• Rapid Communication in Photoscience
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• v.4 no.4
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• pp.82-85
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• 2015

Photoelectrochemical cell (PEC) is one of the attractive ways to produce clean and renewable energy. However, solar to hydrogen production via PEC system generally requires high external bias, because of material's innate electronic band potential relative to hydrogen reduction potential and/or charge separation issue. For spontaneous photo-water splitting, here, we design dye-sensitized solar cell (DSSC) and their monolithic tandem cell incorporated with a $BiVO_4$ photoanode. $BiVO_4$ has high conduction band edge potential and suitable band gap (2.4eV) to absorb visible light. To achieve efficient $BiVO_4$ photoanode system, electron and hole mobility should be improved, and we demonstrate a tandem cell in which $BiVO_4/WO_3$ film is connected to cobalt complex based DSSC.

• Korean Journal of Materials Research
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• v.18 no.11
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• pp.571-576
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• 2008

The simulation program for solar cells, PC1D, was briefly reviewed and the device modeling of a multicrystalline Si solar cell using the program was carried out to understand the internal operating principles. The effects of design parameters on the light absorption and the quantum efficiency were investigated and strategies to reduce carrier recombination, such as back surface field and surface passivation, were also characterized with the numerical simulation. In every step of the process, efficiency improvements for the key performance characteristics of the model device were determined and compared with the properties of the solar cell, whose efficiency (20.3%) has been confirmed as the highest in multicrystalline Si devices. In this simulation work, it was found that the conversion efficiency of the prototype model (13.6%) can be increased up to 20.7% after the optimization of design parameters.

• Current Photovoltaic Research
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• v.5 no.1
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• pp.9-14
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• 2017

The screen printing technique is one of process to form electrode for crystalline silicon solar cell and has been studied a lot, because it has many advantages such as low price, high efficiency and mass production due to simple and fast process. The reason why electrode formation is important is for influence of series resistance and amount of incident light in crystalline silicon solar cell. In this study, electrode was formed by screen printing method with various conditions like squeegee angle, printing speed, snap off, printing pressure. After optimizing various conditions, double printing method was applied to obtain low series resistance and high aspect ratio. As a result, we obtained electrode resistance 45.31 ohm, aspect ratio 4.38, shading loss 7.549% mono-crystalline silicon solar cell with optimal double screen printing condition.

• Clean Technology
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• v.19 no.3
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• pp.191-200
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• 2013

Researches on developing photocatalyst materials for hydrogen production from solar water splitting attract great attentions due to the unlimited and clean characteristics of the solar energy. In this review, photocatalysts used for hydrogen production from the solar water splitting are discussed in terms of material characteristics. In addition, various modification techniques applied to the photocatalysts for improving hydrogen production efficiency are summarized. Finally, light characteristics such as intensity, illumination density and wavelength cutoff are also discussed for the importance of hydrogen production rate.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.7
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• pp.408-413
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• 2016

The dielectric thin films applied to multi-colored semitransparent thin film solar cells have been extensively studied. In this work, we prepared GeSbTe and GeTe chalcogenide thin films using magnetron sputtering, and investigated their optical and phase-change properties to replace the dielectric films. The changes of surface morphology, sheet resistance, and X-ray diffraction of the Te-based chalcogenide films support the fact that the amorphous stability of GeTe films is superior to that of GeSbTe films. While both amorphous GeSbTe and GeTe films thinner than 30 nm have optical transparency between 5% and 60%, GeTe films transmit more visible light than GeSbTe films. It is confirmed by computer simulation that the color of semitransparent silicon thin film solar cells can be adjusted with the addition of GeSbTe or GeTe films. Since it is possible to adjust the contrast of the solar cells by exploiting the phase-change property, the two kinds of chalcogenide films are anticipated to be used as an optical layer in semitransparent solar cells.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.2
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• pp.114.1-114.1
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• 2012

To measure the magnetic field strength in the solar corona, we examined 10 fast (>1000 km/s) limb coronal mass ejections (CMEs) that show clear shock structures in Solar and Heliospheric Observatory/Large Angle and Spectrometric Coronagraph images. By applying the piston-shock relationship to the observed CME's standoff distance and electron density compression ratio, we estimated the Mach number, Alfven speed, and magnetic field strength in the height range 3-15 solar radii (Rs). The main results from this study are as follows: (1) the standoff distance observed in the solar corona is consistent with those from a magnetohydrodynamic model and near-Earth observations; (2) the Mach number as a shock strength is in the range 1.49-3.43 from the standoff distance ratio, but when we use the density compression ratio, the Mach number is in the range 1.47-1.90, implying that the measured density compression ratio is likely to be underestimated owing to observational limits; (3) the Alfven speed ranges from 259 to 982 km/s and the magnetic field strength is in the range 6-105 mG when the standoff distance is used; (4) if we multiply the density compression ratio by a factor of two, the Alfven speeds and the magnetic field strengths are consistent in both methods; and (5) the magnetic field strengths derived from the shock parameters are similar to those of empirical models and previous estimates.

• Journal of the Korean Solar Energy Society
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• v.22 no.3
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• pp.57-65
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• 2002

The photocatalytic degradation of TCE using solar energy in POFR was studied. The use of solar energy was investigated in plastic optica fiber photocatalytic reactor (POFR). In POFR, the main parameters of photocatalytic degradation of TCE were lihgt intensity, thickness of $TiO_2$-coated film on plastic fiber core, the same of total $TiO_2$-coated surface area with changed length. We studied the apparent photonic efficiency and photocatalytic degradation rate of TCE in POFR. The apparent photonic efficiency of various light intensities was decreased by an incresed intensities. The photocatalytic activities of $TiO_2$-coated optical fiber reactor system depended on the coating thickness, and total clad-stripped surface area of POF. Photocatalytic degradation of trichloroethylene ($C_2HCl_3$, TCE) in the gas-phase was elucidated by using $TiO_2$-coated plastic optical fiber reactor. In TCE degradation, in-situ FTIR measurement resulted in mineralization into $CO_2$.

• 한국태양에너지학회:학술대회논문집
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• 2009.11a
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• pp.383-387
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• 2009

Multi-crystalline silicon surface etching without grain-boundary delineation is a challenging task for the fabrication of high efficiency solar cell. The use of sodium hydroxide - sodium hypochlorite (NaOH40% + NaOCl 12%) solution for texturing multi-crystalline silicon wafer surface in solar cell fabrication line is reported in this article. in light current-voltage results, the cells etched in NaOH 40% + NaOCl 12% = 1:2 exhibited higher short circuit current and open circuit voltage than those of the cells etched in NaOH 40% + NaOCl 12% = 1:1 solution. we have obtained 15.19% conversion efficiency in large area(156cm2) multi-Si solar cells etched in NaOH 40% + NaOCl 12% = 1:1 solution.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.61 no.5
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• pp.705-710
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• 2012

An anti-reflection layer (AR) is used in the solar cell to improve the amount of the irradiated light, resulting in the improvement of the performance of the solar cell. In this study, the zinc oxide (ZnO) AR is applied to the dye-sensitized solar cell (DSC) by using zinc nitrate solution. The conditions such as solution concentration and sintering temperature for fabricating the ZnO AR are changed to optimize the performance of the AR. As a result, the best performance is shown when the zinc nitrate solution with 100mM concentration is used and the sintering temperature is $600^{\circ}C$. And then, the ZnO AR formed with these optimal conditions is applied to the DSC. Consequently, a DSC with a ZnO AR had an increased current density up to 13.86$mA/cm^2$ and an enhanced efficiency of 6.32%.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2004.04a
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• pp.31-34
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• 2004

During the last 20 years organic semiconductors have attracted considerable attention due to their interesting physical properties followed by various technological applications in the area of electronics and opto-electronics. It has been a long time since organic solar cells were expected as a low-cost energy-conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerine$(C_{60})$ as electron acceptor(A) with doped charge transport layers, $Alq_3$ as an electron transport or injection layer. We observed the photovoltaic characteristics of the solar celt devices using the Xe lamp as a light source.