• 한국수소및신에너지학회논문집
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• 제26권1호
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• pp.54-63
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• 2015

The secondary battery using sodium is investigating as one of power storage system and power in electric vehicles. The secondary battery using sodium as a sodium battery and sodium ion battery had merits such as a abundant resources, high energy density and safety. Sodium battery (sodium molten salt battery) is operated at lower temperature ($100^{\circ}C$) compared to NAS and ZEBRA battery ($300{\sim}350^{\circ}C$). Sodium ion battery is investigating as one of the post lithium ion battery. In this paper, it is explained for the principle and recent research trends in sodium molten salt and sodium ion battery.

• E2M - 전기 전자와 첨단 소재
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• 제9권3호
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• pp.284-290
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• 1996

The electrical properties of bulk galsses in the system Na$_{2}$O-CaO-Al$_{2}$O$_{3}$-B$_{2}$O$_{3}$-SiO$_{2}$ containing 20 to 30mol% sodium which have been subjected to a sodium .tautm. silver ion exchange reaction for 24, 36 and 48 hrs. were analysed by impedance spectroscopy method. Ion exchanged glasses exhibit activation energy values lower than those of the untreated ones. The electrical conductivity increase with sodium content and ion exchanging time. In this experiment the electrical conductivity exhibits a manximum value of 1.78*10$^{-4}$ S/cm at 200.deg. C which contains 30mol% sodium and subjects ion exchange reaction for 48hrs.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1474-1476
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• 2004

A sodium ion- selective electrode based on dibenzopyridino-18-crown-6 as membrane carrier was successfully prepared. The electrode exhibits a Nernstian response for $Na^+$ ions within the concentration range of $1.0\;{\times}\;10^{-4}-1.0\;{\times}\;10^{-1}$ M. The response time of the sensor is 20 s. The sodium ion-selective electrode exhibited comparatively good selectivities with respect to alkali, alkaline earth and some transition metal ions.

• 한국약용작물학회지
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• 제23권6호
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• pp.446-453
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• 2015

Background : Excessively high concentration of sodium ion causednutrient deficiency and significantly decrease growth. This study was carried out to determine the limiting concentration range of sodium ion in the soil of ginseng field. Methods and Results : The growth of the ginseng cultivar Chunpoong reduced with increase in salinity, and the rate of growth reduction was higher in shoots than that of roots. Particularly, ginseng plants cultivated at high level of nitrate nitrogen or sodium may suffer delayed development and stunted growth. Chlorophyll damage occurred on the leaves of ginseng planted in relatively high levels (> $0.2cmol^+/kg$) of sodium ion, as determined by the fluorescence reaction. The incidence of physiological disorder in ginseng cultivated at 249 sites was correlated with the concentration of sodium ion in the soils. About 74% of ginseng fields in which physiological disorders occurred had concentrations of sodium ion in soil greater than $0.2cmol^+/kg$. In contrast, the concentration of sodium ions at 51 of 85 sites where no damage occurred was relatively ($0.05cmol^+/kg-0.15cmol^+/kg$). Conclusions : The concentration of sodium ion in soil of ginseng fields can be classified into three levels optimum (${\leq}0.15$), permissible allowance (0.15 - 0.2) and excessive (> 0.2).

• Bulletin of the Korean Chemical Society
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• 제22권4호
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• pp.405-408
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• 2001

New lipophilic triesters of calix[4]arene and calix[4]quinone are investigated as sodium ion-selective ionophores in poly(vinyl chloride) membrane electrodes. For an ion selective electrode based on calix[4]arene triester I, the linear response is 1 ${\times}$10-3.5 to 1 ${\times}$ 10-1 M of Na+ concentrations. The selectivity coefficients for sodium ion over alkali metal and ammonium ions are determined. The detection limit (logaNa+ = -4.50) and the selectivity coefficient (logKNa+,K+pot = -1.86) are obtained for polymeric membrane electrode containing calix[4]arene triester I.

• Journal of Electrochemical Science and Technology
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• 제13권1호
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• pp.32-53
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• 2022

Although lithium-ion batteries are currently the most reliable power supply system for various mobile applications, further improvement in energy density is still required as the need for batteries in large energy-consuming devices is rapidly growing. However, in the anode, the most widely commercialized graphite-based anode materials almost face theoretical limitations. In addition, sodium-ion batteries have been actively studied to replace expensive charge carriers with cheaper ones. Accordingly, conversion-based materials have been extensively studied as high-capacity anode materials in both lithiumion batteries and sodium-ion batteries because their theoretical capacity is twice or thrice higher than that of insertion-based materials. This review will provide a comprehensive understanding of conversion-based materials, including basic charge storage behaviors, critical drawbacks that should be overcome, and practical material design for high-performance.

• 한국세라믹학회지
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• 제18권2호
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• pp.91-98
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• 1981

Synthetic zeolite A was prerared from domestic Hadong kaolin with sodium hydroxide solution and their ion exchange isotherms of $K^+$, $NH^{4+}$, $Li^+$ and $Ag^+$ ion were presented. The optimum reaction conditions for synthetic zeolite A from calcinated kaolin were 2 fold excess of 2N sodium hydroxide solution, 10$0^{\circ}C$ and 8 hours. It was observed that before the crystallization of zeolite A the samples reacted with sodium hydroxide solution had rather higher ion exchange capacities than zeolite A. The $K^+$-$Na^+$ and $Ag^+$$Na^+$ ion exchange isotherms were signoidal. The initial selectivity series was in the order $Ag^+$$K^+$>$Na^+$>$NH_4$>$Li^+$. Between approximately 33 and 67% replacement of soium ions the selectivity series became $Na^>$ and above 67% became $Ag^+$>$K^+$. Evidence were also presented to demonstrate that 8 out of 12 sodium ions per pseudo unit cell were not easily replaceable by lithium ions and 4 out of 12 not easily replaceable by ammonium ions.

• 한국염색가공학회지
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• 제23권1호
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• pp.51-59
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• 2011

Calcium alginate fiber were prepared by wet spinning of various conditions, including different concentrations of sodium alginate solution and $CaCl_2$ concentrations for coagulating the fiber through an absorption of calcium ion. The absorption of calcium ion during the coagulating step lead to solidify the fibers by the replacement of sodium ion with calcium ion to produce some crosslinking. The concentration of calcium ion in the calcium alginate fiber seems to be well related to the mechanical and physical property of the fiber, such as fiber strength moisture regain, and degree of swelling. The tensile strength of calcium alginate fiber was increased along with the increasing amount of sodium alginate solution. According to EDS analysis, 7 wt% $CaCl_2$ coagulation bath resulted in more calcium ion in the fiber compared to 3 wt% $CaCl_2$ coagulation bath. The decomposition temperature of calcium alginate fiber was $199^{\circ}C$, which $14^{\circ}C$ higher than that of sodium alginate.

• 한국지하수토양환경학회지:지하수토양환경
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• 제28권6호
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• pp.16-23
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• 2023

Heavy metal (Zinc, Cadmium, Lead) adsorption onto surface modified activated carbon was performed in order to better understand the effect of sodium ion addition to activated carbon. Surface modification methods in this research included water washing, nitric acid washing, and sodium addition after nitric acid washing. These surface modifications generated oxygen functional groups with sodium ions on the surface of the activated carbon.. This caused the change of the specific surface area as well as in the ratio of the carboxyl groups. Heavy metal adsorption onto sodium-containing activated carbon was the most among the three modifications. After the adsorption of heavy metals, the carboxyl group ratio decreased and sodium ions on the surface of the activated carbon were almost non-existent after the adsorption of heavy metals onto sodium-containing activated carbon. The results from this research indicated that ion exchange with sodium ions in carboxyl groups effectively improved heavy metal adsorption rather than electrostatic adsorption and hydrogen ion exchange.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.1-13
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• 2019

Na-ion batteries are being considered as promising cost-effective energy storage devices for the future compared to Li-ion batteries owing to the crustal abundance of Na-ion. However, the large radius of the Na ion result in sluggish electrode kinetics that leads to poor electrochemical performance, which prohibits the use of these batteries in real time application. Therefore, identification and optimization of the anode, cathode, and electrolyte are essential for achieving high-performance Na-ion batteries. In this context, the current review discusses the suitable high-voltage cathode materials for Na-ion batteries. According to a recent research survey, sodium vanadium fluorophosphate (NVPF) compounds have been emphasized for use as a high-voltage Na-ion cathode material. Among the fluorophosphate groups, $Na_3V_2(PO_4)_2F_3$ exhibited the high theoretical capacity ($128mAh\;g^{-1}$) and working voltage (~3.9 V vs. $Na/Na^+$) compared to the other fluorophosphates and $Na_3V_2(PO_4)_3$. Here, we have also highlighted the classification of Fluorophosphates, NVPF composite with carbonaceous materials, the appropriate synthesis methods and how these methods can enhance the electrochemical performance. Finally, the recent developments in NVPF for the application in energy storage devices and its outlook are summarized.