• Applied Biological Chemistry
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• v.41 no.8
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• pp.595-599
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• 1998

An analytical method was developed to determine tricyclazole residues in rice grain, straw, and soil using high-performance liquid chromatography (HPLC) with ultraviolet absorption detection. Tricyclazole was extracted with methanol from moist rice grain, straw, and soil samples. n-Hexane washing was employed to remove nonpolar co-extractives during liquid-liquid partition. Tricyclazole was then extracted with dichloromethane from alkaline aqueous phase, while acidic interferences remained in the phase. Dichloromethane extract was further purified by silica gel column chromatography prior to HPLC determination. Reverse-phase HPLC using an octadecylsilyl column was successfully applied to separate and quantitate the tricyclazole residue in sample extracts monitored at ${\lambda}_{max}$ 225nm. Recoveries from fortified samples averaged $95.5{\pm}3.0%\;(n=6),\;87.5{\pm}20.%\;(n=6),\;and\;84.3{\pm}2.8%$ (n=12) for rice grain, straw, and soil, respectively. Detection limit of the method was 0.02 mg/kg for rice grain and soil samples while 0.05 mg/kg for rice straw samples. The proposed method was reproducible and sensitive enough to evaluate the safety of tricyclazole residues in rice grain, straw, and soil.

• Structural Engineering and Mechanics
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• v.42 no.4
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• pp.571-587
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• 2012

This paper presents results of a numerical analysis performed on a corrugated steel plate (CSP) bridge during a backfilling process. The analysed bridge structure was a box culvert having a span of 12315 mm as well as a clear height of 3550 mm. Obtained calculation results were compared with the experimental ones. The paper is presented with the application of the Fast Lagrangian Analysis of Continua (FLAC) program based on the finite differences method (FDM) to determine behaviour of the soil-steel bridge structure during backfilling. The assumptions of a computational 2D model of soil-steel structure with a non-linear interface layer are described. Parametric analysis of the interface element is also given in order to receive the most realistic calculation results. The method based on this computational model may be used with large success to design calculations of this specific type of structure instead of the conventional and fairly inaccurate analytical methods. The conclusions drawn from such analysis can be helpful mostly for the assessment of the behaviour of steel-soil bridge structures under loads of backfilling. In consideration of an even more frequent application of this type of structure, conclusions from the conducted analysis can be generalized to a whole class of similar structural bridge solutions.

• Geomechanics and Engineering
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• v.23 no.5
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• pp.481-491
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• 2020

Piles installed in row(s) are used as an effective technique to improve the stability of soil slopes. The analysis of pile-stabilized slopes require a reliable prediction of lateral resistance offered by the piles. In this work, an analytical solution is developed to estimate the lateral resistance offered by the stabilizing piles in sand and c - 𝜙 soil slopes considering soil arching phenomenon. The soil arching in both horizontal direction (between the neighboring piles) and vertical direction (in the active wedge in front of the pile row) are studied and their effects are incorporated in the proposed model. The shape of soil arch is assumed to be circular and principal stress trajectories are defined separately for both modes of arching. Experimental and numerical studies found in literature were used to validate the proposed method. A detailed parametric analysis was performed to study the influence of pile diameter, center-to-center spacing, slope angle and angle of internal friction on the lateral pile resistance.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.1
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• pp.32-37
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• 2005

The procedure of soil sampling for on-farm quick test of soil nitrate is very important to improve practical application without weighing or drying soil. To improve application of test strip reflectometer as a quick on-farm analytical procedure for the estimation of soil nitrate concentration, three sampling methods such as gravimetric sampling (GS), particle density sampling (PDS) and bulk density sampling (BDS) for on-farm analytical procedure were investigated with twelve soils of 45 to $281mg\;kg^{-1}$ nitrate nitrogen concentration. The nitrate nitrogen concentrations measured from different soils were compared with two analytical methods, ion electrode method as a standard laboratory analysis (SLA) and test strip reflectometer at three moisture conditions, viz. air dried soil, 20 and 40% of maximum water holding capacity (MWHC). Nitrate nitrogen concentration measured by test strip reflectometer was significantly correlated with that of SLA, and the coefficients of variation (CV) were in the range of 3.5 to 10.9%. These CV values less than 10.9% were thought to be acceptable for the measurement of soil nitrate as an on-farm real time analytical procedure. The nitrate nitrogen concentration by BDS for test strip reflectometer as well as ion electrode method was more similar to that of SLA compared with those by GS and PDS especially in case of moist soils. This result suggests that the BDS is more useful than GS and PDS in case of on-farm analytical procedure of soil nitrate for moist soils. Further the practical measurement by BDS could be improved by substituting the bottle cap with a larger container.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2005.05a
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• pp.772-775
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• 2005

Most engineers, related to soil and civil dynamic field, have been interested in the direct dynamic design of building transmitted from soil and rock to structure due to blasting. However it is not easy to estimate the dynamic response of structures due to blasting by using analytical method because of difficulties of soil modeling, prediction of excitation force and so on. In this paper, dynamic analysis have been performed to predict vibration level and evaluate dynamic safety of structure adjacent to tunnel blast and the semi empirical method, which is based on vibration measurement data, has been employed to consider blast vibration characteristics.

• Structural Engineering and Mechanics
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• v.24 no.2
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• pp.247-268
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• 2006

The parts of pile, above the soil and embedded in the soil are called the first region and second region, respectively. The forth order differential equations of both region for critical buckling load of partially embedded pile with shear deformation are obtained using the small-displacement theory and Winkler hypothesis. It is assumed that the behavior of material of the pile is linear-elastic and that axial force along the pile length and modulus of subgrade reaction for the second region to be constant. Shear effect is included in the differential equations by considering shear deformation in the second derivative of the elastic curve function. Critical buckling loads of the pile are calculated for by differential transform method (DTM) and analytical method, results are given in tables and variation of critical buckling loads corresponding to relative stiffness of the pile are presented in graphs.

• Journal of the Korean Geosynthetics Society
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• v.9 no.4
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• pp.17-25
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• 2010

Evaluation of stability in traditional designing of reinforced soil structures is executed by examination of internal and external stability. Analysis of internal stability is for pull-out and ductile strength. Analysis of external stability is for settlement, overturning and sliding. To minimize inherent uncertainties of soil properties and analytical model, reliability analysis was developed recently. In this study, reliability analysis method considering simultaneous failure probability for various failure mode of internal and external stability is proposed. By applying uni-modal bounds, Stability of system reliability of reinforced soil structures is evaluated by integrating multi failure mode for various analytical model. Because of complex consideration for various failure shapes and modes, it is possible to secure advanced safety by using simultaneous failure probability. And evaluation of reinforced soil structure is executed by representative index, simultaneous failure probability, than previous method.

• Geomechanics and Engineering
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• v.32 no.2
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• pp.145-157
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• 2023

This paper aims at investigating the face stability of large-diameter underwater shield tunnels considering seepage in soft-hard uneven strata. Using the kinematic approach of limit upper-bound analysis, the analytical solution of limit supporting pressure on the tunnel face considering seepage was obtained based on a logarithmic spiral collapsed body in uneven strata. The stability analysis method of the excavation face with different soft- and hard-stratum ratios was explored and validated. Moreover, the effects of water level and burial depth on tunnel face stability were discussed. The results show the effect of seepage on the excavation face stability can be accounted as the seepage force on the excavation face and the seepage force of pore water in instability body. When the thickness ratio of hard soil layer within the excavation face exceeds 1/6D, the interface of the soft and hard soil layer can be placed at tunnel axis during stability analysis. The reliability of the analytical solution of the limit supporting pressure is validated by numerical method and literature methods. The increase of water level causes the instability of upper soft soil layer firstly due to the higher seepage force. With the rise of burial depth, the horizontal displacement of the upper soft soil decreases and the limit supporting pressure changes little because of soil arching effect.

• Steel and Composite Structures
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• v.26 no.1
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• pp.79-87
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• 2018

In order to study the natural vibration characteristics of steel-concrete composite truss beam (SCCTB), the influence of multiple factors such as interface slip, shear deformation and moment of inertia are considered. Afterwards, based on the Hamilton principle the vibration control differential equation and natural boundary conditions of SCCTB are deduced. By solving SCCTB differential equations of vibration control, an analytical calculation method is proposed for analyzing the natural vibration characteristics of SCCTB. The natural frequencies of SCCTBs with different degrees of shear connection and effective lengths are calculated by using the analytical method, and the results are compared against those obtained from ANSYS finite element numerical calculation method. The results show that the analytical method considering the influence factors such as interface slip, shear deformation and moment of inertia are in good agreement with those obtained from ANSYS finite element numerical calculation method. This evidences the correctness of the analytical method and show that the method proposed exhibits improvement over the previously developed theories for the natural vibration characteristics of SCCTB. Finally, based on the analytical method, the influence factors of SCCTB natural vibration characteristics are analyzed. The results indicate that the influence of interface slip stiffness on SCCTB's natural frequency is more than 10% and therefore cannot be neglected. Moreover, shear deformation has an effect of more than 35% on SCCTB's natural frequency and the effect cannot be ignored either in this case too.

• Journal of Soil and Groundwater Environment
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• v.21 no.6
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• pp.56-66
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• 2016

Generally, the contribution of crop-intake pathway (CIP) is remarkable in human health assessment (HHA) of heavy metal contamination. Although the crop exposure concentrations (Cp) should directly be used for calculating the average daily dose (ADD) of CIP, the soil exposure concentration (Cs) multiplied by soil-crop bio-concentration factor (BCF) has frequently been used instead of using Cp values. Thus, the BCF values are significant in the HHA, and care should be taken to ensure the reasonable acquisition of BCF values. Meanwhile, the BCF values are known to be significantly affected by analytical methods. Nevertheless, they have been calculated from the concentrations of soil and crop analyzed by only one method: total digestion (aqua regia extraction). For this reason, this study was initiated to seek appropriate soil analysis methods for effective computation of the ADD of CIP. The concentrations of 5 metal contaminants (As, Cd, Cu, Pb, and Zn) in 127 soil samples obtained from 4 abandoned metal mine areas were analyzed by several methods including total digestion and partial digestions using 0.1/1 N HCl, 1M $NH_4NO_3$, 0.1 M $NaNO_3$, and 0.01M $CaCl_2$. The heavy metal concentrations in 127 crop samples (rice grains) were analyzed by total digestion as well. Using the concentrations of soils and crops, the BCF values of each contaminant were calculated according to the kind of soil extraction methods applied. Finally, the errors between Cp and $C_s{\times}BCF$ were computed to evaluate the relevance of each method. The results indicate that the partial extraction using 0.1 N and 1 N HCl was superior or equivalent to total digestion. In addition, the 0.1M $NaNO_3$ method combined with total digestion is recommended for improving the reliability of BCF values.