• Title/Summary/Keyword: Solid Storage

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Energy Storage Characteristics In Fixed Beds (Charging, Storing, Discharging)

  • Hassanein, Soubhi A.;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2004.11a
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    • pp.17-23
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    • 2004
  • In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during (charging ,storing, discharging) mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also efficiency of energy stored inside the bed is computed. Finally using refined model the effect of air flow rate per unit area Ga (0.2, 0.3, and 0.4 kg/$m^2$-s), and inlet air temperature (200, 250, 300 $^{\circ}C$) on energy storage characteristics was studied in three mode ( charging ,storing, discharging). The rock particles of diameter 1 em is used as bed material in this research.

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Energy Storage Characteristics in Fixed Beds;Part 1. Charging Mode

  • Hassanein, Soubhi A.;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.158-164
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    • 2004
  • In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during charging mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also energy stored inside the bed is computed. A comparison between refined model and non refined model is done. Finally using refined model the effect of bed material (Glass, Fine clay ,and aluminum ), and air flow rate per unit area Ga (0.3, 0.4, and 0.5 kg/$m^2$-s) on energy storage characteristics was studied.

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Recent Progress of Alloy-Based All-Solid-State Li-Ion Battery Anodes (전고체 리튬 이차전지용 합금계 음극 소재의 연구 동향)

  • Jeong-Myeong Yoon;Cheol-Min Park
    • Corrosion Science and Technology
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    • v.22 no.6
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    • pp.466-477
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    • 2023
  • The increasing demand for high-performance energy storage systems has highlighted the limitations of conventional Li-ion batteries (LIBs), particularly regarding safety and energy density. All-solid-state batteries (ASSBs) have emerged as a promising next-generation energy storage system, offering the potential to address these issues. By employing nonflammable solid electrolytes and utilizing high-capacity electrode materials, ASSBs have demonstrated improved safety and energy density. Automotive and energy storage industries, in particular, have recognized the significance of advancing ASSB technology. Although the use of Li metal as ASSB anode is promising due to its high theoretical capacity and the expectation that Li dendrites will not form in solid electrolytes, persistent problems with Li dendrite formation during cycling remain. Therefore, the exploration of novel high-performance anode materials for ASSBs is highly important. Recent research has focused extensively on alloy-based anodes for ASSBs, owing to their advantages of no dendrite formation and high-energy density. This study provides a comprehensive review of the latest advancements and challenges associated with alloy-based anodes for ASSBs.

Electrochemical properties of PEO-based solid polymer electrolytes blended with different room temperature ionic liquids

  • Kim, Y.H.;Cheruvally, G.;Choi, J.W.;Ahn, J.H.;Kim, K.W.;Ahn, H.J.;Song, C.E.;Choi, D.S.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.276-276
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    • 2006
  • The incorporation of room temperature ionic liquids (IL) in poly (ethyleneoxide)-lithium salt (PEO-LiX) based solid polymer electrolytes is presently being studied as an effective means of enhancing the room temperature ionic conductivity of these electrolytes to acceptable levels for use in lithium batteries. In the present study, $PEO_{20}-LiTFSI$ solid polymer electrolyte was blended with three different ionic liquids, namely 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (BMIMTFSI), 1-butyl-3-methylimidazolium tetraflouroborate (BMIMBF4) and 1-butyl-3-methylimidazolium trifluromethanesulfonate ($BMIMCF_{3}SO_{3}$). The incorporation of all these ILs resulted in the enhancement of ionic conductivity, the effect being more pronounced at lower temperatures. Electrochemical properties of the blended electrolytes were studied by cyclic voltammetry, linear sweep voltammetry and interfacial resistance measurements. The optimum results were obtained with the blending of BMIMTFSI in the solid polymer electrolyte.

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A study on the estimation of temperature distribution around gas storage cavern

  • Lee Yang;Moon Hyun-Koo
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.238-243
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    • 2003
  • As there are many advantages on underground caverns, such as safety and operation, they can also be used for gas storage purpose. When liquefied gas is stored underground, the cryogenic temperature of the gas will affect the stability of the storage cavern. In order to store the liquefied gas successfully, it is essential to estimate the exact temperature distribution of the rock mass around the cavern. In this study, an analytic solution and a conceptual model that can estimate three-dimensional temperature distribution around the storage cavern are suggested. When calculating the heat transfer within a solid, it is likely to consider the solid as the intersection of two or more infinite or semi-infinite geometries. Therefore heat transfer solution for the solid is expressed by the product of the dimensionless temperatures of the geometries, which are used to form the combined solid. Based on the multi-dimensional transient heat transfer theory, the analytic solution is successfully derived by assuming the cavern shape to be of simplified geometry. Also, a conceptual model is developed by using the analytic solution of this study. By performing numerical experiments of this multi-dimensional model, the temperature distribution of the analytic solution is compared with that of numerical analysis and theoretical solutions.

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Investigation of Thermal Management Parameters of Metal Hydride Based Hydrogen Storage System (금속수소화물 기반 수소저장시스템의 열관리 인자 조사)

  • PARK, CHU SIK;KIM, JONG WON;BAE, KI KWANG;JEONG, SEONG UK;KANG, KYOUNG SOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.3
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    • pp.251-259
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    • 2018
  • Metal hydride based hydrogen storage under moderate temperature and pressure gives the safety advantage over the gas and liquid storage methods. Still solid-state hydrogen storage including metal hydride is below the DOE target level for automotive applications, but it can be adapted to stationary or miliary application reasonably. In order to develop a modular solid state hydrogen storage system that can be applied to a distributed power supply system composed of renewable energy - water electrolysis - fuel cell, the heat transfer and hydrogen storage characteristics of the metal hydride necessary for the module system design were investigated using AB5 type metal hydride, LCN2 ($La_{0.9}Ce_{0.1}Ni_5$). The planetary high energy mill (PHEM) treatment of LCN2 confirmed the initial hydrogen storage activation and hydrogen storage capacity through surface modification of LCN2 material. Expanded natural graphite (ENG) addition to LCN2, and compression molding at 500 atm improved the thermal conductivity of the solid hydrogen storage material.

Advanced SIL(A-SIL) system for Near Field Recording (A-SIL 을 이용한 근접장 저장)

  • Han, I.G.;Shin, Y.S.;Park, J.M.;Lee, J.U.;Seo, J.K.;Choi, I.H.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.1028-1030
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    • 2007
  • Mutual compensating concept between SIL(Solid Immersion Lens) and OL(Objective Lens) of NFR(Near Field Recording) is proposed, designed and manufactured to achieve a high NA and obtain a wider manufacturing tolerance. Tolerance information is present in article. An effective NA of Advanced SIL is 1.7 and adjustment between OL and SIL is carried out using our interferometer. We measured very clear RF signal using 3-axis actuator at Test bed.

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A Study on the Calculation of Minimum Safety Distance during Storage and Combustion Test of Solid Propellants for Launch Vehicles (발사체 고체추진제의 저장 및 시험 시 안전거리 산정에 관한 연구)

  • Shin, Ahn-Tae;Park, Byung-Mun;Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.180-185
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    • 2021
  • In accordance with the revision of the US-Korea missile guidelines, restrictions on the use of solid propellants for space launch vehicles have been completely lifted. The solid propellant can be used as a solid propellant rocket like the KSR-1 (Korea Sounding Rocket-1), and can also be used as a thrust augmentation booster for liquid fuel launch vehicles. It is known that solid propellants have a lower risk of explosion than liquid propellants. but if an accident such as an explosion at the Alcantara Launch Center in Brazil occurs, it can lead to a large-scale personal accident. In order to prevent such large-scale accidents, it is necessary to review and reflect the minimum safety distance during use, storage and combustion test of solid propellants from the planning phase of the project. In this paper, the minimum safety distance for safe use of the solid propellant is presented by dividing it into storage facilities and combustion tests.

Theoretical and Numerical Lens Design Using Near Field Theory for High Density Storage Device (근접장 이론을 이용한 고밀도 저장 장치용 렌즈의 이론적 설계와 수치적 설계)

  • 이문도;박재혁;박노철;박영필
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.9
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    • pp.173-179
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    • 2003
  • In optical storage device system, there are several research topics to increase its recording density. The main idea is reducing wave length of laser diode and magnifying the number of numerical aperture (NA). In conventional optical system NA cannot be over the unity in the air because of its diffraction limit. But it is possible to overcome its limitation of unity in near field using Solid Immersion Lens. In this work, the mathematical Solid Immersion Lens (SIL) design process was illustrated by using near field theory. Also, numerical SIL design parameters were calculated by means of CODE V. Through the work, we propose the new type of SIL for high density optical recording systems.

Storage Stability and Color Reproducibility of Yellow and Red Dyes Extracted from Carthamus tinctorius L.

  • Shin, Youn-Sook;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.165-172
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    • 2012
  • The stability of yellow and red dyes prepared from safflower (Carthamus tinctorius L.) in aqueous solution and in solid state was investigated. External factors such as light irradiation and temperature on the stability were examined during storage. Changes in absorbance of dye solutions and the color changes of fabrics dyed after long time storage were measured. Also, color reproducibility during storage was investigated by dyeing test on various fabrics. Red colorant in aqueous solution was very unstable to light, resulting that about 40% of absorbance were lost in 12hrs. The absorbance of yellow dye solutions was not decreased within 84hrs. In aqueous medium, yellow dye was much more stable than carthamin. Both dyes are relatively stable for long storage when they are stored in solid state compared to when in aqueous solution. Color changes are marginal in both dyes.