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http://dx.doi.org/10.6108/KSPE.2019.23.5.053

Preparation of Hydrazinium 5-aminotetrazolate(HAT) with High Nitrogen Content and Energetic Material  

Lee, Woonghee (Energetic Materials & Pyrotechnics Department, Hanwha Corporation Defence R&D Center)
Kim, Seung Hee (The 4th R&D Institute - 2nd Directorate, Agency for Defense Development)
Publication Information
Journal of the Korean Society of Propulsion Engineers / v.23, no.5, 2019 , pp. 53-59 More about this Journal
Abstract
Solid fuel reacts with an oxidizer during combustion of a propellant to increase performance. Representative solid fuels are aluminum, cyclotrimethylenetrinitramine (RDX) and octahydro-1, 3,5,7-tetra nitro-1,3,5,7-tetrazocin (HMX). During combustion, these compounds generate white smoke by reacting with moisture and produce materials that are harmful to the environment, such as carbon monoxide, carbon dioxide, and methane gas. This study prepared a high-nitrogen-containing energetic material, hydrazinium 5-aminotetrazolate (HAT), which could be applied as a solid fuel. The compound was characterized by nuclear magnetic resonance (NMR) spectroscopy, and a thermal analysis was measured by differential scanning calorimetry (DSC). Also, the specific impulses and volumes of detonation gases were calculated using the EXPLO5 program.
Keywords
Solid fuel; Tetrazole; Synthesis;
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