• Geomechanics and Engineering
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• v.31 no.2
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• pp.149-158
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• 2022

Ladle furnace (LF) slag, waste from the steel-making process, was incorporated to improve the compressive strength of soil cement. LF slag was mixed to replace the cement in the soil-cement samples with wt% ratio 20:0, 15:5, and 10:10 of cement and slag, respectively. LF slag in the range of 5, 10, and 20 wt% was also separately added to the 20-wt% cement-treated soil samples. The soil-cement mixed LF slag samples were incubated in a plastic wrapping for 7, 14, and 28 days. The strength of soil cement was highly developed to be higher than the standard acceptable value (0.6 MPa) after incorporating slag into soil cement. The mixing of LF slag resulted in more hydration products for bonding soil particles, and hence improved the strength of soil cement. With the LF slag mixing either a replacement or additive materials in soil cement, the LF slag to cement ratio is considered to be less than 1, while the cement content should be more than 10 wt%. This is to promote a predominant effect of cement hydration by preventing the partially absorbed water on slag particles and keeping sufficient water content for the cement hydration in soil cement.

• Korean Journal of Environmental Agriculture
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• v.33 no.2
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• pp.69-77
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• 2014

BACKGROUND: The purpose of this study was to investigate the effects of clothianidin on the soil in terms of clothianidin dissipation and degradation to evaluate its safety in order to provide an analytical foundation for clothianidin and the 5 metabolites related to it. METHODS AND RESULTS: High-performance liquid chromatography(HPLC) was used to separate clothianidin and its metabolites in this study. In soil, after suppressing dissociation-proned ions with weak alkalic $NH_4OH$ and extracting the metabolites with methanol, clothianidin, Methylaminoimidazole(MAI), Methylnitroguanidine(MNG), Thiazolylmethylurea(TZMU) and Thiazolylnitroguanidine(TZNG). Thiazolylmethylguanidine(TMG) were extracted with the addition of neutral $NH_4OAC$ to increasing the intensity of ions. Compounding elements were separated by using Hydrometrix ($ChemElut^{TM}$) and ion-exchanging Solid-phase extraction(SPE) Strong cation-exchanger(SCX) and C18 were used. The recovery rates of clothianidin and 5 metabolites in soil and water ranged from 87.4% to 104.3%. A standard deviation of our analysis for the soil and water samples were less than 5%. CONCLUSION: Well accepted detection limits for clothianidin and 5 metabolites in soil samples based on a dissipation analysis is 0.005 mg/kg and 0.001 mg/L in water samples. The dissipation concentration of this study was decided to be enough to evaluate the dissipation levels of clothianidin and its metabolites.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.5
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• pp.524-530
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• 2016

Agricultural soils near or around industrial complexes can contain a certain amount of heavy metals that readily enter the food chain and negatively affect human health. Therefore, we conducted the study to investigate the distribution of selected heavy metals, including arsenic (As), cadmium (Cd), chromium (Cr), nickel (Ni), lead (Pb), mercury (Hg), and zinc (Zn), in farm-land soils around fifteen industrial complexes in the southwestern provinces, Korea. The concentrations of heavy metals in the soil samples were determined by the pseudo-total aqua regia (3 HCl : $1HNO_3$) digestion procedure. The heavy metal concentrations in most soils examined did not exceed the levels of Soil Contamination Warning Standard (SCWS) for agricultural lands (Region 1) presented in Soil Environment Conservation Law (SECL) established by Ministry of Environment (MOE), Korea. However, only one sampling site showed higher As amount ($27.1mg\;kg^{-1}$) than the SCWS level of As ($25mg\;kg^{-1}$). Pollution index (PI) for heavy metals did not exceed 1.0. The PI values were significantly positively correlated (p < 0.01) with the heavy metal concentrations. In particular, the values of correlation coefficient between the Cd and Pb concentrations and the PI values were higher than those estimated from other combinations, and thus the amounts of Cd and Pb in the agricultural soils highly affected the PI values for the heavy metals.

• Journal of Soil and Groundwater Environment
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• v.15 no.6
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• pp.81-90
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• 2010

In this study, primary investigation for evaluation of abandoned metal mine effect on watershed has been done. 64 abandoned mines have been selected for primary investigation through literature and field survey. 216 soil and 90 water samples were collected and metal pollution concentrations were analyzed. 24 mines have mine water in the pits and acid water below pH 5 was not observed. Soils from 35 mines were over the soil basis of concern and 16 mines were over the soil basis of action. Arsenic average concentration was 188 times of average concentration of the natural background. Drinking water samples from 3 mines were over the drinking water standard and surface water samples from 12 mines were over the river water standard. Integrated pollution index, which was resulted from the integration of field survey, soil and water pollution concentration, showed that, abandoned metal mines had affected on watershed greatly in the order of Samgeum, Daedeok, Cheongdalgeum, Heungsin, Yeongdae and Myeongbong mines.

• Journal of the Korean Geotechnical Society
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• v.18 no.4
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• pp.45-53
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• 2002

There are some previous studies on the determination wave equation soil constants by SPT. However, methods suggested in previous researches had such analytical defects as the non-uniqueness of solutions, long-time consuming in computation, and lacking of accuracy due to the limit of available point values in time domain. In this paper, a modified procedure is proposed to improve the accuracy of determination of wave equation soil constants. It is based upon the least-error approach which minimizes the sum of errors between the measured and the recalculated wave values in total time domain. Finally, its applicability was verified by analyzing measured data presented on the released references.

• Journal of Industrial Technology
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• v.24 no.A
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• pp.251-261
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• 2004

A series of column test with a silty marine soil mixed with Jumunjin Standard Sand were performed to investigate the characteristics of settling and consolidation of non-plastic dredged soils. Column tests were carried out by using the separable column to measure the grain size distribution of consolidated layer. Column tests were performed with changing the mixing ratio of Jumunjin Standard Sand to the silty marine soil, initial water content of slurry and initial height of slurry. Height of interface of slurry was monitored during tests and grain size distribution tests were carried out after finishing tests. Influencing factors on the particle segregation, eventually to the characteristics of settling and consolidation of non-plastic soil, were analyzed on the thesis of test results. As results of column tests, the mixing ratio of sand to the silty marine soil and the initial water content of slurry were known to affect the characteristics of settling and consolidation resulted in significant particle segregation of slurry. Initial height of slurry was found not to affect seriously to particle segregation.

• Korean Journal of Organic Agriculture
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• v.23 no.4
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• pp.923-938
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• 2015

This study was conducted to serve as the basis for establishing a standard cultivation, which enhances the alternative utilization of pig manure, a major cause of environmental pollution, by finding a means for reducing greenhouse gas emissions for eco-friendly cultivation. In a laboratory, $CH_4$ and $CO_2$ emission patterns were investigated corresponding to incremental pig manure treatments in paddy soil. The emissions peaked 12 to 27 days after manure application in the 100~400% applications. It was found that increasing applications of pig manure resulted an increase in $CH_4$ and $CO_2$ emissions. Additionally, application of more than 150% emitted a larger amount of these gasses than applying chemical fertilizer. However, the test application of 100% pig manure emitted a smaller amount of $CH_4$ and hence Global Warming Potential (GWP) than those emitted by chemical fertilizer. If appropriate amount of fertilization is applied in compliance with the standard application rate, the pig manure may be effective in reducing greenhouse gas emissions and the soil environment made more favorable than with the use of chemical fertilizer.

• Proceedings of the Korean Geotechical Society Conference
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• 2008.10a
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• pp.1340-1352
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• 2008

In this study, S-wave velocity range is gauged in every field test method at the total 5 locations in the marine deposits in Incheon area. field test method is accomplished the SPT(Standard Penetration Test), CPT(Cone Penetration Test), SPS(Suspension PS Logger), SCPT (Seismic Cone Penetration Test) and so on. The S-wave velocity of SCPT in the downhole test method is measured lower than SPS logger at the N value > 15 range. But at the N value < 15 range, SPS logger and SCPT result is measured same. In this result, although the soil strength of the downhole test method increased, the rate of S-wave velocity is tend to be slowed. This result shows that the downhole test is difficult to apply at the place that the intensity of soil is more extreme and harder soil. And it shows that the existing Imai(1982) type that is mostly used within the country is not suitable for the marine deposits. Thus, the empirical formula that can show the range of S-wave velocity in each N value for domestic soil is needed.

• Journal of Environmental Science International
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• v.14 no.6
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• pp.605-611
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• 2005

The aim of this study was to analyze the local distribution of the heavy metal concentration in Daegu and Ulsan which were divided into the residual areas, the traffic dense areas and the industrial areas. The Inductively Coupled Plasma(ICP) was used to analyze heavy metals, such as As, Cr, Hg, Zn, Cd, Pb, Cu and minor metals, such as Fe, Si, Mg, Ca, AI, Na, K. The results of this analysis showed that the content of heavy metals which was classified by districts in Daegu and Ulsan was the highest in the industrial areas followed by the traffic dense areas and the residual areas. Compared to the level of heavy metals of national and local soil survey network in 2003, contamination of heavy metals in Daegu was lower than national average. However, the content of Cd, As, Zn in Ulsan was respectively 13.38 times, 472 times and 2.65 times higher than national average contamination. In addition, compared to the soil pollution level of the environmental protection law, contamination of all areas in Daegu was lower. But the content of As at the industrial areas in Ulsan was 10.71 times higher than standard of soil pollution and 4.28 times higher than standard of measures against soil contamination.

• The Journal of Engineering Geology
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• v.33 no.1
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• pp.39-49
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• 2023

Soil contaminants measured and managed in Korea include those of geologic origin such as arsenic, cadmium, copper, lead, zinc, nickel, mercury, and fluoride. This study identifies the distribution of these contaminants using GIS modeling to analyze the spatial probability of soil contamination originating from geology. The modeling found that cadmium, copper, lead, nickel, and mercury often exceed the regulated standard by <1%. Concentrations of arsenic and zinc greatly exceeded the standard in the vicinity of mines and industrial complexes: mining and industry seemed to have substantial effects on the concentrations of these metals. Although fluoride was sampled at the lowest number of points, its frequency of exceeding the standard was the highest. No obvious source of artificial contamination has been identified, and fluoride's distribution characteristics showed continuity over a wide area, suggesting a strong correlation between geological characteristics and fluoride concentration. The highest frequencies of fluoride exceeding the standard were in Jurassic granite (40.00%) and Precambrian banded gneiss (34.12%). As these rocks contributed to the formation of soil through their weathering, high fluoride concentrations can be expected in soil in areas where these rocks are distributed.