• Title/Summary/Keyword: Solid nitrogen

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Preparation of Hydrazinium 5-aminotetrazolate(HAT) with High Nitrogen Content and Energetic Material (고질소 에너지 물질 Hydrazinium 5-aminotetrazolate (HAT)의 제조)

  • Lee, Woonghee;Kim, Seung Hee
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.5
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    • pp.53-59
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    • 2019
  • Solid fuel reacts with an oxidizer during combustion of a propellant to increase performance. Representative solid fuels are aluminum, cyclotrimethylenetrinitramine (RDX) and octahydro-1, 3,5,7-tetra nitro-1,3,5,7-tetrazocin (HMX). During combustion, these compounds generate white smoke by reacting with moisture and produce materials that are harmful to the environment, such as carbon monoxide, carbon dioxide, and methane gas. This study prepared a high-nitrogen-containing energetic material, hydrazinium 5-aminotetrazolate (HAT), which could be applied as a solid fuel. The compound was characterized by nuclear magnetic resonance (NMR) spectroscopy, and a thermal analysis was measured by differential scanning calorimetry (DSC). Also, the specific impulses and volumes of detonation gases were calculated using the EXPLO5 program.

Correlation between operation factors and nitritation using anaerobic digester supernatant at ordinary temperature (상온 조건에서 혐기 소화 상징액을 이용한 아질산화 반응과 운전 인자의 상관성 분석)

  • Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.18 no.3
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    • pp.244-249
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    • 2016
  • Anaerobic digester supernatant including high concentrations of nitrogen is recycled to water treatment line and make pollutant load increase in municipal wastewater treatment plant(MWTP). To treat nitrogen in anaerobic digester supernatant is suggested the method of MWTP retrofit. In this study, the lab scale reactor was operated about 200 days using supernatant of anaerobic digester. The results could draw operation condition that ammonium nitrogen removal efficiency more than 90% and nitrite conversion efficiency over 70%. Correlation between operation efficiency and operation factors was analyzed based on the operation results. Ammonium nitrogen remove efficiency and nitrite conversion efficiency were related to solid retention time (SRT), ammonium nitrogen load and ammonium nitrogen loading per unit mixed liquer suspended solid (MLSS). Results of this study can be used effective data on nitritation of supernatant of anaerobic digester, and be expected to increase availability of nitritation.

An aerobic granular sludge process for treating low carbon/nitrogen ratio sewage

  • Yae, JaeBin;Ryu, JaeHoon;Tuyen, Nguyen Van;Kim, HyunGu;Hong, SeongWan;Ahn, DaeHee
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.238-245
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    • 2019
  • This study investigated the characteristic of aerobic granular sludge (AGS) process to treat the sewage having low carbon/nitrogen ratio (Biochemical oxygen demand ($BOD_5$):Total nitrogen (T-N), 4.5:1) in sequencing batch reactor (SBR). The removal efficiency of $BOD_5$, suspended solid (SS), T-N and phosphorus ($PO_4{^{3-}}$-P) were 92.6%, 64.3% and 90.1%. Concentration and size of AGS were changed in proportion to the organic matters and nitrogen concentration of the influent (Concentration and size of AGS: 1,700-3,000 mg/L, 0.5-1.0 mm). Mixed liquor suspended solid (MLSS) also changed with the concentration of AGS (MLSS: 2,000-3,500 mg/L). When the settling time was shortened from 15 min to 10 min, size and shape of AGS were maintained (Size of AGS: 1.0-1.5 mm). In addition, the concentration of AGS and MLSS increased (Concentration of AGS: 3,500 mg/L, MLSS: 4,000 mg/L). Concentration, size and shape of AGS were affected the settling time of the reactor more than the concentration of organic matter and nitrogen in the influent. In the results of removal efficiency and changes in AGS, we confirmed that the SBR process using AGS can be used to treat the sewage having low carbon/nitrogen ratio by applying short settling time.

Production of Protein-bound Polysaccharides by Solid-substrate Fementation of Lentinus edodes (표고버섯의 고체배양에 의한 단백 다당류 생산)

  • 박경숙
    • The Korean Journal of Food And Nutrition
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    • v.11 no.6
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    • pp.667-672
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    • 1998
  • The possibility of solid-substrate fermentation of Lentinus edoes for the productin of protein-boud polysaccharides (PBP) was studied. Zeolite and orchid-pot soil were used as solid materials for the culture because of the desirable physical properties. Sucrose and starch were good carbon sources for the production of PBP by the solid-substrate fermentatin of L. edodes. Among the nitrogen source, bactosoyton was very effective for the PBP production. The optimum pH for solid-substrate fementation for the production of PBP was at pH of 5.5. The PBP production reached to 5∼5.5mg per 100g solid-substrate.

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Effect of MLSS and Micro-algae on Nitrification based Photosynthetic Oxygen (MLSS와 미세조류가 광합성 산소기반 질산화에 미치는 영향)

  • Lee, Jiwon;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.19 no.4
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    • pp.508-514
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    • 2017
  • Water-bloom and red tide due to eutrophication have been overgrown and have caused various environmental problems. Recently, however, research on bid-diesel that can utilize algae as an energy source has been actively carried out. In particular, many studies variously have been conducted to utilize algal photosynthesis oxygen as a supply method for reducing the energy by an air blower in MWTP. In this study, a lab scale algae-nitrification reactor was operated to replace the oxygen required for nitrogen removal and the operation period was largely divided into three sections. In the first section, ammonia nitrogen removal efficiency was 24 ~ 38% according to the MLSS (Mixed Liquer Suspended Solid) concentration. In the second section, ammonia nitrogen removal efficiency was 38 ~ 50% according to the micro-algae concentration and in the last section ammonia nitrogen removal efficiency was 61 ~ 80% according to HRT (Hydraulic Retention Time). As a result, as the MLSS decreased and algae biomass increased, the ammonia nitrogen removal efficiency tended to increase, but the effect of Algae biomass was greater than that of MLSS.

Methodology for Describing Different Phase States of Molecular Nitrogen

  • Cho, Haeng Muk;Kudryavtsev, I.N.;Kramskoy, A.V.
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.215-222
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    • 2014
  • A theory-based methodology for describing the thermodynamic properties of molecular nitrogen is presented. The results obtained indicate a successful application of a fully consistent statistical method for the description of a molecular system in different phase states. The method employs a density of states equation for solid nitrogen and a perturbation potential for gaseous and liquid nitrogen. The main characteristics of the calculation method include the need for a minimal number of initial data and the absence of fitting parameters. The adequacy of the physical model that is the basis for the method allows a description of existing experimental data and the peculiarities of the thermodynamic properties.

Effect of $Mo_2C$ Content on the Microstructure and Properties of Ti(CN)-$Mo_2C$ Ceramics

  • Park, Dong-Soo;Lee, Yang-Doo;Taejoo Jung
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.230-234
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    • 1999
  • Ti(CN)-0.3mole% $Mo_2C$ ceramics were prepared by pressureless sintering. $Mo_2C$ dissolved in Ti(CN) more easily in a nitrogen environment than in the other environment because nitrogen forced Mo to form a solid solution, (Ti, No)(C, N). A "core-rim" structure developed within the grains. The boundary between the "core" and the rim was delineated by thermal etching in the sample with more than 2 mole% $Mo_2C$. The rim thickness and the grain size decreased as the $Mo_2C$ content increased. The hardness and the flexural strength showed maxima of 18.2 GPa and 1.23 GPa, respectively when the $Mo_2C$ content was 2 mole%. The post-sintering heat treatments improved the properties.oved the properties.

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Effects of Temperature and Culture Media Composition on Sporulation, Mycelial Growth, and Antifungal Activity of Isaria javanica pf185

  • Lee, Jang Hoon;Lee, Yong Seong;Kim, Young Cheol
    • Research in Plant Disease
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    • v.27 no.3
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    • pp.99-106
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    • 2021
  • The fungal isolate Isaria javanica pf185 has potential as a mycopesticide because it demonstrates insecticidal activity against the green peach aphid and antifungal activity against Colletotrichum gloeosporioides. For commercialization of this isolate, determination of the optimal and least expensive culture conditions is required; however, these data are not currently available. This study describes the conditions for optimal development of conidia and production of metabolites for the biocontrol of the fungal pathogen. The optimal culture conditions were examined using cultures on solid agar and liquid media. High growth temperature enhanced spore formation but reduced antifungal activity in both solid and liquid media. The highest spore yield was obtained in a medium containing glucose as a carbon source and yeast extract as a nitrogen source. Soybean powder and wheat bran were effective nitrogen sources that promoted spore production and antifungal activity of the isolate. These results revealed the basic, cost-effective growth media for commercial production of a biopesticide with insecticidal and antifungal properties for use in integrated pest management.

Production of Glutaminase (E.C. 3.2.1.5) from Zygosaccharomyces rouxii in Solid-State Fermentation and Modeling the Growth of Z. rouxii Therein

  • Iyer, Padma;Singhal, Rekha S.
    • Journal of Microbiology and Biotechnology
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    • v.20 no.4
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    • pp.737-748
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    • 2010
  • Glutaminase production in Zygosaccharomyces rouxii by solid-state fermentation (SSF) is detailed. Substrates screening showed best results with oatmeal (OM) and wheatbran (WB). Furthermore, a 1:1 combination of OM:WB gave 0.614 units/gds with artificial sea water as a moistening agent. Evaluation of additional carbon, nitrogen, amino acids, and minerals supplementation was done. A central composite design was employed to investigate the effects of four variables (viz., moisture content, glucose, corn steep liquor, and glutamine) on production. A 4-fold increase in enzyme production was obtained. Studies were undertaken to analyze the time-course model, the microbial growth, and nutrient utilization during SSF. A logistic equation ($R^2$=0.8973), describing the growth model of Z. rouxii, was obtained with maximum values of ${\mu}_m$ and $X_m$ at $0.326h^{-1}$ and 7.35% of dry matter weight loss, respectively. A goodfit model to describe utilization of total carbohydrate ($R^2$=0.9906) and nitrogen concentration ($R^2$=0.9869) with time was obtained. The model was used successfully to predict enzyme production ($R^2$=0.7950).

New Cooling Techniques of High Tc Superconductor Systems (고온초전도 시스템의 새로운 냉각기술)

  • Chang, Ho-Myung
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.7-11
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    • 1999
  • The recent progress in new cooling techniques of the high Tc superconductor(HTS) systems is reported and discussed with some practical examples. At the beginning stage of the HTS development in research laboratories, liquid nitrogen(LN$_2$) is the standard medium for an effective cooling. The success of HTS in many different application areas, however, has required a variety of need in the cooling temperature and the cooling capacity with specific design restrictions. While the utilization of alternative liquid cryogens such as liquid neon (LNe) or liquid hydrogen (LH$_2$) has been tired in some of them, even solid cryogens such as solid nitrogen (SN$_2$) or solid hydrogen (SH$_2$) may be another option in special applications. The gaseous helium cooled by a cryogenic refrigerator has also been a good candidate in many cases. One of the best cooling methods for the HTS is the direct conduction-cooling by a closed-cycle refrigerator with no cryogen at all. The refrigeration may be based on Joul-Thomson, Brayton, Stirling, Gifford-McMahon, or pulse tube cycles. The pros and cons of the newly proposed cooling methods are described and some significant design issues are presented.

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