• Title/Summary/Keyword: Soil chemicals

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Reduction of Fluorine, Boron and Heavy Metals Leaching from Coal Ash by Adding Fixation Chemicals

  • Iwasaki, Makoto;Inoue, Kaori;Ikeshima, Kazuya;Ishizuka, Tadashi
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06a
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    • pp.105-110
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    • 2006
  • In order to utilize coal fly ash (hereafter : coal ash ) discharged from coal boiler as a material for civil engineering usage such as snow melter or soil improver, we have to prevent leaching hazardous elements such as fluorine boron and heavy metals from the coal ash because the leaching concentrations of some elements in the ash exceed the Japanese standards for environmental soil quality. Through the laboratory experiments and mill trials we confirmed that the leaching concentrations of fluorine, boron and heavy metals were maintained below their environmental standards by mixing with fixation chemicals and curing for a short time.

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Evaluation of Stabilization of Arsenic in Contaminated Soil Taken from Farmland Near Abandoned Metal Mine (폐금속광산 주변 오염 농경지에서 비소의 안정화 효율 평가)

  • Han, Su Ho;Jung, Myung Chae;Kim, Jeong Wook;Yoon, Kyung Wook;Min, Seon Ki;Park, So Yeon;Sim, Ki Tae
    • Journal of Soil and Groundwater Environment
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    • v.26 no.1
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    • pp.8-16
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    • 2021
  • This study has evaluated the stabilization of As contaminated paddy and cultivated soils by pot experiments for rice and lettuce. Various ratios of limestone (L) and steel slag (S) were mixed with the soils in each pot. The soils were taken from before and after pot experiments, and analyzed for As extracted by sequentially (Wenzel method) and totally (aqua regia method).. Paddy soils amended with L (0.5%) and L (1.0%) + S (1.0%) showed increasing fraction 2 (specifically bound As) compared with control soil. Arsenic concentrations in rice grain grown on the amended soils decreased 14% and 12% compared with those on the control soil, respectively. According to sequential extraction of As in cultivated soils, the fractions 1~3 were decreased due to stabilization of As by the soil amendment, especially for S (1.0%), S (3.0%) and L (1.0%) + S (1.0%). In addition, relatively low As concentrations were found in lettuce grown on amended soils with L (0.5%) and L (1.0%) + S (1.0%). Therefore, it can be suggested that soil amendments with L (0.5%) or L (1.0%) + S (1.0%) were suitable for enhancing stabilization of As in the study area.

Desorption Characteristics of Volatile Organics Compounds in Soil by Microwave Heating (마이크로파 가열에 의한 토양 유기오염물질 탈착특성)

  • 문경환;김덕찬
    • Journal of environmental and Sanitary engineering
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    • v.11 no.2
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    • pp.65-73
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    • 1996
  • The objective of this study is to investigate the removal efficiency of volitile organic compounds in soil, and the mechanism of desorption by bench scale microwave heating, Silt soil used for experiment and was impregnated with toluene, tetrachloroethylene, o-xylene and p-dichlorobenzene and the microwave treatment was conducted in a modified domestic microwave oven : 2450MHz, 700W. According to the results of the research the removal efficiency was improved with increasing water contents and the soil temperature appeared to plateau period extending to 2-3minutes corresponds to the temperature a which steam distillation was expected. The value of removal rate constant (k) were calculated on dry and moisty silt soil, respectively, which showed linear with increasing microwave heating time. Therefore, addition of a certain amount of water to the contaminated soil can efficiently enhance the ability of the soil to absorb microwave energy and promote the evaporation of the volitile contaminants.

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Potential Application of Environmental Tracer in Hydrogeochemistry Using Sorption Properties (환경 추적자의 흡착 특성을 이용한 수리지화학적 활용 가능성 고찰)

  • Choung, Sungwook;Chang, Seeun;Kim, Minkyung;Kim, Sungpyo;Um, Wooyong
    • Journal of Soil and Groundwater Environment
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    • v.17 no.6
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    • pp.59-68
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    • 2012
  • This study provided sorption properties of chlorofluorocarbons (CFCs), and elucidated potential application of CFC sorption data in hydrogeochemistry. Prior sorption studies were reviewed for hydrophobic organic compounds similar to the CFCs, because there were only few CFC sorption studies. The CFCs are regarded as relatively conservative chemicals in groundwater environments based on their moderate hydrophobicity. However, thermally altered carbonaceous matter (TACM) can significantly increase sorption capacity and nonlinearity for hydrophobic organic compounds such as CFCs, compared to general soil organic matter. CFC sorption behavior are close to the sorption for reviewed organic chemicals. Therefore, the CFC sorption data can be used for determining hydrogeochemical properties and predicting transport of organic contaminants in TACM-containing aquifer environments.

Evaluation on the effects of pesticide residues to agroecosystem in Korea (농업 생태계에 대한 잔류농약의 영향 평가)

  • Lee, Kyu-Seung
    • Korean Journal of Environmental Agriculture
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    • v.16 no.1
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    • pp.80-93
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    • 1997
  • Pesticide residues in soil could be affected to the growth of micro organisms and the activity of enzymes directly, and successively to the soil properties as pH, Eh and nitrogen metabolism. However, residues are diminished by degradation of soil microorganisms, run-off, leaching, volatilization, photodecomposition and uptake through crops. In this paper research results published in Korea were summarized about translocation of soil residues into crops, fates of residues in soil, effects to the activity of soil microorganisms and metabolic pathways of some pesticides. Generally speaking, pesticide residues in soil were not much affected to the agro-ecosystem except few chemicals. So it should be needed more further researches in this field, continuously.

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Biological Properties of Benfuresate and Cinosulfuron for Chemical Control of Eleocharis kuroguwai Ohwi (올방개 방제용(防除用) 제초제(除草劑) Benfuresate와 Cinosulfuron의 생물적(生物的) 특성(特性) 비교(比較))

  • Lee, H.K.;Lee, I.Y.;Ryu, G.H.;Lee, J.O.;Lee, E.J.
    • Korean Journal of Weed Science
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    • v.14 no.4
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    • pp.272-279
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    • 1994
  • In order to compare the biological properties of benfuresate and cinosulfuron as herbicides for the chemical control of Eleocharis kuroguwai, some experiments were conducted at greenhouse and field conditions in 1993. Benfuresate and cinosufuron moved to 2cm and 6cm deep in paddy soil and inhibited the growth of E. kuroguwai. Benfuresate was absorbed into the roots of E. kuroguwai. whereas cinosulfuron was absorbed into not only the roots and shoots but also the mesocotyls. After the emergence was inhibited by the soil application of herbicides, the percentage of regrowing numbers was higher at cinosulfuron than at benfuresate, whereas the growth rate was higher at benfuresate on the contrary. Benfuresate brought about complete death of buds as a killing type, but cinosulfuron produced lots of abnormal shoots as an inhibiting type. Benfuresate was able to apply on soil surface from the preemergence to the early stage of 2cm high, but cinosulfuron was able to use from the preemergence to the stage of 15cm high. The foliar application of cinosulfuron showed a good control effect, but it induced a severe phytotoxicity to rice. A good control effect of Benfuresate/bensulfuron GR lowered at the late stage, but that of cinosulfuron/mefenacet/dymron GR at the early stage maintained until the late stage of 65 days after transplanting.

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The Analysis of Surface Characteristics of the Hydrophilic Chemicals Treated PET Fibers using Tensiometric Methods (Tensiometric법을 이용한 친수하 PET 섬유의 표면특성 분석)

  • Chung Hae Won;Obendorf S. Kay
    • Journal of the Korean Society of Clothing and Textiles
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    • v.15 no.4 s.40
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    • pp.431-435
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    • 1991
  • The dispersion and Poiar force components of the surface free energy of PET fibers untreated and treated with hydrophilic chemicals, such as nonionic-soil release polymer (SRP), anionic, nonionic and hydrophilic silicone, were determined using harmonic-mean and geometric-mean methods. Contact angles of water and methylene iodide on the fibers were determined from the adhesion tensions using tensiometric method. Fibers treated with hydrophilic chemicals have the increased polar force component and the decreased dispersion force component. The adhesion tensions of triolein for the hydrophilic treated fibers were smaller than that for untreated fiber.

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Distribution of Heavy metals in Soil at Iksan 1st Industrial Complex Area (익산 제 1 공단 토양의 중금속 함량 분포 조사)

  • Kim, Seong-Jo;Baek, Seung-Hwa;Moon, Kwang-Hyun;Jang, Kwang-Ho;Kim, Su-Jin
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.48-53
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    • 1998
  • The purpose of this study was to compare heavy metal concentrations in uncontaminated soil with those in soil influenced by industrial activities, and to investigate the relationship between change of heavy metal content and the kind of industry at the Iksan 1st Industrial Complex that has started since 1975. Soils sampled in 0-3㎝ and 3-6㎝ soil depth, respectively were analized for content of Cd, Cu, Ni, Pb and Zn. Change of heavy metal content in soil of the industrial complex were more accumulated 16 to 25% of Cd and Cu, 93% of Pb and Zn, respectively in samples compared with natural soil uncontaminated. But there was no different in Ni content between two soil. Distribution of Cd in soil layer of 0 to 3cm was the highest concentration of 5 ppm more at the textile industries, and then higher at the chemicals and the food processing industries. In 3 to 6㎝ soil layer Cd content was the highest concentration of 5 ppm more at the metal processing industries, and then higher at the textile industries. Cd accumulation in soil was different according to a kind of industry and soil depth. Cu content was the highest value of 400 ppm more in soil layer of 0 to 3cm at the manufacturing electric wires industry area and showed the accumulation phenomenon in soil layer 3 to 6cm at the ohmmeter, machines and electric wires industry area. Ni content was 35 ppm more in soil of the metal plating and processing industries regardless of soil sampling layer. Then it was 25 ppm more in soil of the building stones and semiconductor industries. Pb content was from 400 to 1000 ppm in soil of the chemicals and textiles industries regardless of soil sampling layer. Zn content was 1200 ppm more in soil of the chemicals and silk fabrics industries regardless of soil depth, and then lower in order to soil of leather processing${\le}$metal plating industries. In conclusion, changes of heavy metal kinds and content in soil of this industrial complex area were caused by the type or kinds of industrial activities. Changes of Pb and Zn content in soil were dominated at this area.

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Review of Management Methods and Criteria for Environmentally-Sound Soil (친환경 토양 관리 방법과 기준에 대한 평가)

  • Ryu, Jin-Hee;Lee, Kyo-S.;Chung, Doug-Y.
    • Korean Journal of Agricultural Science
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    • v.35 no.1
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    • pp.53-67
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    • 2008
  • The principle goal of environmentally-friendly agriculture is to maintain and conserve water and agriculture environment including drinking water resources by properly using agricultural materials such as agricultural chemicals, chemical fertilizers, and other agricultural materials according to act 19 of foster law of environmentally-friendly agriculture. To achieve these goals, we have to establish Integrated Nutrient Management(INM) and Integrated Pesticide Management(IPM) which are most important core technologies for environmentally-friendly rice cultivation. However, there are lack of criteria and technology for evaluation category according to soil management and its soil classes to practice an environmentally-friendly agriculture. Therefore, we should eatablish the standards to produce the safe agricultural products based on the soil physical and chemical characteristics which are basic properties of soil to accomplish the principle aims of environmentally-friendly agriculture.

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