• Title/Summary/Keyword: Solid loading rate

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The Measurement Technique of Burning Rate in Solid Proplellant at High Pressure (고체추진제의 고압 연소속도 측정기법)

  • Yoo, Ji-Chqang;Jung, Jung-Young;Yim, Yoo-Jin;Ko, Seung-Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.12 no.4
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    • pp.1-6
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    • 2008
  • The burning characteristics of HTPB/AP solid propellants were measured by closed bomb of internal volume of 200 cc and 700 cc up to 30,000 psia. The burning rates of closed bomb method showed good agreement with those of strand burner method between 1,000 psia and 5,000 psia, and the sharp increment of pressure exponent(n) around 6,000 psia as a result of testing in accordance with loading densities. The burning rate measured in 200 cc and 700 cc of internal volume of closed bomb agreed well without the relation of internal volume size.

High Temperature Gas Leak Behavior of Glass-Ceramic Fiber Composite Seals for SOFC Applications (SOFC용 유리-세라믹섬유 복합기밀재의 고온 기체누설 거동)

  • Lee, Jae-Chun;Kwon, Hyuk-Chon;Kwon, Young-Pil;Park, Sung;Jang, Jin-Sik;Lee, Jongho;Kim, Joosun;Lee, Hae-Won
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.842-845
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    • 2005
  • Glass composites containing ceramic fiber have been developed for Solid Oxide Fuel Cell (SOFC) seals. Effect of glass type, loading pressure and thermal cycle the leak rates of composite seals was investigated. Seal performance of two commercial glasses was compared with that of $SiO_2BaO-B_2O_3$ glass synthesized in this work. The leak rate for seals made of pyrex(R) increases from $\~0.0005\;to\;\~0.004sccm/cm$ as the gas pressure increases from 10 to 50 kPa. The soda lime silicate glass seal shows the leak rate two times higher than the one made of pyrex(R) or $SiO_2BaO-B_2O_3$ glass. The viscosity of glass at the seal test temperature is presumed to affect the leak rate of the glass seal. As the applied loading pressure increases from 0.4 to 0.8 MPa at $750^{\circ}C$, the leak rate decreases from 0.038 to 0.024 sccm/cm for composite seals. It has been found that during 50 thermal cycles between $450^{\circ}C\;to\;700^{\circ}C$ leak rates remained almost constant, ranging from 0.025 to 0.03sccm/cm. The results showed an excellent thermal cycle stability as well as sealability of the glass matrix ceramic fiber composite seals.

Mathematical Model for Adsorption of Berberine on Encapsulated Adsorbent (캡슬에 고정화된 흡착제에의 Berberine의 흡착에 관한 수학적 모델)

  • 최정우;조상원이원홍
    • KSBB Journal
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    • v.10 no.4
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    • pp.358-369
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    • 1995
  • A mathematical model using local thermodynamic equilibrium isotherms for adsorption in encapsulated adsorbent is proposed in order to optimize the design parameters in situ bioproduct separation process. The model accurately follows the experimental data on the adsorption of berberine, secondary metabolite produced in Thaictrum rugosum plant cell culture. The adsorption rate on encapsulated adsorbent is compared with that on alginate-entrapped adsorbent. The result shows that the higher loading capacity in encapsulated adsorbent is mainly due to the increase in the maximum solid phase concentration. Based on the adsorption rate and loading capacity, the encapsulated adsorbent would be more useful than the entrapped adsorbent when used in situ bioproduct separation process. Design parameters in situ bioproduct separation process, such as the size of the capsule, membrane thickness, the ratio of capsule volume to bulk volume, the ratio of single capsule volume to total capsule volume and the adsorbent content in the capsule, are evaluated by using the model. The ratio of single capsule volume to total capsule volume is the most effective parameter for adsorption of berberine on encapsulated adsorbent.

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Solid-Phase Extraction of Caffeine and Catechin Compounds from Green Tea by Caffeine Molecular Imprinted Polymer

  • Jin, Yinzhe;Row, Kyung-Ho
    • Bulletin of the Korean Chemical Society
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    • v.28 no.2
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    • pp.276-280
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    • 2007
  • In this work, caffeine and some catechin compounds + C, EC, EGC, and EGCG were extracted from green tea by using molecular imprinted polymers (MIP) as sorbent materials in a solid-phase extraction (SPE) process known as MISPE (molecular imprinted solid-phase extraction). For synthesis of MIP, caffeine was employed as the template, MAA as the monomer, EGDMA as the crosslinker, and AIBN as the initiator. A solution of caffeine (0.2 mg/mL in methanol) was utilized in the solid extraction cartridges following loading, washing, and elution procedures with acetonitrile, methanol, and methanol-acetic acid (90/10, %v/v) as the solvents, respectively. This solid-phase extraction protocol was applied for the extraction of caffeine and some catechin compounds from green tea. A comparison was made between the results obtained with the MIP cartridges and a traditional C18 reversed-phase cartridge. It was thereupon found that the recovery of caffeine by the MIPbased sorbent used in this work was almost two and four times greater than that by a commercially available C18 material. A quantitative analysis was conducted by high performance liquid chromatography (HPLC) using a C18 column (5 μm, 250 × 4.6 mm) with methanol/water (40/60, %v/v) as the mobile phase at a flow rate of 0.5 mL/min.

The Feasibility of Co-Incineration for Municipal Solid Waste and Sewage Sludge through the Change of Heat Loading and Atmospheric Pollutants Loading (하수슬러지와 생활폐기물 혼합소각시 열부하 변화 및 대기오염물질 부하 변화를 통한 혼합소각 가능성에 관한 연구)

  • Cho, Jae-Beom;Kim, Woo-Gu;Yeon, Kyeong-Ho;Shin, Jung-Hun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.9
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    • pp.583-589
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    • 2012
  • The various promotion countermeasures such as solidification, carbonization, and the creation of cement materials have been considered to existing treatment methods such as incineration and the creation of composts, since direct landfill was prohibited for encouraging the recycling based on the sludge treatment on land. The Main objective of this study is to investigate the feasibility of co-incineration for MSW (Municipal Solid Waste) and SS (Sewage Sludge) through the change of heat and atmospheric pollutants. In this study, LHV (Low Heating Value) is 100~300 kcal/kg because the MC (Moisture Content) of de-hydrated sewage sludge is approximately 80%. From the results, we knew the feasibility of co-incineration for MSW (80%) and SS (20%). As the co-incineration rate of SS up to 20% became higher, the loading of heat and atmospheric pollutants was not influenced.

A Study on the COD Removal in the Paste-board Wastewater by Activated Sludge Process (활성오니법에 의한 판지폐수중의 COD 제거에 관한 연구)

  • 도갑수;김영운
    • Journal of the Korean Professional Engineers Association
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    • v.18 no.3
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    • pp.28-35
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    • 1985
  • As the paper industry consumes much water in process and discharge wastewater containing suspended solid and COD(chemical oxygen demand), relevant law against this discharge has been set up to limit the total containment of COD in discharge. This study has been carried out to improve the treatment method for the soluble COD in wastewater produced during the process of paste-board production, which is made of semichemical pulp and waste paper. Applicated methods are, O$_2$AS : O$_2$ activated sludge process DAS : Deep well activated sludge process SAS : standard activated sludge process and proper combination of DAS and SAS 1) As a result of this experiment, we get the following conclusion between in COD sludge loading "X" and COD removable rate in the process of treating waste-water. COD removable rate(%)=(0.778+0.0146/X)${\times}$100(%)……(7) 2) In case that the COD sludge loading is high, it has been cleared out that the COD removable rate shall become low due to unknown unsoluble substances contained in the process. Meanwhile, to increase the efficiency rate of treatment, it is thought to be necessary, to provide long-time contacts with activated sludge. 3) Once the COD of original waste-water and the target COD of treated water are decided, COD sludge loading is obtained from equation(7), and capacity of aeration tank in the effective systems such as O$_2$AS, DAS, to bet the required COD removable rate can be decided. Therefore the choice among SAS, O$_2$AS, DAS methods is made in consideration of required COD removable rate and allowable installation area. 4) In the sedimentation tank with sludge bulking, it is possible to increase the COD removable rate by 3~7% but still there exist many obstacles to manage this operation.

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Polarization Behavior of Li4Ti5O12 Negative Electrode for Lithiumion Batteries

  • Ryu, Ji-Heon
    • Journal of Electrochemical Science and Technology
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    • v.2 no.3
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    • pp.136-142
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    • 2011
  • $Li_4Ti_5O_{12}$ is prepared through a solid-state reaction between $Li_2CO_3$ and anatase $TiO_2$ for applications in lithium-ion batteries. The rate capability is measured and the electrode polarization is analyzed through the galvanostatic intermittent titration technique (GITT). The rate characteristics and electrode polarization are highly sensitive to the amount of carbon loading. Polarization of the $Li_4Ti_5O_{12}$ electrode continuously increases as the reaction proceeds in both the charge and discharge processes. This relation indicates that both electron conduction and lithium diffusion are significant factors in the polarization of the electrode. The transition metal (Cu, Ni, Fe) ion added during the synthesis of $Li_4Ti_5O_{12}$ for improving the electrical conductivity also greatly enhances the rate capability.

An Overstress Model for Non-proportional Loading of Nylon 66 (Nylon 66의 무비례 하중에 대한 과응력 모델)

  • Ho, Gwang-Su
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.12
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    • pp.2056-2061
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    • 2001
  • Non-proportional loading tests of Nylon 66 at room temperature exhibit path dependent behavior and plasticity-relaxation interactions. The uniaxial formulation of the viscoplasticity theory based on overstress (VBO), which has been used to reproduce the nonlinear strain rate sensitivity, relaxation, significant recovery and cyclic softening behaviors of Nylon 66, is extended to three-dimensions to predict the response in strain-controlled, comer-path tests. VBO consists of a flow law that is easily written for either the stress or the strain as the independent variable. The flow law depends on the overstress, the difference between the stress and the equilibrium stress that is a state variable in VBO. The evolution law of the equilibrium stress in turn contains two additional state variables, the kinematic stress and the isotropic stress. The simulations show that the constitutive model is competent at modeling the deformation behavior of Nylon 66 and other solid polymers.

Analysis of Turbulent Gas-Particle Suspension Flows in a Venturi (固體粒子 가 浮上된 벤츄리管 流動 의 解析)

  • 성형진;정명균
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.2
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    • pp.133-140
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    • 1984
  • A "two-fluid" equation model has been applied for predicting gas-solid suspension flows through a Venturi tube. In the "two-fluid"equation model, the bulk motion of the particles is considered as a continuum whose governing equation is obtained by averaging the conservation equations over a volume and expressing the equations in differential forms. Closure of the time-mean equations is achieved by modeling the turbulent correlations with an extended mixing-length theory. Proposed closure model is found to aptly simulate the dependency of the static pressure drop on the particle size, flow rate and the loading ratio.d the loading ratio.

A Study on the Kinetics and the Biogas Formation for Organic Wastewater Treatment in Anaerobic Fluidized-Bed Bioreactor and New Model AFPBBR (혐기성 유동층 생물 반응기와 새로운 모델의 AFPBBR에서 유기성폐수 처리시 Biogas 생성과 반응상수에 관한 연구)

  • 김재우;장인용
    • Journal of Environmental Health Sciences
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    • v.19 no.2
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    • pp.23-33
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    • 1993
  • The anaerobic digestion of organic synthetic wastewater in anaerobic fluidized bed bioreactor (AFBBR) and anaerobic fluidized packed bed bioreactor (AFPBBR) was studied. This study was conducted to evaluate efficiency and reliability of two reactor. Experiment was performed to find the effect of upflow rate with AFBBR and the height of packed bed with AFPBBR. As a result, this program obtained several conclusion. These are given as follows: As applied the upflow rate increased in AFBBR the produced volume of biogas increased, while the gas production and COD removal decreased at above 0.3 m$^3$/h. When a upflow rate is 0.4 m$^3$/h in AFBBR the volatile suspended solid (VSS) became significantly increased. At an organic loading rate from 0.1 to 0.4 of upflow rate in AFBBR, the methane yield was 1.5584 m$^3$CH$_4$/kgCOD removed, and the observed cell yield coefficient was 0.0933 gVSS/gCOD. In case of AFPBBR, the results showed also that 20 cm of height of packed bed was superior to other in the aspect ot biogas production, the content of methane and COD removal. At 20 cm of height, the profile of microorganisms was stable, while at 30 cm the VSS of effluent became higher than AFBBR. Though COD removal of AFPBBR increased with packed bed, COD removal deteriorate with over packing because the loss of pressure became higher in the reactor. At an organic loading rate from 20 to 40 cm of packed bed in-AFPBBR, the methane yield was 2.5649 m$^3$CH$_4$/kgCOD removed, and the observed cell yield coefficient was 0.0506 gVSS/gCOD. Based upon the results obtained, it is suggested that AFBBR and AFPBBR is the most effective conditions at 0.3 m3/h of upflow rate, the 20cm of packed bed, respectively. The rate constant are summarized as follow:

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