Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Challenges and Design Strategies for Conversion-Based Anode Materials for Lithium- and Sodium-Ion Batteries

  • Kim, Hyunwoo (Department of Energy Science, Sungkyunkwan University) ;
  • Kim, Dong In (Department of Energy Science, Sungkyunkwan University) ;
  • Yoon, Won-Sub (Department of Energy Science, Sungkyunkwan University)
  • Received : 2021.09.15
  • Accepted : 2021.10.21
  • Published : 2022.02.28
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Abstract

Although lithium-ion batteries are currently the most reliable power supply system for various mobile applications, further improvement in energy density is still required as the need for batteries in large energy-consuming devices is rapidly growing. However, in the anode, the most widely commercialized graphite-based anode materials almost face theoretical limitations. In addition, sodium-ion batteries have been actively studied to replace expensive charge carriers with cheaper ones. Accordingly, conversion-based materials have been extensively studied as high-capacity anode materials in both lithiumion batteries and sodium-ion batteries because their theoretical capacity is twice or thrice higher than that of insertion-based materials. This review will provide a comprehensive understanding of conversion-based materials, including basic charge storage behaviors, critical drawbacks that should be overcome, and practical material design for high-performance.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. NRF-2019R1A2C2003731).

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