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Studies on the Solar Activated Insecticidal Activities of Dihydroxyl Phosphorus(V) Triazatetrabenzocorrole Derivatives  

Oh, Hyun-Chul (Department of Industrial Chemistry, Sangmyung Univ.)
Woo, Je-Wan (Department of Industrial Chemistry, Sangmyung Univ.)
Publication Information
The Korean Journal of Pesticide Science / v.15, no.2, 2011 , pp. 87-96 More about this Journal
Abstract
To study solar activated insecticide, three types of dihydroxyl phosphorus(V) triazatetrabenzocorrole derivatives ($P(OH)_2TBCs$) including H, 4'-methoxy phenoxy, 4'-tert butyl phenoxy substituents were synthesized. The results show that slightly red-shift with introducing substituents was observed and singlet oxygen was generated by the sunlight. Based on photochemical properties, solar activated insecticidal activity tests against Liriomyza trifolii (Burgess) were carried out. Overall insecticidal activities were 100~85.7% in the concentration of 500ppm, and especially in the case of compound $P(OH)_2TBC$ the insecticidal activities was 100%.
Keywords
Dihydroxyl phosphorus(V) triazatetrabenzocorroles; aggregation; singlet oxygen; Liriomyza trifolii (Burgess); solar activated insecticide;
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