• Title/Summary/Keyword: Soil acidity(pH)

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Mathematical model for reactive transport of heavy metals in soil column: Based on PHREEQC and HP1 simulators

  • Tameh, Fatemeh Izadi;Asadollahfardi, Gholamreza;Darban, Ahmad Khodadadi
    • Advances in environmental research
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    • v.6 no.1
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    • pp.67-81
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    • 2017
  • Mining activities play a significant role in environmental pollution by producing large amounts of tailings which comprise heavy metals. The impressive increase in mining activities in recent decades, due to their high influence on the industry of developing countries, duplicates the need for a substantial effort to develop and apply efficient measures of pollution control, mitigation, and abatement. In this study, our objective was to investigate the effect of simulation of the leachate, pH and inflow intensity of transport of $Pb^{2+}$, $Zn^{2+}$, and $Cd^{2+}$ through Lakan lead and zinc plant tailings, in Iran, and to evaluate the modeling efficiency by comparing the modeling results and the results obtained from previous column studies. We used the HP1 model and the PHREEQC database to simulate metals transport through a saturated soil column during a 15 day time period. The simulations assumed local equilibrium. As expected, a lower pH and inflow intensity increased metal transport. The retardation of heavy metals followed the order $Zn^{2+}$ > $Pb^{2+}$ > $Cd^{2+}$ and the removal concentrations of Cd, Pb, and Zn at the inflow intensity critical scenario, and Cd and Pb at inflow acidity critical scenario exceeded the allowable EPA and Iranian's 1053 standard thresholds. However, although the simulation results generally agreed well with the results of the column study, improvements are expected by using multi-dimensional models and a kinetic modeling approach for the reactions involved. The results of such investigations will be highly useful for designing preventative strategies to control reactive transport of hazardous metals and minimize their environmental effects.

Structure and Management Devices of Vegetation at Weolmi Urban Nature Park, Incheon (도시자연공원의 식생구조에 따른 관리방안 - 인천광역시 월미공원의 사례 -)

  • Cho, Woo
    • Journal of the Korean Institute of Landscape Architecture
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    • v.30 no.1
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    • pp.61-74
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    • 2002
  • The purpose of this study is to propose vegetation management devices through analyzing the actual vegetation, flora, plant community structure and soil chemical concentrations in Weolmi urban nature park, Incheon. The actual vegetation of Weolmi Park in various areas is composed of urbanization area(2 types, 25.9%), landscape planting area(4 types, 16.1%), grass and marsh area(5 types, 7.6%) and mountain forest areal(14 types, 50.4%). The flora is composed of 295 taxa with 80 families, 253 species, 35 varieties and 7 formas, and among them there are 16 naturalized plant families, 39 species, 3 varieties. In reflection of size, the number of the species seems high but most of the them are under influence of human disturbance. Nine survey plots of plant community structure are classified into two groups. One is the semi-natural plant community(Prunus sargentii-Acer palmatum, Quercus accutissma-Prunus sargentii, Quercus serrata-Quercus accutissma-Prunus sargentii, Prunus sargentii, and Zelkova serrata-Prunus sargentii) that migrated finn the planting forest to the natural forest and the other is planting forest(Pinus koraienssis-Pinus thunbergii-Abies holophylla-Chamaectparis obtusa, Prunus sargentii, Pinus thunbergii-Alnus firma, Zelkova serrata). The average pH is 4.65 which means the soil acidity is quite high. The concentration of K, Ca, Mg and base saturation is very low. It seems that the environmental pollutants from Incheon Port and industrial plants near by survey site and long-distance transport of air pollutants from China made the soil condition worse. On the basis of the results above, six vegetation management devices are suggested: 1) removing the hazard plants(Pueraia thunbergiana and Humulus japonica), 2) natural landscape management of the middle and long term, 3) increasing species diversity, 4) Robinia pseudoacacia management, 5) keeping the naturalized plants from being distributed any further inside the mountain forest, 6) improving soil acidification.

Studies on the Precipitation of Lead Ion and the Inhibition of Plant Growth (연(Pb) 이온의 침전과 식물생장의 억제에 관한 연구)

  • 성민웅
    • Journal of Plant Biology
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    • v.19 no.1
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    • pp.1-6
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    • 1976
  • This study was carried out to investigate the formation of precipitates between lead ion and the essential anions of plants, the effects of lead concentration on seed germination and plant growth in water and soil culture, and the germinating and growing recovery of inhibited seed germination and plant growth by lead. Four kinds of the seeds (Glycine max M., Triticum vulgare V., Setaria viridis (L) P. De Beauvois, and Digitoria sanguinalis (L) Scopoli var) were germinated and growth in water and soil culture included the different concentrations of lead for five days. The seeds and plants inhibited germination and growth by lead were transferred to lead free Hoagland solution and the growing recovery was observed. The precipitates of lead ion were observed in the solution of both acidity and alkalinity included each anion of $H_2PO_4^-, HPO_4^{2-}, PO_4^{3-}, SO_4^{2-} and MoO_4^{2-}$ in a room temperature, whereas the precipitates between lead ion and other anions were observed largely in the solution of alkalinity, so that it seemed that lead could be remained in the state of non-soluble in plant and soil. The inhibition of germination and growth in the water culture was observed in 100ppm of lead, whereas the inhibition in the case of the soil culture was observed in 10000ppm of lead. The difference of the effected concentration between water and soil culture in germination and the growth was 100 times. When the seed and plant inhibited the growth in 5000ppm or 10000ppm of lead for five days were transferred to lead free Hoagland solution, the recovery of germination and growth was observed in three days. This growing recovery was different according to the kinds of plant and concentrations of lead. It seemed that plant growth could be inhibited by the inhibition of the metabolism concerned with the precipitates between lead iion and other anions.

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Ecological Management Plan and Biotope Structure of Namsan Urban Natural Park in Seoul (서울 남산도시자연공원의 비오톱 구조 및 생태적 관리방안)

  • Lee Kyong-Jae;Han Bong-Ho;Lee Soo-Dong
    • Journal of the Korean Institute of Landscape Architecture
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    • v.32 no.5
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    • pp.102-118
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    • 2004
  • The purpose of this study was to propose an ecological management plan by the comprehensive analysis of biotope structures on Namsan Urban Natural Park in Seoul. Classified by actual vegetation, structure of layer and vegetation damage, biotope structures were composed of forest area, compact management area, herb area, cultivated area and non-ecology(urban) area. Succession had seened to stop in the Native forest. Artifical forest was divided into two types. The first, upper layer, was too dense to accommodate lower layer plants, the other case was the appearance of Quercus spp. and the first stage plants of succession following the declination of the upper layer plants. The soil pH of Nam-san Urban Park was 4.21∼4.51, which meant the soil was becoming acid. As the result of acidity, leaching of available nutrition(K/sup +/, NH₄/sup +/, Ca/sup ++/ etc.) was immediately influenced by the natural ecosystem, influence of acid rain was disturbed to becoming organic matter which was use to plants. In the case of a biotope structure management plan, the urban area was prohibited to spread outside. Cultivated and herb area was regenerated to natural forest. In the forest area, the compact management area was maintained with its present condition, and then it is desirable to make a preservation area and to plant shrubs. Planted Pinus densiflora Community was needed to eliminate competitive species of canopy layer, and plant shrubs. Management of deciduous broad-leaved Comm. was maintained in its present conditionand it is desirable to raise the diversity of the understory and shrub layer. The management of the artifical forest seems to be suitable for Q. spp. community. The care of naturalized plants prevents the expansion and restores the structure of wild plants. The soil management was a marked restoration soil ecosystem in order to prevent soil acid and drying.

A Study on Growth Conditions of the Protected Trees in Gyeongju-si (경주시 보호수 생육실태 연구)

  • Heo Sang-Hyun;Ha Jae-Ho
    • Journal of Environmental Science International
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    • v.13 no.10
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    • pp.883-890
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    • 2004
  • The purpose of this study is to survey and analyze the growth, management and surrounding environment of the big and old trees in Kyoungju-si or the cultural assets alive in our history, and thereby, provide for some data useful to their reasonable protection and use of their surrounding areas. As a result of surveying the growth conditions of the big and old trees, it was found that the height of new grass was 10.5cm on average, the activity scale of the wood was 7.2k$\Omega$, the soil hardness was $16.7kg/cm^2$, the soil acidity was pH 4.8, and the soil moisture was $13.3\%$. Such findings suggest that the soil has been acidified by people's frequent passages, but that the other growth conditions are more or less normal. Hence, it is desirable to secure a sufficient space around the trees or reduce people's stamping pressure with some mechanisms. On the other hand, the visible conditions of the trees were found more or less normal, but many trees remained cut or barked (with some cavities), requiring an optimal treatment or measure. Lastly, as the population has decreased in the suburban traditional villages, the surrounding environment seems to be less vulnerable to people's frequent visits. Nevertheless, in consideration of the fact that there are only a few public space for the villagers, it is deemed necessary to rearrange or maintain some parts of the surrounding environment as public space for villagers or hikers.

Plant Community Structure Analysis in Gunpo Experimental Forest of Mt. Suri, Kyonggi-do (경기도 수리산 군포시험림 식물군집구조)

  • 이경재;민성환;한봉호;김호식
    • Korean Journal of Environment and Ecology
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    • v.11 no.3
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    • pp.290-309
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    • 1997
  • To investigate the plant community structure in Gunpo Experimental Forest of Mt. Suri, Kyonggi-do, sixty-four plots were set up and surveyed. By DCA ordination technique, sixty-four plots were divided into seven groups. The dividing groups were * Pinus rigitaeda community, P. densiflora community, P. densiflora-Quercus mongolica community, Q. variabilis community, Q. aliena comunity, Q. serrata community, Carpinus laxiflora community. Though the successional trend of seven communities by DCA ordination technique and DBH class distribution analysis was not clearly inferred, * Pinus rigitaeda community and P. densiflora-Q: mongolica community seems to be trended from present state to Q. spp. community. P. densiflora community, Q. variabilis community, Q. aliena community and Q. serrata community seems to be maintained preaent state and C. laxiflora community will be maintainde stable state. Shannon's diversity was 0.7430~1.3025(unit area: 300m$^{2}$) and soil acidity was pH 4.16~5.13 in surveyed areas.

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Study on Acidification and Neutralization Characteristics of Precipitation in JejuCity between 1997 and 2005 (1997~2005년 제주시 지역 강수의 산성화 및 중화 특성 연구)

  • Kang Chang-Hee;Hong Sang-Bum;Kim Won-Hyung;Ko Hee-Jung;Lee Sun-Bong;Song Jung-Min
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.4
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    • pp.487-498
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    • 2006
  • Total 438 precipitation samples were collected in Jeju City between 1997 and 2005, and their major ionic components were analyzed. The comparison tests using ion balance, electric conductivity and acid fraction were performed. It was found their correlation coefficients were in the range of 0.977$\sim$0.994, indicating the good quality of collected dam. The volume-weighted mean pH and electric conductivity were 4.8 and 23.0 $\mu$S/cm, respectively. with the ionic strength of 0.23$\pm$0.20 mM. The marine ($Na^+$, $Mg^{2+}$, and $CI^-$), anthropogenic (nss$SO_4{2-}$, $NO_3^-$, and $NH_4^+$) and soil (nss-$Ca^{2+}$) species have contributed to the ionic components of precipitation samples with 43$\sim$74%, 16$\sim$37% and $\sim$5%, respectively. The seasonal variations of $NO_3^-$ and nss-$SO_4^{2-}$ showed a distinct seasonality with higher concentrations in winter than summer, indicating an increase of fossil fuel consumption and a possibility of long-range transport of those pollutants from continental area along the dominant winter westerly. The levels of nss-$Ca^{2+}$ also were appeared the highest in winter and increased comparatively in spring season. possibly due to the soil influences including the Asian Dust. The acidification contribution of nss-$SO_4^{2-}$ and $NO_3^-$ showed 88$\sim$96%, and the free acidity was in the range of 6.0$\sim$40.1%. Interestingly, the backward trajectories for the case of upper 10% nss-$SO_4^{2-}$ and $NO_3^-$ levels have passed through the China continent before their arrival to Jeju. The precipitation of pH below 4.5 has been occurred frequently when the trajectory's path lied over the China continents. On the other hand, the air masses from the North Pacific area were characterized by lower 10% of nss-$SO_4^{2-}$- and $NO_3^-$ concentration, which demonstrated that air mass from the North Pacific was the cleanest among air masses moved to Jeju.

Application Cases of Test Construction of Hydro-Seeding Measures on the Slopes Along the National Road Between Gamchon and Yaechon (감천예천구간 국도비탈면 종자뿜어붙이기 시험시공 적용사례)

  • Jeon, Gi-Seong;Woo, Kyung-Jin
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.10 no.6
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    • pp.139-151
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    • 2007
  • To protect the surface of ground-cutting slopes and ground-raised slopes and to recover environment-friendly slopes at the national road expansion construction between Gamchon and Yaechon, test-construction work was done using several modes of hydro-seeding measures to select a suitable construction method through the field survey; the results were as follows : As a result of survey on physio-chemical characteristics of soil, the average soil inclination on ground-raised slopes was from 4.73 mm to 5.37 mm; the average soil acidity was from pH 6.47 to 6.73; the average soil humidity was within the scope of 0.57~1.70 %,; the average soil inclination on ground-cutting slopes was 9.17~10.43mm; the average soil acidity was pH 6.67~6.77 and the average soil humidity was within the scope of 0.53~1.27 %; considered overall, they showed generally satisfactory base materials for plant breeding. As a result of the number of sprouting individuals, the average sprouting number of individuals on test spots executed by Coir net with Seed spray construction methods and the average number of sprouting individuals on other test spots executed by furrow-digging with Seed spray and Straw mat-mulching measures were 1,172 number of per square meter and 970 number of per square meter respectively; thus they showed higher numerical value comparing with other test spots. Likewise, the average number of sprouting individuals on test spots of the ground-cutting slopes executed by Coir net with Seed spray method and the average number of sprouting individuals on other test spot executed by furrow-digger with Seed spray and Straw mat-mulching measures were found to be 1,107 number of per square meter and 1,105 number of per square meter respectively, whose numerical value showed rather higher other test spots. As a result of a survey on living plants' breeding index [dried weight], the weight in dried state on test spots executed by Coir net with Seed spray method and other test spots executed by furrow-digger with Seed spray and Straw mat-mulching measures on both ground-raised and ground-cutting slopes was found to be higher and showed similar characteristics statistically. As a result of survey on the surface-covering degree of ground-raised slopes, nine weeks after test construction, test spots executed by Coir net with Seed spray method and other test spots executed by furrow-digger with Seed spray and Straw mat-mulching measures showed commonly more than 70% of surface-covering degree, but other test spots showed only below 35% of surface covering degree; especially in case of test spots by Verdvol seed spray measures, they showed 10% of the lowest surface-covering. Surface-covering degree on the test spot of ground-cutting slopes nine weeks after test construction showed more than 75% both executed by Coir net with Seed spray construction method and executed by furrow-digger with Seed spray and Straw mat-mulching measures. As a result of survey on appearing plants on the test spots, there dominates Eragrostis curvula both on ground-raised slopes and on ground-cutting slopes with other seeding plant life's lower breeding and there appear intruders, such as Setaria viridis Beauv, Digitaria sanguinalis Scop, and Chenopodium album var.centrorubrum Makino. As for water-borne excavation and soil's washing-away on the slopes, there happened less washing-away and water-borne excavation with good breeding of plant life on test spots executed both by Coir net with Seed spray construction method and by furrow-digger with Seed spray and Straw mat-mulching measures, but there happened much more soil's washing-away along with water-home excavation at the test spot executed by Seed spray with measures. After the research results of test construction sites are examined overall, it's presumed that furrow-digger with Seed spray and Straw mat-mulching measures [interval between lines is 40cm, 5cm in depth] will be preferred to prevent erosion and water-home excavation of slopes located within the construction sites.

Plant Community Structure Snalysis in Chohangyoung Valley of Soraksan National Park (설악산 국립공원 저항령계곡 식물군집구조)

  • 이경재;조현서;한봉호
    • Korean Journal of Environment and Ecology
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    • v.10 no.2
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    • pp.251-269
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    • 1997
  • To investigate the plant community structure of Chohangyoung valley in Soraksan National Park, thirty nine plots(each size was 100m$^{2}$) were set up and surveyed and to analyze the plant community characteristics of valley area and slope area, twenty five plots in five sites were set up and surveyed. According to DCA ordination techniques, the communities were six divided into community types, which were Pinus densiflora community, P. densiflora-Populus maximowiczii community, Po. maximowiczii-P. densiflora community, Po. maszimowiczii community, Fraxinus rhyuchophylla community, Quercus serrata community. Q. serrata community was only distrivuted at slope area and the others were distributied at valley area. The successional trend of six communities was not clearly inferred. Shannon's diversity was 0.9458~1.1769(unit area:500m$^{2}$), and soil acidity was pH 4.65~6.09 in surveyed areas. According to the belt-transect analysis, the dominant species of valley area were P. densiflora, Po. maximowiczii, but the dominant species of slope area was Q. serrata.

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Changes in Chlorophyll Content and Leaf Damages of Liliodendron tulipifera L. Seedlings Treated with Simulated Acid Rain (인공산성비 처리에 의한 백합나무 묘목의 엽피해와 엽록소함량 변화)

  • Yoon, Jun-Hyuck;Lee, Do-Hyung;Woo, Kwan-Soo
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.3
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    • pp.75-81
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    • 2008
  • This study was conducted to analyze the influence of simulated acid rain on leaves of Liliodendron tulipifera seedlings. The seedlings were treated with four levels of simulated acid rain with pH of 5.6, 4.9, 3.9 and 2.9, and then chlorophyll contents and the degree of foliar damage were investigated. Differences were statistically significant among treatments in chlorophyll contents in all of the tested soils. The total contents of chlorophyll tended to decrease as the simulated acid rain treatment was maintained. Chlorophyll contents, however, did not decrease according to the decrement of pH levels. Foliar damage increased as the simulated acid rain was maintained in all tested soils. Especially, the damage dramatically increased between May and July as the acidity increased. As the treatment of simulated acid rain continued, deformed new leaves appeared. In all treatments except the control, the leaves turned brown and the damage increased with time. Necrotic spots appeared during the first month of treatment at the pH level of 2.9 in all soil types. The damage by acid rain should be considered when we plant Liliodendron tulipifera.