• Journal of Electrochemical Science and Technology
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• v.4 no.3
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• pp.89-92
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• 2013

Poly (3,4-ethylenedioxythiophene) (PEDOT) polymers with different electric conductivities were synthesized directly on a FTO substrate via a chemical polymerization method and applied as a platinum (Pt)-free counter electrode for dye-sensitized solar cells (DSSCs). The catalytic properties of the PEDOT as a function of electrical conductivity were studied using cyclic voltammograms, J-V measurements and impedance spectroscopy. The PEDOT counter electrode with around 340 S/cm conductivity exhibited the best performance as a counter electrode for tri-iodide reduction. The ability to modulate catalytic activity of PEDOT with changes in conductivity shows one of promising routes for developing new counter electrode of Pt-free DSSCs.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.2
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• pp.85.1-85.1
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• 2011

The magnetic field at the surface of the Sun is concentrated in magnetic features that often have spatial extents of 100 km or less. The study of the fine scale structure of the Sun's magnetic field has been hampered by the limited spatial resolution of the available observations. This has recently changed thanks to various new high-resolution facilities, among them the SUNRISE observatory, built around the largest solar telescope to leave the ground, and containing two science instruments. SUNRISE successfully had its first long-duration science flight on a stratospheric balloon in June 2009 and a host of scientific results have been obtained from the data. After a brief introduction to the Sunrise mission, an overview of selected results obtained so far will be given. A reflight at higher solar activity is currently being prepared.

• Carbon letters
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• v.8 no.3
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• pp.214-224
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• 2007

The field of photocatalysis is one of the fastest growing areas both in research and commercial fields. Titanium dioxide is the most investigated semi-conductor material for the photocatalysis applications. Research to achieve $TiO_2$ visible light activation has drawn enormous attentions because of its potential to use solar light. This paper reviews the attempts made to extend its visible photocatalytic activity by carbon doping. Various approaches adopted to incorporate carbon to $TiO_2$ are summarized highlighting the major developments in this active research field. Theoretical features on carbon doping are also presented. Future scenario in the rapidly developing and exciting area is outlined for practical applications with solar light.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.276.2-276.2
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• 2016

Dye-sensitized solar cells (DSCs) are promising candidates for light-to-energy conversion devices due to their low-cost, easy fabrication and relative high conversion efficiency. An important component of DSCs is counter electrode (CE) collect electrons from external circuit and reduct I3- to I-. The conventional CEs are thermally decomposed Pt on fluorine-doped tin oxide (FTO) glass substrates, which have shown excellent performance and stability. However, Pt is not suitable in terms of cost effect. In this report, we demonstrated that nickel sulfide thin films by atomic layer deposition (ALD)-using Nickel(1-dimethylamino-2-methyl-2-butanolate)2 and hydrogen sulfide at low temperatures of $90-200^{\circ}C$-could be good CEs in DSCs. Notably, ALD allows the thin films to grow with good reproducibility, precise thickness control and excellent conformality at the angstrom or monolayer level. The nickel sulfide films were characterized using X-ray photoelectron spectroscopy, scanning electron microscopy, X-ray diffraction, hall measurements and cyclic voltammetry. The ALD grown nickel sulfide thin films showed high catalytic activity for the reduction of I3- to I- in DSC. The DSCs with the ALD-grown nickel sulfide thin films as CEs showed the solar cell efficiency of 7.12% which is comparable to that of the DSC with conventional Pt coated counter electrode (7.63%).

• The Korean Journal of Pesticide Science
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• v.15 no.2
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• pp.87-96
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• 2011

To study solar activated insecticide, three types of dihydroxyl phosphorus(V) triazatetrabenzocorrole derivatives ($P(OH)_2TBCs$) including H, 4'-methoxy phenoxy, 4'-tert butyl phenoxy substituents were synthesized. The results show that slightly red-shift with introducing substituents was observed and singlet oxygen was generated by the sunlight. Based on photochemical properties, solar activated insecticidal activity tests against Liriomyza trifolii (Burgess) were carried out. Overall insecticidal activities were 100~85.7% in the concentration of 500ppm, and especially in the case of compound $P(OH)_2TBC$ the insecticidal activities was 100%.

• Journal of Astronomy and Space Sciences
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• v.17 no.2
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• pp.241-248
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• 2000

A groung Fabry-Perot interferometer has been used to measure atomic oxygen nightglow (OI 630.0nm) from the thermosphere (about 250km) at King Sejong station (KSS, geographic: $62.22^{\circ}$S, $301.25^{\circ}$E; geomagnetic: $50.65^{\circ}$S, $7.51^{\circ}$E), Antarctica. While numerous studies of the thermosphere have been performed on high latitude using ground-based Fabry-Perot interferometers, the thermospheric measurements in the Southern Hemisphere are relatively new and sparse. Therefore, the nightglow measurements at KSS play an important role in extending the thermospheric studies to the Southern Hemisphere. In this study, we investigated the effects of the geomagnetic and solar activities on the thermospheric neutral temperatures that have been observed at KSS in 1989 and 1997. The measured average temperatures are 1400K in 1989 and 800K in 1997, reflecting the influence of the solar activity. The measurements were compared with empirical models, MSIS-86 and semi-empirical model, VSH.

• Journal of The Korean Astronomical Society
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• v.35 no.3
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• pp.151-157
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• 2002

From the data of solar wind observation by ACE spacecraft orbiting the Earth-Sun Lagrangian point, we selected 48 forward interplanetary shocks(IPSs) occurred in 2000, maximum solar activity period. Examining the profiles of solar wind parameters, the IPSs are classified by their shock drivers. The significant shock drivers are the interplanetary coronal mass ejection(ICME) and the high speed stream(HSS). The IPSs driven by the ICMEs are classified into shocks driven by magnetic clouds and by ejectas based on the existence of magnetic flux rope structure and magnetic field strength. Some IPSs could be formed as the blast wave by the smaller energy and shorter duration of shock drivers such as type II radio burst. Out of selected 48 forward IPSs, $56.2\%$ of the IPSs are driven by ICME, $16.7\%$ by HSS, and $16.7\%$ of the shocks are classified into blast-wave type shocks. However, the shock drivers of remaining $10\%$ of the IPSs are unidentified. The classification of the IPSs by their driver is a first step toward investigating the critical magnitudes of the IPS drivers commencing the magnetic storms in each class.

• Journal of Environmental Science International
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• v.30 no.1
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• pp.57-67
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• 2021

Photocatalytic green energy H2 production utilizing inexhaustible solar energy has been considered as a potential solution to problems of energy scarcity and environmental contamination. However, the design of a cost-effective photocatalyst using simple synthesis methodology is still a grand challenge. Herein, a low-cost transition metal, Cu-loaded one-dimensional TiO2 nanorods (Cu/TNR) were fabricated using an easy-to-use synthesis methodology for significant H2 production under simulated solar light. X-ray photoelectron spectral studies and electron microscopy measurements provide evidence to support the successful formation of the Cu/TNR catalyst under our experimental conditions. UV-vis DRS studies further demonstrate that introducing Cu on the surface of TNR substantially increases light absorption in the visible range. Notably, the Cu/TNR catalyst with optimum Cu content, achieved a remarkable H2 production with a yield of 39,239 µmol/g after 3 h of solar light illumination, representing 7.4- and 27.7-fold enhancements against TNR and commercial P25, respectively. The notably improved H2 evolution activity of the target Cu/TNR catalyst was primarily attributed to its excellent separation and efficiently hampered recombination of photoexcited electron-hole pairs. The Cu/TNR catalyst is, therefore, a potential candidate for photocatalytic green energy applications.

• Journal of The Korean Astronomical Society
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• v.37 no.1
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• pp.41-53
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• 2004

It has been a big mystery what drives filament eruptions and flares. We have studied in detail an X1.8 flare and its associated filament eruption that occurred in NOAA Active Region 9236 on November 24,2000. For this work we have analyzed high temporal (about 1 minute) and spatial (about 1 arcsec) resolution images taken by Michelson Doppler Imager (MDI) onboard the Solar and Heliospheric Observatory, Hoc centerline and blue wing ($-0.6{\AA}$) images from Big Bear Solar Observatory, and 1600 ${\AA}$ UV images by the Transition Region and Corona Explorer (TRACE). We have found that there were several transient brightenings seen in H$\alpha$ and, more noticeably in TRACE 1600 ${\AA}$ images around the preflare phase. A closer look at the UV brightenings in 1600 ${\AA}$ images reveals that they took place near one end of the erupting filament, and are a kind of jets supplying mass into the transient loops seen in 1600 ${\AA}$. These brightenings were also associated with canceling magnetic features (CMFs) as seen in the MDI magnetograms. The flux variations of these CMFs suggest that the flux cancellation may have been driven by the emergence of the new flux. For this event, we have estimated the ejection speeds of the filament ranging from 10 to 160 km $s^{-1}$ for the first twenty minutes. It is noted that the initiation of the filament eruption (as defined by the rise speed less than 20 km $s^{-1}$) coincided with the preflare activity characterized by UV brightenings and CMFs. The speed of the associated LASCO CME can be well extrapolated from the observed filament speed and its direction is consistent with those of the disturbed UV loops associated with the preflare activity. Supposing the H$\alpha$/UV transient brightenings and the canceling magnetic features are due to magnetic reconnect ion in the low atmosphere, our results may be strong observational evidence supporting that the initiation of the filament eruption and the preflare phase of the associated flare may be physically related to low-atmosphere magnetic reconnection.

• Journal of Astronomy and Space Sciences
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• v.21 no.4
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• pp.315-328
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• 2004

In this paper, we present a good example of extreme solar and geomagnetic activities from October to November, 2003. These activities are characterized by very large sunspot groups, X-class solar flares, strong particle events, and huge geomagnetic storms. We discuss ground-based and space-based data in terms of space weather scales. Especially, we present several solar and geomagnetic disturbance data produced in Korea : sunspots, geo-magnetograms, aurora, Ionogram, and Total Electron Content (TEC) map by GPS data. Finally, we introduce some examples of the satellite orbit and communication effects caused by these activities; e.g., the disturbances of the KOMPSAT-1 operational orbit and HF communication.