• 한국환경과학회지
• /
• 제11권6호
• /
• pp.561-567
• /
• 2002

This study was investigated to evaluate the effect of the sodium ion and pH on toxicity of dinitrophenol at high concentrations (0.41 to 0.54 mM), over a sodium concentration range of 0.1 mM to 107 mM and over a pH range of 5 to 9. The concentration of sodium ions in the activated sludge mixed liquor seemed to have very little effect on dinitrophenol toxicity. However, lack of sodium in the growth media resulted in a reduction of the dinitrophenol degradation rate by bacterial isolate from the activated sludge culture, which has been identified as Nocardia asteroides. Dinitrophenol inhibition was found to be strongly dependent on mixed liquor pH. The dinitrophenol degradation rate was highest in the pH range of 6.95 to 7.84; at pH 5.94 degradation of 75 mg/L dinitrophenol was significantly inhibited; at pH < 5.77, dinitrophenol degradation was completely inhibited after approximately 30% of the dinitrophenol was degraded.

• 대한화학회지
• /
• 제16권4호
• /
• pp.249-256
• /
• 1972

하동 kaolin을 NaOH용액으로 처리하여 그의 결정성을 X-선 분말회절법으로 조사하였다. 각 결정 생성의 최적 처리 조건은 다음과 같다. <표> Sodium A zeolite 결정 생성을 위해 적당한 $Na_2O 대 SiO_2$의 비는 0.5${\sim}$1.5이다. 생성된 Sodium A zeolite 의$ 25^{\circ}C$, 0.2N $CaCl_2$ 용액에서의 $Ca^{++}ion$ 교환능은 이론값의 65%였다.

• 전기화학회지
• /
• 제18권4호
• /
• pp.161-171
• /
• 2015

수열합성법을 이용하여 $Zn_2GeO_4$ 및 $Zn_2SnO_4$ 나노선을 대량 합성하였고 리튬이온 전지와 소듐이온전지의 전기화학적 특성을 조사하였다. 리튬이온전지에서 $Zn_2GeO_4$ 나노선은 50 사이클 이후에 1021 mAh/g, $Zn_2SnO_4$ 나노선은 692 mAh/g의 높은 방전용량을 갖는 것을 확인하였고 두 나노선 모두 98%가 넘는 쿨롱 효율을 보였다. 따라서 이들 나노선은 고성능 리튬이온전지의 개발을 위한 음극소재로 기대된다. 또한 소듐이온전지에 대한 관심이 국내는 물론 전 세계적으로 집중이 되고 있어 처음으로 $Zn_2GeO_4$과 $Zn_2SnO_4$ 나노선에 대한 소듐이온전지를 제작하여 용량을 측정하였다. 측정한 결과 이들 나노선은 50 사이클 이후에 각각 168 mAh/g 과 200 mAh/g의 방전용량을 갖는 것을 확인하였고 두 나노선 모두 97%가 넘는 높은 쿨롱 효율을 보였으며 이에 우리의 첫 시도가 앞으로 많은 연구에 기여할 것으로 예상한다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
• /
• pp.705-710
• /
• 2003

In this study, to confirm the diffusion coefficient of chloride ion is affected by the concentration of NaCl solution, capacity of voltage, time of an electric current, the diffusion coefficient of chloride ion in concrete was investigated through an electrochemical accelerated test. and the results of these test were compared with the diffusion coefficient of chloride ion by test of sodium chloride solution digestion. As the results of this study, the diffusion coefficient of chloride ion wasn't affected by the concentration of NaCl solution, capacity of voltage, time of an electric current within the range of this study and was similar to the diffusion coefficient of chloride ion by test of sodium chloride solution digestion.

• 한국환경과학회지
• /
• 제9권5호
• /
• pp.437-441
• /
• 2000

A study on the removal of Pb ion from Pb-contaminated soil was carried out using ex-site extraction process. Tartaric acid (TA) and iminodiacetic acid sodium salt(IDA) as a washing agent were evaluated as a function of concentration reaction time mixing ratio of washing agent and recycling of washing agent. TA showed a better extraction performance than IDA. The optimum washing condition of TA and IDA were in the ratio of 1:15 and 1:20 between soil and acid solution during 1 hr reaction. The total concentrations of Pb ion by TA and IDA at three repeated extraction were 368.8 ppm and 267.5 ppm respectively. The recovery of Pb ion from washing solution was achieved by adding calcium hydroxide and sodium sulfide form the precipitation of lead hydroxide and lead sulfide and optimum amounts of sodium sulfide and calcium hydroxide were 7 g/$\ell$ for the TA washing solution and 4 g/$\ell$, 5g/$\ell$ for the IDA washing solution respectively. The efficiency of recycle for TA and IDA washing solution were 78.8% , 95.1%, and 89.2%, 96.6% at third extractions under $Na_2S$ and $Ca(OH)_2$, respectively.

• 한국표면공학회지
• /
• 제50권4호
• /
• pp.237-243
• /
• 2017

We demonstrated the thin film deposition of sodium phosphorous oxynitride (NaPON) via RF magnetron sputtering of $Na_3PO_4$, as a solid-state Na-ion conductor similar to lithium phosphorous oxynitride (LiPON), which is a commonly used solid electrolyte. The deposited NaPON thin film was characterized by scanning electron microscopy, X-ray diffractometry, and electrochemical impedance spectroscopy, to investigate the feasibility of the solid-state electrolyte in several different cell configurations. The key properties of a solidstate electrolyte, i.e., ionic conductivity and activation energy, were estimated from the complex non-linear least square fitting of the measured impedance spectra at various temperatures in the range of $27-90^{\circ}C$. The ionic conductivity of the NaPON film was measured to be $8.73{\times}10^{-6}S\;cm^{-1}$ at $27^{\circ}C$, which was comparable to that of the LiPON film. The activation energy was estimated to be 0.164 eV, which was lower than that of the LiPON film (0.672 eV). The obtained values encourage the use of a NaPON thin film in the future as a reasonable solid-state electrolyte.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 1995년도 춘계학술대회 논문집
• /
• pp.100-105
• /
• 1995

$Na_2O$함량 20, 52, 30 mol% 변화를 준 $Na_2O$-CaO-$Al_2O_3$-$B_2O_3$-$SiO_2$계 유리를 제조하여 $AgNO_3$용융염에 각각 0, 24, 36, 48 시간동안 이온교환처리를 행한후 시편의 전기적 특성을 분석하였다. 이온 교환처리된 유리의 저항값과 활성화에너지값이 이온교환처리 되지 않은 모유리보다 낮았다. $Na_2O$의 함량이 증가할수록, 이온교환시간이 증가할수록 전기전도도는 증강하였다. 본 실험에서는 $Na_2O$ 함량 30 mol%의 유리를 48시간 이온교환시킨후의 시료의 전기전도도가 제일 좋았으면 $200^{\circ}C$ 에서의 전기전도도는 $1.78\times$$10^{-4}$S/cm이었다.

• 분석과학
• /
• 제5권4호
• /
• pp.425-431
• /
• 1992

$La(OH)_3$ 공침에 의한 극미량 인산이온의 부선 및 농축에 관한 연구를 가시/자외선 분광광도법을 이용하여 수행하였다. 암모니아용액으로 조절한 pH 9.5의 1.0L 시료용액 중 인산 이온을 수산화란탄 침전에 공침시켰다. 1:8의 sodium oleate와 sodium dodecyl sulfate 혼합 계면활성제를 가하고 질소기체를 bubbling하여 침전들을 용액 표면으로 띄웠다. 뜬 침전들을 감압 플라스크에 모은 다음 용액을 걸러 버리고 침전을 묽은 암보니아용액으로 씻고 황산에 녹였다. 몰리브덴 청색법으로 농축된 용액 중 인산이온을 정량하였다. 이상의 방법으로 수도물과 강물 중 인산이온을 분석하였고 각 시료에 인산이온을 20.0ng/mL 가하여 분석한 결과 각각 93%와 86%의 회수율을 얻었다.

• 한국세라믹학회지
• /
• 제37권2호
• /
• pp.117-121
• /
• 2000

Er-doped sodiumborosilicate glass films for waveguides amplifier were fabricated by Aerosol Flame Deposition(AFD) method. Al2O3 was added to sodium borosilicate glass films to suppress the formation of crystalline phase and control the refractive index. the formation of crystalline phase was suppressed above Al2O3 of 6 wt%. As the amount of Al2O3 increased from 2 to 12 wt% the refractive index of glass films increased lineary from 1.4595 up to 1.4710. After the core of 77SiO2-15B2O3-8Na2O＋6 wt%Al2O3＋8wt%Er2O3 was coated on the buffer layer of 77SiO2-15B2O3-8Na2O＋6 wt%Al2O3, the core was etched by reactive ion etching. The absorption spectrum of 3 cm waveguide amplifier showed two peaks of 1530 and 1550 nm.

• 한국환경과학회지
• /
• 제18권6호
• /
• pp.595-601
• /
• 2009

The effects of the cation-to-anion resin ratio and bed depth on ion exchange performance of mixed-bed were studied at ultralow solution concentration. Breakthrough curves were experimentally obtained for NaCI solution as functions of resin ratio and bed depth. The bed depth affects the pattern of the sodium breakthrough curve but not the chloride breakthrough curve in beds because of the selectivity difference. Resin selectivity determines the shape of breakthrough curves, Some sodium and chloride breakthrough curves crossed at a point as a function of resin ratio. The lower cation-to-anion resin ratio showed the higher effluent concentration or treated volume of the crossover point regardless of the total resin weight.