• Title/Summary/Keyword: Solid Oxide

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Application on Supercapacitor of Manangese Oxide Electrodes Prepared by Various Synthesis Methods (다양한 합성방법으로 제조된 망간옥사이드 전극들의 수퍼커패시터에 대한 응용)

  • 김한주;신달우;김용철;김성호;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.606-609
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    • 2000
  • We describe the preparation of a manganese oxide polymorph in which the solid-pore architecture of the material is controllably varied. All MnO$_2$ gels derived from a KMnO$\_$4/-based sol-gel synthesis. The mesoporous structure of the initial gel is maintained by removingore fluid under conditions where the capillary forces that result fro extraction are either low or no existent. are either low or noexistent. Controlling both the pore and solid architecture on the nanoscale offers a strategy for the design of supercapacitor.

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Electrical Characteristics of NVM Devices Using SPC Substrate (SPC 기판을 사용한 NVM 소자의 전기적 특성)

  • Hwang, In-Chan;Lee, Jeoung-In;Yi, J.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.60-61
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    • 2007
  • In this paper, the p-channel poly Si thin-film transistors (Poly-Si TFT's) using formed by solid phase crystallization (SPC) on glass substrate were fabricated. And we propose an ONO(Oxide-Nitride-Oxide) multilayer as the gate insulator for poly-Si TFT's to indicate non-volatile memory (NVM) effect. Poly-Si TFT is investigated by measuring the electrical properties of poly-Si films, such as I-V characteristics, on/off current ratio. NVM characteristics is showed by measuring the threshold voltage change of TFT through I-V characteristics.

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Fabrication of $TiO_2$ Blocking Layers for CuSCN Based Dye-Sensitized Solar Cells by Atomic Layer Deposition Method

  • Baek, Jang-Mi;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.310.2-310.2
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    • 2013
  • For enhancement of dye-sensitized solar cell performance, TiO2 blocking layer has been used to prevent recombination between electron and hole at the conducting oxide and electrolyte interface. In solid state dye-sensitized solar cells, it is necessary to fabricate pin-hole free TiO2 blocking layer. In this work, we deposited the TiO2 blocking layer on conducting oxide by atomic layer deposition and compared the efficiency. To compare the efficiency, we fabricate solid state dye-sensitized solar cell with using CuSCN as hole transport material. We see the efficiency improve with 40nm TiO2 blocking layer and the TiO2 blocking layer morphology was characterized by SEM. Also, we used this blocking layer in TiO2/Sb2S3/ CuSCN solar cell.

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Joining of Lanthanum Chromite and Yttria Stabilized Zirconia in Sealing of Planar Solid Oxide Fuel Cell

  • Lee, You-Kee;Park, Jong-Wan
    • Korean Journal of Materials Research
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    • v.4 no.7
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    • pp.741-749
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    • 1994
  • The planar solid oxide fuel cell(SOFC) contains several ceramic materials depending on its structure and has rdfractory metal parts for manifolds, shrouds and current leads. Among ceramic materials for planar SOFC, joining of lanthanum chromite separator and yttria stabilized zirconia(YSZ) electoyte in planar SOFC stack to give strong gas tight seals is necessary for satisfactory operation and high performance. Nevertheless, for planar SOFC/sub s/, how to seal the cell stack and gas manifold remains as one of the unsolved problems. Therefore, in this study. we investigated the joining of sintered lanthanum chromite and YSZ pellets using unsintered lanthanum chromite green films as sealent. Scanning electron microscopy(SEM) and energy dispersive X-ray analysis(EDX) revealed that Ca in the sealing material diffused and dissolved into YSZ and sintered lanthanum chromite, and unsintered lanthanum chromite green films reacted with YSZ to from a new phase at the interface. Also, the densification of unsintered lanthanum chromite green films was inpeded by the Ca migration.

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Design Performance Analysis of Solid Oxide Fuel Cell/Gas Turbine Hybrid Systems for Various Gas Turbine Pressure Ratios (가스터빈 압력비 변화에 따른 고체 산화물 연료전지/가스터빈 하이브리드 시스템의 설계 성능 해석)

  • Park, Sung-Ku;Kim, Tong-Seop
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.885-890
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    • 2006
  • This study presents analysis results for the hybrid system combining solid oxide fuel cell and gas turbine. Two different system layouts(an ambient pressure system and pressurized system) are considered and their design performance are comparatively investigated taking into account critical design factor, the most critical parameter such as turbine inlet temperature, gas turbine pressure ratio, temperature difference at the fuel cell and fuel cell operating temperature are considered as design constraints. Performance variations according to system layout and design parameters are examined in energetic view point.

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Curing Properties of HTPB-based Solid Propellants (HTPB계 고체추진제의 경화 특성에 관한 연구)

  • Su-A Jeon;Jee-Hun Ahn;Hang-seok Seo;Han-Jun Kim;Eui-yong Park
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.6
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    • pp.28-33
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    • 2022
  • In this study, the curing characteristics of commonly used Hydroxyl terminated polybutadiene(HTPB)-based solid propellant according to the curing temperature and Equivalent ratio change were investigated. In addition, the effect of curing reaction according to their ratio and content in the Triphenyl bismuth(TPB), Maleic anhydride(MA) and Magnesium oxide(MgO) catalyst systems was confirmed. Finally, moisture was added for each propellant mixing process to check the effect of moisture on propellant curing.

The Effect of the Anode Thickness on Electrolyte Supported SOFCs

  • So Yeon Shin;Dae-Kwang Lim;Taehee Lee;Sang-Yun Jeon
    • Journal of Electrochemical Science and Technology
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    • v.14 no.2
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    • pp.145-151
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    • 2023
  • Planer-type electrolyte substrates are often utilized for stack manufacturing of electrolyte-supported solid oxide fuel cells (ES-SOFCs) to fulfill necessary requirements such as a high mechanical strength and redox stability. This work did an electrochemical analysis of ES-SOFC with different NiO-YSZ anode thicknesses to find the optimal value for the high performance of the fuel cell. The cell resistivities were constant at anode thickness between 25-58 ㎛, but a thick anode (74 ㎛) caused a high electrode resistivity leading to a dramatic reduction in cell performance. A stability test was performed for 50 hours at 700℃, and the results showed a degradation rate of 0.3% per 1000 h by extrapolated fitting.

A Review on Performance Prediction of Marine Fuel Cells (선박용 연료전지 성능 예측 방법에 관한 고찰)

  • EUNJOO PARK;JINKWANG LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.4
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    • pp.437-450
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    • 2024
  • Sustainable shipping depends on eco-friendly energy solutions. This paper reviews methods for predicting marine fuel cell performance, including empirical approaches, physical modeling, data-driven techniques, and hybrid methods. Accurate prediction models tailored to the marine environment's unique conditions are crucial for operational efficiency. By evaluating the strengths and weaknesses of each method, this study provides a comprehensive analysis of effective strategies for forecasting polymer electrolyte membrane fuel cell and solid oxide fuel cell performance in marine applications. These insights contribute to the advancement of eco-friendly shipping technologies and enhance fuel cell performance in challenging marine environments.

Densification of Cu-50%Cr Powder Compacts and Properties of the Sintered Compacts (Cu-50%Cr 분말성형체의 치밀화 및 소결체 물성)

  • 김미진;정재필;도정만;박종구;홍경태
    • Journal of Powder Materials
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    • v.7 no.4
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    • pp.218-227
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    • 2000
  • It is well known that the Cu-Cr alloys are very difficult to be made by conventional sintering methods. This difficulty originates both from limited solubility of Cr in the Cu matrix and from limited sintering temperature due to high vapor pressures of Cr and Cu components at the high temperature. Densification of Cu-50%Cr Powder compacts by conventional Powder metallurgy Process has been studied. Three kinds of sintering methods were tested in order to obtain high-density sintered compacts. Completely densified Cu-Cr compacts could be obtained neither by solid state sintering method nor by liquid phase sintering method. Both low degree of shrinkage and evolution of large pores in the Cu matrix during the solid state sintering are attributed to the anchoring effect of large Cr particles, which inhibits homogeneous densification of Cu matrix and induces pore generation in the Cu matrix. In addition, the effect of undiffusible gas coming from the reduction of Cu-oxide and Cr-oxide was observed during liquid phase sintering. A two-step sintering method, solid state sintering followed by liquid phase sintering, was proved to have beneficial effect on the fabrication of high-dendsity Cu-Cr sintered compacts. The sintered compacts have properties similar to those of commercial products.

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Electrolyte Preparation and Characteristics of La1-xSrxMnO3 for Solid Oxide Fuel Cell (고체전해질형 연료전지용 전해질 제작 및 La1-xSrxMnO3의 특성에 관한 고찰)

  • Rim, Hyung-Ryul;Lee, Ju-Seong
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.9-17
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    • 1996
  • Solid oxide electrolytes of 8mol% YSZ($Y_2O_3$ stabilized zirconia) were prepared at various sintering conditions and their ionic conductivities were measured. The highest ionic conductivity of $10^{-1}S.cm^{-1}$ was obtained when the sintering temperature was 1400oC and the sintering time was 10hr. Also the cathode material, $La_{1-x}Sr_xMnO_3$ was prepared by solid state reaction method and the overpotential, electrical conductivity, and charge transfer resistance between cathode material and YSZ electrolyte were studied. It was found that the optimum doping content of Sr for La was 50mo1%.

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