• Journal of Powder Materials
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• v.12 no.2 s.49
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• pp.112-116
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• 2005

In the present study, the focus is on the analysis of carbothermal reduction of oxide powder prepared from waste WC/Co hardmetal by solid carbon under a stream of argon for the recycling of the WC/Co hard-metal. The oxide powder was prepared by the combination of the oxidation and crushing processes using the waste $WC-8 wt.\%Co$ hardmetal as the raw material. This oxide powder was mixed with carbon black, and then this mixture was carbothermally reduced under a flowing argon atmosphere. The changes in the phase structure and gases discharge of the mixture during carbothermal reduction was analysed using XRD and gas analyzer. The oxide powder prepared from waste $WC-8wt.\%Co$ hardmetal has a mixture of $WO_{3} and CoWO_{4}$. This oxide powder reduced at about $850^{\circ}C$, formed tungsten carbides at about $950^{\circ}C$, and then fully transformed to a mixed state of tungsten carbide (WC) and cobalt at about $1100^{\circ}C$ by solid carbon under a stream of argon. The WC/Co composite powder synthesized at $1000^{\circ}C$ for 6 hours from oxide powder of waste $WC-8wt.\%Co$ hardmetal has an average particle size of $0.3 {\mu}m$.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.6
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• pp.657-665
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• 2010

Carbon dioxide ($CO_2$) is known to be a major greenhouse gas partially emitted from waste combustion facilities. According to the greenhouse gas emission inventory in Korea, the quantity of the gas emitted from waste sector in 2005 represents approximately 2.5 percent of all domestic greenhouse gas emission. Currently, the emission rate of greenhouse gas from the waste sector is relatively constant partly because of both the reduced waste disposal in landfills and the increased amounts of waste materials for recycling. However, the greenhouse gas emission rate in waste sectors is anticipated to continually increase, mainly due to increased incineration of solid waste. The objective of this study was to analyze the property of Municipal Solid Waste (MSW) and estimate $CO_2$ emissions from domestic MSW incineration facilities. The $CO_2$ emission rates obtained from the facilities were surveyed, along with other two methods, including Tier 2a based on 2006 IPCC Guideline default emission factor and Tier 3 based on facility specific value. The $CO_2$ emission rates were calculated by using $CO_2$ concentrations and gas flows measured from the stacks. Other parameters such as waste composition, dry matter content, carbon content, oxidation coefficient of waste were included for the calculation. The $CO_2$ average emission rate by the Tier 2a was 34,545 ton/y, while Tier 3 was 31,066 ton/y. Based on this study, we conclude that Tier 2a was overestimated by 11.2 percent for the $CO_2$ emission observed by Tier 3. Further study is still needed to determine accurate $CO_2$ emission rates from municipal solid waste incineration facilities and other various combustion facilities by obtaining country-specific emission factor, rather than relying on IPCC default emission factor.

• Journal of Korea Society of Waste Management
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• v.35 no.7
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• pp.606-615
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• 2018

Over the past two decades, the options for solid waste management have been changing from land disposal to recycling, waste-to-energy, and incineration due to growing attention for resource and energy recovery. In addition, the reduction of greenhouse gas (GHG) emission has become an issue of concern in the waste sector because such gases often released into the atmosphere during the waste management processes (e.g., biodegradation in landfills and combustion by incineration) can contribute to climate change. In this study, the emission and reduction rates of GHGs by the municipal solid waste (MSW) management options in D city have been studied for the years 1996-2016. The emissions and reduction rates were calculated according to the Intergovernmental Panel on Climate Change guidelines and the EU Prognos method, respectively. A dramatic decrease in the waste landfilled was observed between 1996 and 2004, after which its amount has been relatively constant. Waste recycling and incineration have been increased over the decades, leading to a peak in the GHG emissions from landfills of approximately $63,323tCO_2\;eq/yr$ in 2005, while the lowest value of $35,962tCO_2\;eq/yr$ was observed in 2016. In 2016, the estimated emission rate of GHGs from incineration was $59,199tCO_2\;eq/yr$. The reduction rate by material recycling was the highest ($-164,487tCO_2\;eq/yr$) in 2016, followed by the rates by heat recovery with incineration ($-59,242tCO_2\;eq/yr$) and landfill gas recovery ($-23,922tCO_2\;eq/yr$). Moreover, the cumulative GHG reduction rate between 1996 and 2016 was $-3.46MtCO_2\;eq$, implying a very positive impact on future $CO_2$ reduction achieved by waste recycling as well as heat recovery of incineration and landfill gas recovery. This study clearly demonstrates that improved MSW management systems are positive for GHGs reduction and energy savings. These results could help the waste management decision-makers supporting the MSW recycling and energy recovery policies as well as the climate change mitigation efforts at local government level.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.2
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• pp.101-111
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• 2009

In this study, the physico-chemical characteristics of municipal solid waste (MWS) which was treated in gangwon area were investigated. It is necessary to measure the characteristics of municipal solid waste for build a waste treatment and RDF facility and for data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $101.8{\sim}199.8kg/m^3$. This MSW was composed of 30.7% of food wastes, 36.3% of papers, 15.8% of plastics & vinyls, 1.9% of textiles, 3.2% of wood and 1.5% of rubber & leathers respectively. Most of MSW are composed of food, paper and plastic waste and the combustible waste is more than 90%. For three components, moisture is 44.6%, combustible component is 47.7% and ash is 7.7% respectively. The chemical elements are carbon, oxygen, and hydrogen on the dry basis of wastes. The low heating value of the MSW measured by calorimeter was obtained as 2,631 kcal/kg, and the high heating value of the MSW was obtained as 3,310 kcal/kg.

• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.415-420
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• 2001

Water usage in the semiconductor industries is dramatically increased by not only using bigger wafer from 8 inches to 12 inches but also by adapting new process such as Chemical Mechanical Planarization (CMP) process invented by IBM in late '80. However, The document published by International Semiconductor Association suggests the decreasing ultra pure water (UPW) use from 22 gallon/in$^2$in 1997 to 5 gallon/in$^2$ in 2012. The criteria will possibly used as exporting obstacle in the future. Generally, Solid content of CMP slurry is about 15wt%. The slurry is diluted with UPW before fed to a CMP process. When the slurry is discharged from the process as waste, it contains 0.1~0.6wt% of solid content and 9~10 at pH. The CMP waste slurry is discharged to stream with minimum treatment. In this study, to find optimum condition of coagulation for water recovery from the waste CMP slurry various condition of coagulation were examined. After coagulation far 0.1 wt% solid content of waste CMP slurry, the sludge volume was 10~15% after 30 min of sedimentation time. For the 0.5 wt%, sludge volume was 50~55% after one hour of sedimentation time. For more than 80% of water recycling, the solid content should be in the range of 0.1 to 0.2wr%. Based on the result of the turbidity removal, the Zeta Potential and the analysis of heavy metals, the optimum condition for 0.1 wr% of waste CMP slurry was with 20 mg/L of PACI at 4 to 5 of pH. The result showed that the optimum conditions fer the 0.1 wt% waste CMP slurry were 100mg/L of Alum at 4~5 of pH, 100 mg/L of MgCI$_2$at pH 10 to 11 and 100 mg/L of Ca(OH)$_2$at pH 9 to 11, respectively.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.4
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• pp.39-48
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• 2016

An information management system for a solid waste landfill site was developed, in this study, to optimize the operation and management of solid waste landfill in real time in addition to provide the information of landfill status to the landfill operator, public official concerned and local residents. The landfill information management system is composed of two systems (Solid waste landfill history management system and landfill operation and performance management system). The solid waste landfill history management system based on automated RFID/LPR system allows landfill operators to provide information of waste collection vehicles and received waste. In addition, the system aids in the identification of 3-dimensional (3D) position for landfilled solid wastes. Using the landfill operation and performance management system based on 3D laser scanner delivers information about landfill volume, settlement, landfill density, and current landfill capacity to landfill operators in real time, resulting in optimum space utilization. Ultimately, this system would dramatically reduce exposure of landfill operators to hazardous materials and improve the productivity of landfill operations.

• Environmental and Resource Economics Review
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• v.24 no.4
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• pp.747-761
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• 2015

This paper investigates the impact of an increase in unit price of solid waste collection on demand for alternative solid waste disposal types. I control for other variables affecting the demand and employ both community and time fixed effects models in the estimation of each reduced-form demand functions. Estimation results show that an increase in unit price reduces the demand for garbage bag collection services of non-food solid wastes while it increases the demand for food wastes and source-separated recyclables. These results imply that reduction in the demand for non-food solid wastes collection is mainly achieved by increasing the amount of recyclables and food wastes collected. However, it appears that an increase in unit price increases the total amount of solid wastes generated. This suggests that price incentive effects are offset by the decrease in source-reduction efforts because of feedback effects resulting from the increase in recycling, food waste separation, and illegal disposal of wastes.

• Journal of environmental and Sanitary engineering
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• v.13 no.3
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• pp.93-101
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• 1998

This study was carried out to investigate and analyze the citizen's attitude for the issue of the municipal solid wastes in Miryang city. The waste generation rate was decreased by 56% compared with 1991, and 71.8% of generated wastes were treated by landfill method. 61.6% among respondents were contacted waste problem by TV and the majority of respondents felt seriousness of food-waste problem. The majority of people felt that waste discharge decreased after "volume-base charge system" and 71% of total respondents were burdened down with use of volume-base charge envelope. The greater part of citizens answered that they experienced damage due to wastes and satisfied with the collection system but they recognized the necessity of the establishment of collection system and increase of cleaners must be nessary.

• Korean Management Science Review
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• v.20 no.1
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• pp.65-76
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• 2003

The increased environmental concerns and the emphasis on recycling are gradually shifting the orientation of municipal solid waste (MSW) management. This paper is designed to evaluate regionalization programs for MSW management system. We developed a mixed intiger network programming (MIP) model to identify environment-friendly, cost-effective expansion plans for regionalization scenarios considered. The MIP model is a dynamic capacity expansion model based on the network flow model that depicts the MSW management cycle. In particular, our model is designed to determine the optimal form of regionalization using binary variables. We apply this model to assess the regionalization program of Seoul Metropolitan City, which includes three scenarios such as 1) districting, 2) regionalization with neighboring self-governing districts, and 3) g1obalization with all districts. We demonstrate how our model can be used to plan the MSW system. The results indicate that optimal regionalization with nearby self-governing districts can eliminate unnecessary landfills and expansions if jurisdictional obstacles are removed.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.5
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• pp.561-572
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• 2010

The efficiency of biological hydrolysis at $80^{\circ}C$ on municipal solid waste mixed with anaerobic digestion sludge was investigated in 100L batch reactors. The hydrolysis effect was observed within a day, when the hydrolysis reactor used for a pre-treatment reactor for methanogenesis, and the effect was observed during two days, When the reactor used for post-treatment reactor. For both configurations, methane production rate decreased, when hydrolysis was carried out more than a day. Gaseous ammonia in the hydrolysis reactors was successtully removed by the ammonia stripping system. Microbial diversity analysis on the hydrolysis reactors indicated dependency of microbial diversity on the configuration of the hydrolysis reactors. Carbohydrate and lactate degrading microbes dominated in the hydrolysis reactor, when the hydrolysis reactor used for a pre-treatment reactor for methanogenesis, while protein degrading microbes dominated in the post-treatment reactor.