• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.4
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• pp.366-371
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• 2022

Recently many efforts have been made to develop a novel class of non-fullerene electron acceptor materials for high-performance organic solar cells. In this work, anthraquinone derivatives, TMAQ and THAQ, were prepared and their availability as electron acceptor materials for organic solar cells were investigated in terms of optical, thermal, electrochemical properties, and solar cell devices. Compared to TMAQ, a significant bathochromic shift of absorption band was observed for THAQ owing to intramolecular hydrogen-bond-assisted CT interactions. Thanks to the fused aromatic ring structure and benzoquinone unit, both TMAQ and THAQ exhibited a high thermal stability and an efficient electron reduction process. In particular, the intramolecular O-H---O=C hydrogen bond of THAQ plays an important role in improving the thermal stability and electron reduction properties. In the P3HT:acceptor solar cell system, THAQ-based devices had more than ca. 6 times higher power conversion efficiency than TMAQ -based devices. These results serve as a guide for developing high-efficient anthraquinone-based electron acceptor materials.

• Journal of the Korea Institute of Military Science and Technology
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• v.27 no.1
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• pp.8-14
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• 2024

In this study, the scale of renewable photovoltaic(PV) panels and hydrogen fuel storage facilities required to achieve "net zero carbon emissions" in military facilities were predicted based on actual electricity consumption. It was set up to expect the appropriate installation size of PV panel and hydrogen fuel storage facility for achieving carbon neutrality, limited to the electricity consumption in the public sector, including national defense and social security administration in Yeongcheon. The experimental results of this paper are largely composed of two parts. First, representative meteorological factors were considered to predict solar power generation in the Yeongcheon area, and solar power generation was estimated through a multiple regression model using deep learning techniques. Second, the size of solar power generation facilities and hydrogen storage facilities in military bases was estimated with the amount of solar power generation and electricity consumption. As a result of this analysis, it was calculated that a site of 155.76×104 m² for PV panels was needed and a facility capable of storing 27,657 kg of hydrogen gas was required. Through these results, it is meaningful to demonstrated the prospect that military units can lead the achievement of "carbon net zero 2050" by using PV panels and hydrogen fuel storage facilities on idle sites of military bases.

• Journal of Hydrogen and New Energy
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• v.18 no.2
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• pp.151-156
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• 2007

Solar cell and nanofiltration membrane were utilized in a system of enzymatic hydrogen production through light-sensitized photoanode, which resembles photoelectrochemical(PEC) configuration. Solar cell uses no additional light energy to increase energy for electrons to reduce protons and for holes to oxidize water to oxygen, and nanofiltration membrane replaces a salt bridge successfully with increased ion transport capability. With this system configuration, optimized amount of enzyme(10.98 unit), and an anodized tubular $TiO_2$ electrode($5^{\circ}C$/1 hr in 0.5 wt% HF-$650^{\circ}C$/5 hr) hydrogen evolved at a rate of ca. $43\;{\mu}mol/(cm^2{\times}hr)$ in a cathodic compartment and oxygen generated at a rate of ca. $20\;{\mu}mol/(cm^2{\times}hr)$ in an anodic compartment. The stoichiometric evolution of gases indicated that water was splitted in the system.

• 한국태양에너지학회:학술대회논문집
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• 2011.11a
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• pp.169-176
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• 2011

The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

• Journal of Hydrogen and New Energy
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• v.26 no.4
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• pp.331-338
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• 2015

Solar air heaters (SAHs) are simple in design and widely used for solar energy collection devices, and a packed bed is one of typical solar energy storage systems of thermal energy captured by SAHs. This paper presents mathematical modeling and simulation on the thermal performance of various packed bed energy storage systems. A MATLAB program is used to estimate the thermal efficiency of packed bed SAH. Among the various packed bed energy storage systems considered, the wire mesh screen packed bed SAH shows the best thermal efficiency over the entire range of design conditions. The maximum of thermal efficiency of packed bed SAH with wire mesh screen matrices has been found to be 0.794 for Re=2000 - 20000 and ${\Delta}T/I=0.002-0.02$.

• Proceedings of the KIEE Conference
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• 2005.04a
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• pp.274-276
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• 2005

This paper present an effective modeling scheme of SPE cell system for hydrogen production. As oxygen and hydrogen produced by water electrolysis using SPE are high purity, we can use oxygen in biomedical and hydrogen could be used in many ways. Recently, it is under the eye as a surplus power storage system. PSCAD/EMTDC model of SPE cell system for hydrogen production to efficiently utilize solar cell energy is showed in this paper. The simulated results are then verified by comparing them with the actual values obtained from the data acquisition system. Authors are sure that it is a useful method to the researchers who study SPE cell system for hydrogen production.

• Journal of the Korean Society of Industry Convergence
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• v.27 no.2_1
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• pp.277-285
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• 2024

Hydrogen is considered a key energy source to achieve carbon neutrality through the global goal of 'net zero'. Due to limitations in producing green hydrogen domestically, Korean companies are interested in importing green hydrogen produced overseas. The Middle East has high-quality solar energy resources and is attracting attention as a region producing green hydrogen using renewable energy. To build a green ammonia plant, optimization of the production facility configuration and economic feasibility analysis are required. It is expected that it will contribute to reviewing the economic feasibility of constructing overseas hydrogen production plants through preliminary economic feasibility analysis.

• Journal of Hydrogen and New Energy
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• v.22 no.6
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• pp.942-948
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• 2011

The performance of a supercharger for vehicle using solar cell attached on the exterior of a car, an auxiliary battery, and an air compressor was evaluated in this study. This supercharger is composed of a solar cell of 40W, a battery of 60 Ah, an air compressor of 17 A, 8 $kgf/cm^2$ and an air tank of 8L. It takes about 6 days to charge the battery with the solar cell and the high pressure air of 8L can be supplied about 70 times to engine intake with this battery. The intake pressure increased by about 20~40% with this supercharger. The vehicle power and accelerating performance are enhanced by 87% and 50% each in the low speed range. But the performance improved little in the high speed range because of the rather constant flow rate of air supplied by this type of supercharger.

• Journal of Hydrogen and New Energy
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• v.15 no.4
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• pp.324-332
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• 2004

According to the rapid depletion of the fossil fuels, the electricity and hydrogen will gradually take charge of the future energy supply. Especially, in order to control the supply and demand of electricity, energy storage medium is necessary and this could be solved by the combination of water electrolysis and fuel cell. Although electricity can be generated from such alternative energies as hydropower, nuclear, solar, and wind-power resources, alternative energy storage medium is also required since regenerative energies, solar and wind-powers, are intermittent energy resources. In this regard, hydrogen production from water electrolysis was recognized as a superb method for electricity storage. In this work, the current development and economic status of alkaline, solid polymer, and high temperature electrolysis were reviewed, and then the practical use of water electrolysis technology were discussed.

• Journal of Electrochemical Science and Technology
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• v.3 no.4
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• pp.149-153
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• 2012

Among the various solar-hydrogen production techniques a combination of a photovoltaic (PV) and an electrolytic cell into one single system, a monolithic PV-electrolytic cell, has been suggested as a promising one in terms of efficiency and stability. In this mini-review, we describe our recent efforts on the fabrication of the monolithic PV-electrolytic cell. Particularly, we focus on the electrocatalysts for water oxidation and its fabrication method suitable for a monolithic PV-electrolytic cell. We also introduce proto-type devices with a dye-sensitized solar cell module and an InGaP/GaAs photoelectrodes.