• Journal of the Korean Chemical Society
• /
• v.43 no.5
• /
• pp.511-516
• /
• 1999

Shiff Base ligand such as [NOIPH] have been synthesized from 2-hydroxy-1-naphthaldehyde and arometic amine. Co(II), Ni(II), and Cu(II) complexes from the reaction metal salts with Tridentate Schiff Base [NOIPH] were sythesized. The ligand and metal(II) complexes were characterized by the elementary analysis, IR, UV-Vis, NMR spectra, and thermogravimetric analysis. Metal(II) complexes in solid state have been shown that the mole raio of Schiff base [NOIPH] as $N_2O$ type to Metal(II) is 2:1 and the metal(II) complexes of $N_2O$ ligand type were four-coordinated configuration.

• Structural Engineering and Mechanics
• /
• v.52 no.5
• /
• pp.875-887
• /
• 2014

The aim of the shaking table experiment is to verify the isolation effect of a storage liquid tank with multiple friction pendulum bearings. A 1:20 scale model of a real storage liquid tank that is widely used in the petroleum industry was examined by the shaking table test to compare its anchored base and isolated base. The seismic response of the tank was assessed by employing the time history input. The base acceleration, wave height and tank wall stress were used to evaluate the isolation effect. Finally, the influences of the bearing performance that characterizes the isolated tank, such as the friction force and residual displacement, were discussed.

• Journal of Welding and Joining
• /
• v.23 no.6
• /
• pp.99-105
• /
• 2005

The mixing ratio effect of the GTD-111(base metal) powder and the GNI-3 (Ni-l4Cr-9.5Co-3.5Al-2.5B) powder on TLP(Transient Liquid Phase) bonding phenomena and mechanism was investigated. At the mixing ratio of the base metal powder under $50wt\%$, the base metal powders fully melted at the initial time and a large amount of the base metal near the bonded interlayer was dissolved by liquid inter metal. Liquid insert metal was eliminated by isothermal solidification which was controlled by the diffusion of B into the base metal. The solid phases in the bonded interlayer grew epitaxially from the base metal near the bonded interlayer inward the insert metal during the isothermal solidification. The number of grain boundaries farmed at the bonded interlayer corresponded with those of base metal. At the mixing ratio above $60wt\%$, the base metal powder melted only at the surface of the powder and the amount of the base metal dissolution was also less at the initial time. Nuclear of solids firmed not only from the base metal near the bonded interlayer but also from the remained base metal powder in the bonded interlayer. Finally, the polycrystal in the bonded interlayer was formed when the isothermal solidification finished. When the isothermal solidification was finished, the contents of the elements in the boned interlayer were approximately equal to those of the base metal. Cr-W borides and Cr-W-Ta-Ti borides formed in the base metal near the bonded interlayer. And these borides decreased with the increasing of holding time.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.11 no.6
• /
• pp.1-8
• /
• 2007

The objective of the present work is to characterize design parameters of solid propellant ignitor for composite, double base, and nitramine propellants using arc image furnace. Arc image furnace and fiber optics surface reflectometer were used to measure ignition delay time and reflected optical energy of several compositions of composite, double base and nitramine base rocket propellant at different pressure levels each other. The order of ignitability was double base > composite> nitramine propellants at initial pressure of over 75 psia. The highest ignition energy was needed to ignite nitramine propellant, however, the ignition delay time decreased abruptly as the pressure increased up to the range of $75{\sim}400$ psia. The absorbtion of radiation energy could be increased by the addition of small amount of opacifiers as carbon black, ZrC, WC and burning catalyst.

• Journal of the Korean Chemical Society
• /
• v.58 no.3
• /
• pp.283-288
• /
• 2014

A column solid phase extraction procedure based on modified polyurethane foam (PUF) by a newly synthesized Schiff base ionophore, named 2,2'-{iminobis[propane-3,1-diylnitrilo(1E)prop-1-yl-1-ylidene]}diphenol, was developed for preconcentration step of trace amounts determination of copper ions in water samples by atomic absorption flame spectroscopy. The influence of parameters on the adsorption process such as sample pH, amount of modified PUF packed in the column, type and volume of stripping reagent and its flow rate were investigated and optimized. Under optimum experimental conditions, the calibration graph was linear in a relatively wide range ($0.005-210{\mu}g/ml$) with a limit of detection $0.002{\mu}g/ml$ of copper. The proposed method allows achieving to a concentration factor of >133. The capacity of a column (1.6 cm i.d.) packed by 6 g of PUF modified by 12 mg of the Schiff base was found to be $247.7({\pm}2.1){\mu}g$ of copper. It was found that the adsorption process was highly selective towards copper ions with respect to some associated metal ions. The presented procedure was successfully applied for determination of copper in some water samples.

• Journal of Powder Materials
• /
• v.9 no.3
• /
• pp.189-198
• /
• 2002

In this work, transient liquid phase (TLP) bonding of Ni-Cr heat resisted cast alloy (HP) was investigated. And also the behaviors of the solid particles distributed in the interlayer during TLP bonding were investigated. The MBF-60 and solid particles (Ni, Fe, and $Al_2O_3$ powders respectively) added MBF-60 which will be a liquid phase coexisting with solid particles at the bonding temperature were used as insert metal. The effective and sound bonding was possible by spark plasma sinter-bonding due to the differences of electric resistance between base metal and liquid insert layer which creates high temperature region. During the isothermal solidification, $Al_2O_3$ particles and solid particles of liquid phase sintered insert metal have shown no growth, while Ni and Fe particles grow rapidly. In this TLP bonding using the MBF-60 and distributed Fe, Ni particles as insert materials, the whole isothermal solidification process was dominated by the growth rate of the solid particles distributed in the interlayer.

• Journal of the Korean Ceramic Society
• /
• v.32 no.2
• /
• pp.234-238
• /
• 1995

MgFe2O4 formation, grain growth in Fe2O3, Fe solid-solution limit in MgO for MgO-Fe2O3 mixture were studied by means of investigating the distribution of phases and compositions in reaction area between MgO and Fe2O3. The reaction area at equlibrium was composed with MgO-FexO matrix and MgFe2O4 precipitation, MgFe2O4 was formed by precipitating from MgO-FexO matrix dependent on oxygen partial pressure. Fe contents was exponentially decreased with diffusion distance in MgO single crystal, and thus Fe solid-solution limitation in MgO was about 4mol%. The grain growth rate in Fe2O3 base was increased with Mg contents diffused from MgO single crystal.

• Smart Structures and Systems
• /
• v.26 no.2
• /
• pp.185-193
• /
• 2020

Nonlinear vibration of sandwich plate with functionally graded material (FGM) core and carbon nano tubes reinforced (CNTs) nano-composite layers by considering temperature-dependent material properties are studied in this paper. Base on Classical plate theory (CPT), the governing partial differential equations of motion for sandwich plate are derived using Hamilton principle. The Galerkin procedure and multiple scales perturbation method are used to find relation between nonlinear frequency and amplitude of vibration response. The dynamic responses of the sandwich plate are also investigated in both time and frequency domains. Then, the effects of nonlinearity, excitation, power law index of FG core, volume fraction of carbon nanotube, the function of material variations of FG core, temperature changes, scale transformation parameter and damping factor on the frequency responses are investigated.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.45-50
• /
• 2014

A fully packed capillary electrochromatographic (CEC) microchip with an on-column micro-solid phase extraction (SPE) bed for the preconcentration and separation of organic analytes was prepared. A linear microchannel with monodisperse colloidal silica packing was formed on a cyclic olefinic copolymer microchip with two reservoirs on both ends. Silver-cemented silica packing frit structure was formed at the entrance of the microchannel by electroless plating treatment as a base layer. A gold coating was formed on it by reducing $Au^{3+}$ to gold with hydroxylamine. Finally micro-SPE bed was formed by self-assembly adsorption of 1-dodecanethiol on it. Micro-SPE beds were about 100-150 ${\mu}m$ long. Approximately $10^3$ fold sensitivity enhancements for Sulforhodamine B, and Fluorescein in nM concentration levels were possible with 80 s preconcentration. Basic extraction characteristics were studied.

• Proceedings of the PSK Conference
• /
• 2003.10b
• /
• pp.236.1-236.1
• /
• 2003

Evaluation of solid surface properties is very important for formulation of solid dosage form, specially insoluble drugs. The contact angle of insoluble drugs was measured by the penetration rate into powder bed using Washburn equation and wicking method. From the measured contact angle data, the surface free energy value of pharmaceutical powders ${\gamma}$s was divided and analysized into the polar component, ${\gamma}$s$\^$p/ and the dispersion component, ${\gamma}$s$\^$d/. Furthermore, the data was interpreted for acid part, ${\gamma}$s$\^$+/ and base part, ${\gamma}$s$\^$$\square$/ of surface free energy. (omitted)