• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.11a
• /
• pp.215-218
• /
• 2007

Internal Ballistic modeling and performance prediction for solid propellant micro thruster was performed with heat loss to the chamber wall as an important factor of miniaturization. Simple l-D end-burner type thruster and general HTPB-AP type composite propellant were selected for computation model. The results showed that the performance loss with the heat loss to the surroundings becomes larger as the surface-to-volume ratio is increased. In this case, the total impulse was reduced about 3% of the case in adiabatic condition.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.23 no.2
• /
• pp.78-86
• /
• 2019

Aluminum, which is a metal fuel contained in the composite solid propellant, is not ignited and burned on the combustion surface by the oxide film, and it partially melts and coalesces with surrounding aluminum particles. For the evaluation and design of the propellant performance, modeling was performed to predict the size and distribution of agglomerated particles, and the size and distribution of agglomerates were compared and verified through experiment. The predicted values showed the tendency to decrease with pressure as in the experiment, but the error increased as the pressure increased. The agglomerated particle distribution graph showed a difference in the volume fraction although the diameter at the peak was the same.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.8
• /
• pp.2257-2262
• /
• 2014

$C_{60}$ is widely investigated because of its unique structure. But its applications in solid propellant seem to be relatively neglected. $C_{60}$ has more outstanding features than carbon black which is widely used as a catalyst ingredient of solid propellant. To combine the advantages of fullerene and lead salts, another good composite in propellant catalysts, we synthesized a kind of fullerene phenylalanine lead salt (FPL) and explored its thermal performances by differential thermal analysis (DTA) and thermogravimetry analysis (TGA). The results show it undergoes four exothermic processes started from 408 K. Combined TGA and X-ray diffractometer (XRD), the decomposition mechanism of FPL was derived by TG-IR and comparing IR spectra of FPL and its residues after burned to $327^{\circ}C$, $376^{\circ}C$ and $424^{\circ}C$, respectively. Effect of FPL on the decomposition characteristic of hexogen (RDX), a type of explosive in propellant, has been investigated using DTA at different heating rate, which shows the decomposition temperatures of the explosive are all reduced by more than 20 K. The corresponding activation energy ($E_a$) is decreased by $30kJ{\cdot}mol^{-1}$. So FPL has potential application as a combustion catalyst in solid propellant.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2007.04a
• /
• pp.225-228
• /
• 2007

The objective of this study is to characterize design parameters of rocket igniters for composite, double base and nitramine propellant. Arc image furnace and fiber optics surface reflectometer were used to measure ignition delay time and reflected optical energy of several compositions of composite, double base and nitramine base rocket propellant at different pressure levels each other. The order of ignitability was double base > composite > Nitramine propellants at initial pressure of over 75 psia. The highest ignition energy was needed to ignite nitramine propellant, however, as the pressure increased up to the range of $75{\sim}400$ psia as the ignition delay time decreased abruptly. The absorbtion of radiation energy could be increased by the addition of small amount of opacifiers as carbon black, ZrC, WC and burning catalyst.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2006.11a
• /
• pp.247-250
• /
• 2006

In the previous study, we have developed an ultrasonic measurement system and analysis technique for borning rate testing of solid propellants using ultrasound. And then, using the developed system, burning rate of composite propellants were measured. So, in this study, we performed measurement of double base solid propellant, which has non-linear homing rate as pressure increasing, using the developed system in order to evaluate capability of ultrasonic method. Furthermore, accuracy of measured homing rates using ultrasound was verified by comparison to homing rate measured by the strand burner method.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2006.05a
• /
• pp.383-386
• /
• 2006

Several HTPB/AP and HTPB/AP/HMX propellants were investigated experimentally for ignition characteristics in subatmospheric pressure. The threshold ignition pressure was 4psia for HTPB/AP composite propellant. The partial replacement of AP in HTPB/AP composite propellant by $5\sim15%$ of HMX, HNIW showed improvements in the threshold pressure was below 0.4psia. This appears to be due to the exothermic dissociation characteristics of HMX and HNIW at lower temperature $(\sim220^{\circ}C)$ than that of AP. The ignition substance B/KNO3 was coated thinly on the propellant surface for better ignition effect. As a result, ignition delay time of 15% was improved. NC is applied to $B/KNO_3$ ignition substance as a secondary binder and $NC-B/KNO-3$ suspension solution is coated to the propellant surface.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.10 no.3
• /
• pp.67-72
• /
• 2006

Several propellants were investigated experimentally for ignition characteristics in subatmospheric pressure. The threshold ignition pressure was 4 psia for HTPB/AP composite propellant. The partial replacement of AP in HTPB/AP propellant by $5{\sim}l5%$ of HMX, HNIW showed that the improvements in ignition delay was over 50% and the threshold pressure was below 0.4 psia. This appears to be due to the characteristics of HMX and HNIW exothermic dissociated at the temperature(${\sim}220^{\circ}C$) love. than that of AP. The ignition substance $B/KNO_3$ was coated thinly on the propellant surface for better ignition performance. As a result, ignition delay time of 15% was improved. NC is applied to $B/KNO_3$ ignition substance as a secondary binder and $NC-B/KNO_3$ suspension solution is coated to the propellant surface.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.20 no.1
• /
• pp.14-19
• /
• 2016

The viscosity and mechanical property of HTPB/AP composite solid propellant are profoundly affected by particle size of AP. In HTPB/AP propellant formulated by two mode of AP size such as $190{\mu}m$ and $7{\mu}m$, the propellant was found to be much less viscose at end of mix when coarse/fine AP ratio is ranged from 70/30 to 60/40 due to high solid packing fraction. It was shown that the toughness of tensile strength test for HTPB/AP propellant increased with the increase in coarse AP. Considering both lower viscosity and better tensile strength, the optimum ratio of AP coarse/fine was estimated to be 70/30.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.24 no.6
• /
• pp.101-107
• /
• 2020

In this paper, step-curing, which includes the change of curing temperature on the curing process, was applied to reduce curing day of HTPB/AP based propellant. This study targets the improvement of productivity of HTPB/AP based solid rocket motor. Comparison of mechanical properties of propellant resulted in the change of normal curing condition (60℃, 5 days) to step-curing condition (60℃, 1 day / 65℃, 3 days). Post-cure test was conducted to determine the impact on the shelf life of the solid rocket motor. The aging characteristics of propellants were analyzed by measuring mechanical properties and thermal expansion factor. To step-cured propellant, accelerated aging test was performed for 12 weeks, followed by tensile test. Sm(bar) and Em(%) were higher than 8 bar and 40% each, showing excellent mechanical properties.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.6 no.1
• /
• pp.30-38
• /
• 2002

Bullet impact tests for two solid rocket motors were performed and its results were compared and analyzed. One was loaded with the existing propellant with decreased weight content of burning rate catalyst and added high density additives to improve mechanical properties and the other was loaded with the existing propellant with decreased weight content of burning rate catalyst to improve its insensitivity as well as to maintain the ballistic performance. The composite cases were used for both motors.