• 대한토목학회논문집
• /
• 제32권4B호
• /
• pp.261-266
• /
• 2012

본 연구에서는 중금속에 의한 토양환경영향평가 시 노출농도 기반의 평가와 위해성 기반의 평가를 비교하였다. 이를 위해서 폐광산 지역에서 중금속 오염노출을 조사하였다. 발암위해도와 비발암위해도 평가 결과, 토양섭취의 영향이 토양접촉의 영향보다 지배적이었고, 우려기준을 초과하는 경우에는 총 위해도도 기준을 초과하였다. 우려기준을 초과하지 않는 경우도 대부분 총 위해도 기준을 초과하였으므로, 위해도 기반의 평가가 노출농도 기반의 평가보다 더 민감한 기준이라는 기존 인식을 확인하였다. 하지만 토양접촉 경로의 비발암위해성 결과들의 심층 분석 결과, 우려기준을 초과함에도 위해도 기준을 초과하지 않는 경우들이 검출되었다. 본 연구에서는 신뢰성 있는 폐광산지역의 토양오염정화사업 타당성 평가를 위해서는 현재 노출농도기반의 평가 위주에서 위해성 기반 평가로의 정책 전환의 필요성이 확인되었고, 위해도 원단위 및 판단기준의 객관적 설정을 위한 연구 필요성이 제시되었다.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제26권3호
• /
• pp.37-49
• /
• 2021

There is domestic Soil Contamination Warning Standard (SCWS) as remediation standard concentration of contaminated soils. No risk should be observed at soil concentration less than SCWS. Therefore, SCWS was evaluated to confirm the risk assessment. Background Concentration of Soil (BGC) and target remediation concentration were also assessed. The results show that Excess Cancer Risk (ECR) of SCWS was the highest in the groundwater intake pathway (Adult: 6.27E-04, Child: 2.81E-04). Total Cancer Risk (TCR) was 7.76E-04 and 4.30E-04 for adult and child, exceeding reference value (10^-6). Hazard Quotient (Non-Carcinogenic Risk, HQ) was the highest in the indoor air inhalation pathway (Adult: 3.64E+03, Child: 8.74E+02). Hazard Index (Total Non-Carcinogenic Risk, HI) exceeded reference value 1. ECR of the BGC was the highest in the groundwater intake pathway (Adult: 1.71E-04, Child: 7.67E-05). TCR was 2.12E-04 for adults and 1.17E-04 for children, exceeding the reference value (10^-6). HQ was the highest in groundwater intake pathway (Adult: 4.10E-01, Child: 1.84E-01). HI was lower than reference value 1 (Adult: 4.78E-01, Child: 2.50E-01). The heavy metal affecting ECR was Arsenic (As). The remediation-concentration of As was 7.14 mg/kg which is higher than BGC (6.83 mg/kg). TCR of As should be less than reference value (10^-6), but it was higher for all of SCWS, BGC and target remediation concentration. Therefore, it is suggested that risk assessment factors should be re-evaluated to fit domestic environmental settings and SCWS should be induced to satisfy the risk assessment.

• 한국환경보건학회지
• /
• 제36권6호
• /
• pp.456-464
• /
• 2010

Recently, heavy metals contamination of the agricultural soil and crops surrounding mining areas has been identified as one of the most serious environmental problems in South Korea. The Ministry of the Environment in Korea conducted a Preliminary National Environmental Health Survey (PNEHS) in abandoned metal mines in 2007. The priority for a subsequent detailed examination was ranked from the results of PNEHS. The studied mine which was ranked as being of the highest priority is located in the midwestern part of Korea and was operated from 1911 to 1985. In this study, the contamination levels of the heavy metals in the abandoned metal mine were investigated. From the results, the average daily dose (ADD), target hazard quotient (THQ) and target cancer risk of the heavy metals were evaluated. The concentration of arsenic (As) in all of the tailings from the mine was higher than its countermeasure standard of Korea. In particular, the highest concentration of As, 330 mg/kg, was up to 15 times higher than its countermeasure standard. The average concentration of As in agricultural soils was higher than the warning standard of Korea, and higher than its countermeasure standard at six sites. The average concentrations of the analyzed heavy metals in agricultural soil were below the warning standard, but concentrations of cadmium (Cd) and lead (Pb) at 4 sites were higher than its warning standard. The average concentration of As in surface water exceeded the warning standard of Korea. The value of the THQ of As for the tailings was higher than the health protection standard 1. The value of THQ of As for the farmlands was lower than the standard, while the hazard index (HI) of As was higher than the standard. The value of target cancer risk (TCR) of As, $6.44{\times}10^{-4}$, were higher than the health protection standard of a lifetime risk for TCR at $1{\times}10^{-6}$. This suggests that the residents around the metal mines are exposed to As pollution with a carcinogenic risk.

• 지질공학
• /
• 제16권4호
• /
• pp.393-402
• /
• 2006

본 논문에서는 점오염원 형태의 유류누출이 발생되었던 실트질 토양층에서 BTEX와 TPH 성분의 오염특성이 연구되었다. TPH 성분의 토양오염기준별 초과율은 BTEX 성분에 비해 $1.5{\sim}1.7$ 배정도 높았다. BTEX와 TPH 성분의 채취지점별 평균과 최대값은 B-zone>A-zone>C-zone의 순이며, 두 성분 모두 지표면하 $1{\sim}2m$구간에서 오염농도가 가장 높게 나타났다. 오염원에서 수리경사 하부 방향으로 120m와 80m 이내인 지역에서는 BTEX와 TPH 농도가 이격거리에 따라 증가하였으며, 120 m 이상 이격된 지역에서는 토양오염기순 이하인 것으로 나타났다. BTEX와 TPH 성분에 대한 지시크리깅의 제한값으로는 토양오염 확인기준, 우려기준 및 대책기준 값이 적용되었다. 지시변환된 자료의 베리오그램 분석에 의하면, BTEX와 TPH성분 모두 선형모델이 가장 적합한 것으로 나타났다. 선형모델을 적용한 BTEX와 TPH 성분의 확률도에서 토양오염 확인기준과 우려기준의 오염 범위는 유사하게 나타났으나, 대책기준의 오염 범위는 매우 축소되었다. 토양오염 확인기준, 우려기준 및 대책기준에 의해 작성된 확률도에서 BTEX와 TPH 성분의 최대 오염 확률은 BTEX성분이 26%, 26% 및 13%, TPH 성분은 44%, 38% 및 26%인 것으로 추정되었다.

• 한국토양비료학회지
• /
• 제49권5호
• /
• pp.524-530
• /
• 2016

Agricultural soils near or around industrial complexes can contain a certain amount of heavy metals that readily enter the food chain and negatively affect human health. Therefore, we conducted the study to investigate the distribution of selected heavy metals, including arsenic (As), cadmium (Cd), chromium (Cr), nickel (Ni), lead (Pb), mercury (Hg), and zinc (Zn), in farm-land soils around fifteen industrial complexes in the southwestern provinces, Korea. The concentrations of heavy metals in the soil samples were determined by the pseudo-total aqua regia (3 HCl : $1HNO_3$) digestion procedure. The heavy metal concentrations in most soils examined did not exceed the levels of Soil Contamination Warning Standard (SCWS) for agricultural lands (Region 1) presented in Soil Environment Conservation Law (SECL) established by Ministry of Environment (MOE), Korea. However, only one sampling site showed higher As amount ($27.1mg\;kg^{-1}$) than the SCWS level of As ($25mg\;kg^{-1}$). Pollution index (PI) for heavy metals did not exceed 1.0. The PI values were significantly positively correlated (p < 0.01) with the heavy metal concentrations. In particular, the values of correlation coefficient between the Cd and Pb concentrations and the PI values were higher than those estimated from other combinations, and thus the amounts of Cd and Pb in the agricultural soils highly affected the PI values for the heavy metals.

• 한국농공학회논문집
• /
• 제51권4호
• /
• pp.67-73
• /
• 2009

Chemical properties of soil in the proposed horticultural complexes of Saemangeun reclaimed tideland were studied for sustainable development of the newly reclaimed land resources. The soil texture of Gwanghwal, Gyehwa, Mangyeong and Okgu complex area were sandy loam. The pH and ESP (exchangeable sodium percentage) were 7.42 to 7.82 and 61.05 to 73.62 %, respectively. Compared to general agricultural land in Korea, the soil organic matter and other plant nutrients were low. The concentrations of heavy metals in the soil were found to be acceptable except several sites where they doesn't meet the warning standard of agricultural land contamination. Continuous monitoring and interception of external pollutants are suggested for water-soil-plant system conservation.

• 농업과학연구
• /
• 제46권4호
• /
• pp.799-811
• /
• 2019

The aim of this study was to evaluate heavy metal contamination and pollution index of agricultural soils around industrial complexes in the Jeon-Buk Regions of Korea. Soil samples near industrial complexes in 2017 were collected at two depths (0 - 15 and 15 - 30 cm) within a 500- and 1000-meter radius before planting. Eight heavy metals (Arsenic (As), cadmium (Cd), chromium (Cr), Cupper (Cu), nickel (Ni), lead (Pb), mercury (Hg) and zinc (Zn)) and the pollution index (PI), geoaccumulation index (Igeo) and soil pollution index (SPI) were evaluated based on soil contamination warning standard (SCWS). Overall, the heavy metal concentrations were below the SCWS. The PI ranged from 0.1 to 0.9 and categorized into Group 1 which is not polluted with any heavy metals. The average Igeo values of all the soil samples ranged from - 2.56 to 3.22. The Igeo values of Cd and Hg may not represent well the pollution index because the heavy metal concentrations in the soil is lower compared to the SCWS. In fact, based on the heavy metal concentrations, the Igeo for monitored soils should be categorized into Group 1, uncontaminated to moderately contaminated. However, the Igeo of Cd and Hg are classified into heavily contaminated. These results suggest that for calculating the Igeo, the heavy metal concentration and background concentration should be used very carefully if the heavy metal concentration in the soil is lower than the background concentration. SPI for all the soil samples ranged from 0.00 to 0.11 which indicates no heavy metal pollution was observed.

• 한국토양비료학회지
• /
• 제45권5호
• /
• pp.738-743
• /
• 2012

Topographic conditions of agricultural fields work as a important factor to identify different soil properties. This study was conducted to investigate the selected soil chemical properties and the concentrations of heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields of different topographic areas at four year intervals from 1999 to 2011. Three-hundred soil sampling sites in the paddy fields were selected from the different topographic areas that were local valley and fans, fluvio-marine deposits, alluvial plains, and diluvial terraces. The mean values of soil pH ranged 5.7~5.8 that were within optimal range for rice cultivation. The mean values of other properties such as soil organic matter (SOM) content, the concentrations of exchangeable cations, $K^+$, $Ca^{2+}$, and $Mg^{2+}$, and available silicate concentration were lower or close to the optimal values, but the mean concentrations of available phosphorus were exceeded the range of optimal value, $80{\sim}120mg\;kg^{-1}$, in many paddy fields. In particular, The concentrations of available phosphorus in the paddy fields of local valley and fans, alluvial plains, and fluvio-marine plains were mostly declined. However, in diluvial terrace areas, the phosphorus concentrations unexpectedly increased; furthermore, they were significantly higher than those in other topographic areas. The mean concentrations of 0.1 M HCl-extractable heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields were slightly and gradually declined during the study years, but the Pb concentrations were not statistically changed. In addition, the concentrations of heavy metals were widely ranged depending on the different sampling sites. Nevertheless, the concentrations of heavy metals were significantly lower than the levels of Soil Contamination Warning Standard (SCWS) for agricultural lands (1-region) presented in Soil Environment Conservation Law (SECL).

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제7권4호
• /
• pp.31-39
• /
• 2002

본 연구는 소하천형 호수의 수질개선 및 친환경적 생태공원조성을 위한 퇴적저니 처리방안을 수립하기 위하여 기존에 실시된 기본계획의 타당성 및 퇴적저니의 오염도 등을 검토하고 이를 토대로 최적의 퇴적저니 처리.처분계획을 수립하는데 목적이 있다. 퇴적저니의 정확한 오염도 분석을 위하여 총 9개 지점에 대해 저니층별로 23개소에 대한 퇴적저니를 채취하여 오염도를 분석한 결과 Cu의 경우 4개 시료가 지정폐기물 기준(3mg/L)을 초과하였다. 거의 전 지점의 시료가 농경지에 대한 Cu의 토양오염우려기준(50 mg/kg)을 초과한 것으로 조사되었다 그외 Pb및 Hg은 모두 기준이하로 분석되었다. 퇴적저니의 적정 처리방안을 수립하기 위하여 유기물 및 영양염류 오염도에 따른 퇴적저니의 준설필요성 여부를 국내 팔당호 및 한강하류 적용기준과 일본 동경만 및 요코하마만 적용기준에 의거 검토하고, 또한 중금속 오염도에 따른 퇴적저니의 처리여부를 일본, 미국 및 캐나다 기준을 적용하여 검토한 결과, 유기물 및 영양염류에 대한 오염도는 심각한 수준은 아니었으며, 유해물질에 의한 오염도는 일본기준에는 대부분 만족하나 저서생물에 미치는 악영향을 기준으로 설정된 미국 및 캐나다 기준에 대해서는 모두 중간오염 또는 심한오염에 해당하는 것으로 판정되었다. 그래서 퇴적저니 처리방안을 검토하기 위하여 선진국에서 많이 사용되고 있는 퇴적저니 정화방안중 중금속 안정화에 효과적인 고형화/안정화 방안을 검토한 결과 저니내의 Cu의 용출농도를 줄일 수 있었다. 또한 혼합된 시멘트 고화체는 높은 압축강도를 나타내어 건설용 토사나 제방성토용으로 사용 가능할 것으로 생각되었다. 나타내는 결과이다. 특별히 토양내 흡착력이 약하고 지하수내에 쉽게 용해될 수 있으며 독성 및 발암성물질로 알려진 사염화탄소와 같은 염소계 유기화합물의 제거에 효과적으로 적용될 수 있을 것으로 사료된다.3}$C(PDB)값은 -6.2~0.0$\textperthousand$범위이며, 그 기원은 대수층인 지층내 탄산염암 또는 탄산염 광물의 용해에서 유래한 무기기원 탄소로 해석된다.다.으로 변화하였으며 치료 전에 반응하지 않던 항원에 새롭게 반응하는 항체가 나타나는 경우는 드물었다.ms of chlorophyll-a concentration estimation, however, the accuracy stays very similar compared to that of the CZCS-type algorithm. This is considered to be due to the nature of in-water algorithm which relies on spectral ratio of water-leaving radiances.ethanol의 혈중농도(血中濃度)가 높을수록 더 심(甚)한 혈압강하작용(血壓降下作用)을 나타내며, ethanol 로 인(因)한 이뇨작용(利尿作用)도 ethanol 량(量)이 증가(增加)함에 따라 뇨량(尿量)도 증가(增加)함을 보여 주었다.ults showed that the overall quality of Sullungtang significantly decreased as the parity increased for Hanwoo cows. The Sullungtang extracted

• 한국토양비료학회지
• /
• 제44권4호
• /
• pp.591-596
• /
• 2011

The applications of chemical fertilizers and various types of organic materials may cause heavy metal accumulation in soil. In this study, we conducted to investigate the relationship between the different chemical forms of heavy metals such as Cr, Cd, Pb, Cu, Ni, and Zn retained in soil and the metal concentrations in Korean raspberry plant. Forty five soil samples were collected from 2 to 6 years old Korean raspberry cultivation fields (RCFs), Gochang, Korea, to determine total, exchangeable (1.0 M $MgCl_2$-extractable), DTPA-extractable metal contents. The leaves and fruits of raspberry plant were sampled at harvest stage. Total metal contents in soils ranged from $0.87mg\;kg^{-1}$ to $66.82mg\;kg^{-1}$. Exchangeable and DTPA-extractable metals ranged between 0.02 and $0.67mg\;kg^{-1}$ and between $0.05mg\;kg^{-1}$ and $7.07mg\;kg^{-1}$, respectively. The metal concentrations in the plant leaf and fruit determined on a dry-basis were between $1.30mg\;kg^{-1}$ and $38.82mg\;kg^{-1}$ and between $0.05mg\;kg^{-1}$ and $21.51mg\;kg^{-1}$, respectively, but Cd and Pb were not detected in the leaf. The total, exchangeable, and DTPA-extractable contents of the metal ions in soil were directly correlated one another, but the contents of different metals in the different fractions were inversely correlated in general. Most of total and DTPA-extractable metals in the soil were directly correlated with the contents of the same metals in the plant, whereas exchangeable metals in the soil were not statistically correlated with the same metals in plants. Thus, we concluded that the metal contents in the raspberry field soils were much lower thanthe levels of Soil Contamination Warning Standard (SCWS), and the plant metal concentrations were also less than the maximum permissible limits. The total and DTPA-extractable metals in the soil were closely related to the metal concentrations in the plant.