silicon-based photo-detecting materials, HgCdTe has unique characteristics such as adjustable bandgap, very high electron mobility, and large difference between electron and hole mobilities. Many research groups have been interested in this material since early 70's, but mainly due to its thermodynamic difficulties for preparing materials, no single growth technique is appreciated as a standard growth technique in this research field. Solid state recrystallization(SSR), travelling heater method(THM), and Bridgman growth are major techniques used to grow bulk HgCdTe material. Materials with high quality and purity can be grown using these bulk growth techniques, however, due to the large separation between solidus and liquidus line on the phase diagram, it is very difficult to grow large materials with minimun defects. Various epitaxial growth techniques were adopted to get large area HgCdTe and among them liquid phase epitaxy(LPE), metal organic chemical vapor deposition(MOCVD), and molecular beam epitaxy(MBE) are most frequently used techniques. There are also various types of photo-detectors utilizing HgCdTe materials, and photovoltaic and photoconductive devices are most interested types of detectors up to these days. For the larger may detectors, photovoltaic devices have some advantages over power-requiring photoconductive devices. In this paper we reported the main results on the HgCdTe growing and characterization including LPE and MOCVD, device fabrication and its characteristics such as single element and linear array($8{\times}1$ PC, $128{\times}1$ PV and 4120{\times}1$ PC). Also we included the results of the dewar manufacturing, assembling, and optical and environmental test of the detectors.

• Advances in concrete construction
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• v.9 no.5
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• pp.511-527
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• 2020

The main aim of the current research is to investigate the flexural behavior of the reinforced concrete (RC) slabs strengthened with strain hardening cementitious composites (SHCC) experimentally and numerically. Seven RC slabs were prepared and tested under four-points loading test. One un-strengthened slab considered as control specimen while six RC slabs were strengthened with reinforced SHCC layers. The SHCC layers had different reinforcement ratios and different thicknesses. The results showed that the proposed strengthening techniques significantly increased the ultimate failure load and the ductility index up to 25% and 22%, respectively, compared to the control RC slab. Moreover, a three dimensional (3D) finite element model was proposed to analyze the strengthened RC slabs. It was found that the results of the proposed numerical model well agreed with the experimental responses. The validated numerical model used to study many parameters of the SHCC layer such as the reinforcement ratios and the different thicknesses. In addition, steel connectors were suggested to adjoin the concrete/SHCC interface to enhance the flexural performance of the strengthened RC slabs. It was noticed that using the SHCC layer with thickness over 40 mm changed the failure mode from the concrete cover separation to the SHCC layer debonding. Also, the steel connectors prevented the debonding failure pattern and enhanced both the ultimate failure load and the ductility index. Furthermore, a theoretical equation was proposed to predict the ultimate load of the tested RC slabs. The theoretical and experimental ultimate loads are seen to be in fairly good agreement.

• Korean Journal of Environmental Agriculture
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• v.39 no.2
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• pp.142-169
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• 2020

BACKGROUND: A new analytical method has been developed to determine 261 pesticide residues in herbal medicines. METHODS AND RESULTS: The extraction of pesticides was carried out by modified method of the Korea Food Standards Codex sample extraction and determination was performed using GC-MS/MS and LC-MS/MS. During the pre-treatment process of the test method, Solid-liquid separation was changed to centrifugation. The method was validated by the precision and accuracy results. 261 pesticides spiked at three level 20, 50, 100 ug/kg in herbal medicines. The limit of quantification of method were 4-40 ug/kg for GC-MS/MS and 2-45 ug/kg for LC-MS/MS, respectively. Among the pesticides analysed by GC-MS/MS and LC-MS/MS, 244 pesticides (94% of total number) in chinese matrimony vine and 224 pesticides (86% of total number) in korean angelica root and 231 pesticides (89% of total number) in jujube and 214 (82% of total number) in cnidium showed recoveries in the range of 70-120% with RSD⪯20%. CONCLUSION: These results indicated that GC-MS/MS and LC-MS/MS analysis with the sample extraction in this study can be applied to multi-residue analysis of pesticides in herbal medicines.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.591-591
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• 2016

최근에는 재이용을 위한 하 폐수의 처리 공정에 막을 이용한 기술적용이 증가되고 있는 추세이다(현 등, 2005). 막(membrane)을 이용한 수처리 공정은 원수에 상관없이 고도처리가 가능하며, 재이용수 이용 용도에 따른 수질제어가 가능할 뿐만 아니라 운용의 편리성 때문에 많은 각광을 받고 있다(박 등, 2004). 본 연구에서는 하수처리에 이용되는 분리막의 성능을 극대화하고, 분리막의 오염부하를 줄여주기 위하여 분리막 직전 전처리 시설로 부상방식의 고액분리장치를 개발하였다. 초고속 고액분리시스템은 기존의 응집부상공정을 응용한 기술로서 유기물의 응집시간을 최대 10초~2분 이내로 줄이는 기술을 바탕으로 타워형 모듈 형태로 개발하였다. 초고속 고액분리시스템과 분리막을 연계한 재이용수 수처리시스템의 성능 평가 및 현장적용을 위해 제주도 서부 하수 처리장에 일 $3,000m^3$ 규모의 Test-bed를 구축하였다. 구축된 하수재이용시스템의 처리 공정도는 "유입${\rightarrow}$고액분리시스템${\rightarrow}$분리막(UF, RO)${\rightarrow}$농경지 공급"으로 구성되어 있다. 먼저 하수처리장 방류수를 1차 유입조에 압송하면 전처리시설인 고액분리시스템을 통해 SS 등 입자성 물질이 처리되고, 다음 공정인 2차 처리공정(UF/RO)을 통과한 처리수는 인근지역의 농업용수로 공급되고 있다. 고액분리시스템은 ZT(Zeta Potential Tower) 모듈에서 유입수에 함유되어 있는 부유물질(SS), 유기물(질소, 인)을 응집제와 순간 반응시켜 응결, 응집, 부상방식으로 제거하는 공정이다. 고속 고액분리장치는 분리막 공정과 융 복합하여 다양한 유입수 성상에 따른 수처리를 가능하게 하여 재이용수 수질 향상뿐만 아니라 안정된 수자원 확보 측면에서 긍정적인 기술로 평가되었다.

• Journal of Environmental Impact Assessment
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• v.29 no.3
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• pp.157-181
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• 2020

Sediments from rivers, lakes and marine ports serve as end points for pollutants discharged into the water, and at the same time serve as sources of pollutants that are continuously released into the water. Until now, the contaminated sediments have been landfilled or dumped at sea. Landfilling, however, was expensive and dumping at sea was completely banned due to the London Convention. Therefore, this study applied contaminated sedimentation soil of 'Royal Palace Livestock Complex' as soil purification method. Soil remediation methods were applied to pretreatment, composting, soil washing, electrokinetics, and thermal desorption by selecting overseas application cases and domestically applicable application technologies. As a result of surveying the site for pollutant characteristics, Disolved Oxigen (DO), Suspended Solid (SS), Chemical Oxygen Demand (COD), Total Nitrogen (TN), and Total Phosphorus (TP) exceeded the discharged water quality standard, and especially SS, COD, TN, and TP exceeded the standard several tens to several hundred times. Soil showed high concentrations of copper and zinc, which promote the growth of pig feed, and cadmium exceeded 1 standard of Soil Environment Conservation Act. In the pretreatment technology, hydrocyclone was used for particle size separation, and the fine soil was separated by more than 80%. Composting was performed on organic and Total Petroleum Hydrocarbon (TPH) contaminated soils. TPH was treated within the standard of concern, and E. coli was analyzed to be high in organic matter, and the fertilizer specification was satisfied by applying the optimum composting conditions at 70℃, but the organic matter content was lower than the fertilizer specification. As a result of continuous washing test, Cd has 5 levels of residual material in fine soil. Cu and Zn were mostly composed of ion exchange properties (stage 1), carbonates (stage 2), and iron / manganese oxides (stage 3), which facilitate easy separation of contamination. As a result of applying acid dissolution and multi-stage washing step by step, hydrochloric acid, 1.0M, 1: 3, 200rpm, 60min was analyzed as the optimal washing factor. Most of the contaminated sediments were found to satisfy the Soil Environmental Conservation Act's standards. Therefore, as a result of the applicability test of this study, soil with high heavy metal contamination was used as aggregate by applying soil cleaning after pre-treatment. It was possible to verify that it was efficient to use organic and oil-contaminated soil as compost Maturity after exterminating contaminants and E. coli by applying composting.

• Analytical Science and Technology
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• v.35 no.6
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• pp.256-266
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• 2022

It is important to determine the concentration of long-lived radionuclides (e.g., ¹²⁹I) in nuclear waste to ensure safety when handling it. To analyze nuclides in a solid sample (e.g., concrete and soil), it is essential to effectively separate and purify the nuclides of interest in the sample. This study reports the comprehensive efforts made to validate the analytical procedure for ¹²⁹I detection in solid samples, using a high-temperature combustion furnace. ¹²⁹I volatilized from the sample collected in 0.01 M HNO₃ solution with a reducing agent (e.g., NaHSO₃) and was rapidly measured by ICP-MS. Analytical conditions, such as pyrolysis temperature and types of mobile phase gas, catalyst, and trapping solution, were optimized to obtain a high recovery rate of spiked ¹²⁹I. Finally, the optimized method was applied for the simultaneous analysis of other volatile radionuclides, such as ³H and ¹⁴C. The performance test results for the optimized method confirmed that the LSC (for ³H and ¹⁴C) and ICP-MS (for ¹²⁹I) measurements, with the separation of volatile nuclides using a high-temperature combustion furnace, were reliable.

• Analytical Science and Technology
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• v.21 no.5
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• pp.412-423
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• 2008

A procedure based on solid-phase extraction (SPE) followed by liquid chromatography-tandem mass spectrometry has been developed for the simultaneous analysis of 55 basic drugs in equine urine. The test scope covers diversified classes of drugs including some ${\beta}$-blockers, ${\beta}$-agonists, antihypotensives, CNS stimulants, sedatives, tranquilizers, antidepressants, antihypertensives and so on. LC-MS/MS separation and quantification was carried out in positive electrospray ionization and multiple reaction monitoring (MRM) mode. Four different brands of mixed mode cation exchange SPE sorbents; UCT XTRACT$^{(R)}$ XRDAH, Supelco DSC-MCAX$^{(R)}$, Varian Bond Elut Certify$^{(R)}$ and Waters Oasis$^{(R)}$ MCX were compared. The UCT XTRACT$^{(R)}$ XRDAH sorbent provided the best results in the preconcentration of samples, yielding relative recoveries higher than 80% except for terbutaline (41.3%), salbutamol (71.5%), heptaminol (70.7%), phenylpropanolamine (66.3%). Detection limits of the target drugs provided by the proposed analytical procedure were between 0.2~8.3 ng/mL.

• Journal of Animal Environmental Science
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• v.6 no.3
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• pp.175-184
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• 2000

A lab-scale MF membrane reactor was installed to investigate the membrane permeability, characteristics of membrane fouling at each conditions, and quality of permeate (liquid livestock manure) in the separation of solid-matters using membrane. Experiment was divided three filtration type such as follows; continuous filtration, gravity filtration, and intermittent filtration. As a result of experiment, flux 1 LMH was maintained for 7days, and trans-membrane pressure(TMP) was increased gradually under 10cmHg, but it was increased immediately after 10cmHg, respectively. However, the flux was increased, the Tmax was decreased exponential more and more. During the pure-flux test, most of the fouling of membrane was reversible. At the gravity filtration, permeate could be obtained as 1.75 LMH for 3.5days without any other electronic pressure. As an investigation of membrane surface, this study could be decided that the reason of fouling at the lower flux (Run 1 and 2) was attached matters in membrane surface, but at the higher flux (Run 4-6) was concentration polarization.