• Title/Summary/Keyword: Sodium dodecyl benzene sulfonate

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Identification of Aeromonas caviae and the Activity Test for Biodegradation of Sodium Dodecyl Benzene Sulfonate (Aeromonas caviae에 의한 Sodium Dodecyl, Benzene Sulfonate 의 분해조건)

  • 권오근;금두희
    • Journal of environmental and Sanitary engineering
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    • v.8 no.1
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    • pp.81-91
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    • 1993
  • This paper was carried out to isolate and identify Aeromonas caviae which can degrade Sodium Dodecyl Benzene Sulfonate(SDBS) effectively. And the affecting factors for the ability of bacterial degradation were also studied. Frm October 1991 to February 1992, two hundred samples from sweage in Taegu area and Nakdong river waters in Talsung Gun area were tested. Minimal salt medium which contain SDBS only as a carbon source was used as a culture medium. The isolated new strain was identified as Aeromonas caviae Kim & Kweon. The optimal pH for SDBS degradation were 7.0 and temperature, $32^{\circ}C.$ It was taken 24 hours to degrade SDBS of 20mg/l completely under the optimal pH and temperature. And in the case of 30 mg/l of SDBS, it was taken 36 hours. The nitrogen sources were added to the minimal salt media containing 20mg/l of SDBS, and they were incubated at $32^{\circ}C$ for 14 hours. 86.9% SDBS were degraded after addition of 0.03% peptone as a organic nitrogen source. And 70.5% SDBS after addition of 0.05% ammonium sulfate as a inorganic nitrogen source. In the case of metal compounds(0.015%), the degradation rate for SDBS were 3.5 fold increased in the media containing magnesium chloride and calcium chloride than in the media that were not containing these metal compounds. And where the media containing magnesium chloride was 0.05%, the degradation rate was 65.8%. And above 0.3% NaCI, the degradation rate was decreased slowly.

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Electrochemical Determination of Ciprofloxacin Based on the Enhancement Effect of Sodium Dodecyl Benzene Sulfonate

  • Zhang, Shenghui;Wei, Shuang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.543-546
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    • 2007
  • Herein, a new electrochemical method was described for the determination of ciprofloxacin based on the enhancement effect of an anionic surfactant: sodium dodecyl benzene sulfonate (SDBS). In pH 4.0 phosphate buffer and in the presence of 1.0 × 10-4 mol/L SDBS, ciprofloxacin yields a well-defined and sensitive oxidation peak at the carbon paste electrode (CPE). Compared with that in the absence of SDBS, the oxidation peak current of ciprofloxacin remarkably increases in the presence of SDBS. The experimental parameters, such as supporting electrolyte, concentration of SDBS, and accumulation time, were optimized for ciprofloxacin determination. The oxidation peak current is proportional to the concentration of ciprofloxacin over the range from 8.0 × 10-8 to 5.0 × 10-6 mol L-1. The detection limit is 2.0 × 10-8 mol L-1 after 2 min of accumulation. This new voltammetric method was successfully used to detect ciprofloxacin in drugs.

Isolation and Characterization of an Alkaline Cellulase Produced by Alkalophilic Bacillus sp. HSH-810 (알칼리성 Cellulase를 생산하는 호알칼리성 Bacillus sp. HSH-810의 분리 및 효소 특성)

  • 김지연;허성호;홍정화
    • Korean Journal of Microbiology
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    • v.40 no.2
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    • pp.139-146
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    • 2004
  • A bacterium producing alkaline cellulase was isolated from soil, leaf mold and compost, and was identified as alkalophilic Bacillus sp. HSH-810 by morphological, cultural and biochemical determination. The optimum cul-ture condition of Bacillus sp. HSH-810 for the growth and alkaline cellulase production was $30^{\circ}C$ and pH 10.0. The maximum alkaline cellulase production was obtained when 1.0%(w/v) CMC, 0.5%(w/v) peptone, 0.02%(w/v) $CaCl_2$ and 0.02(w/v) $CoCl_2$ were used as carbon source, nitrogen source and mineral source, respectively. The optimum pH and temperature of the enzyme activity were pH 10.5 and $50^{\circ}C$, respectively. This enzyme was fairly stable in the pH range of 6.0-13.0 and at $50^{\circ}C$. For the effect of surfactants, the activity of alkaline cellulase was stable in the presence of sodium-$\alpha$-olefin sulfonate (AOS), sodium dodecyl sulfonate (SDS), Tween 20 and Tween 80, but inhibited by the presence of 0.1 linear alkyl-benzene sulfonate (LAS) sig-nificantly.

Growth and Biodegradability of Facultative Psychrophilic SDBS-degrading Pseudomonas spp. (Facultative Psychrophilic Pseudomonas spp.의 생장 및 SDBS분해능에 대하여)

  • 이혜주
    • Korean Journal of Microbiology
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    • v.19 no.4
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    • pp.179-185
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    • 1981
  • Facultative psychrophilic bacteria utilizing SDBS (Sodium Dodecyl Benzene Sulfonate) as their carbon source were isolated in the Han River. All of these isolated faculatative psychrophilic bacteria were identified as Pseudomonas spp. The growth and biodegradation rates of Ps.fluorescens LP6, Ps. fluorescens LS6 and Ps. putida LC1 among 8 identified facultative psychrophilic bacteria were investigated with spectrophotometer. The specific growth rates of these three facultative psychrophilic bacteria at $25^{\circ}C$ were higher than those at any other temperatures. However, the final cell yields were the highest for cells grown at $5^{\circ}C$. The biodegradation of SDBS by Ps. fluorescens LP 6 was started at the stationary phase of cells. The biodegradation rate of SDBS by Ps. fluorescens LP6 was the highest when the cells were cultured at $25^{\circ}C$.

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Chemiluminescence Determination of Balofloxacin Based on Europium (III)-Sensitized KBrO3-Na2S2O4 Reaction in Micellar Medium

  • Zhao, Fang;Qi, Yu;Xiong, Wei
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.204-208
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    • 2012
  • A novel chemiluminescence (CL) flow injection method for the determination of balofloxacin is described. The method is based on the weak CL signal arising from the reaction of $KBrO_3$ with $Na_2S_2O_4$ in acidic medium being significantly enhanced by balofloxacin in the presence of europium (III) ion and sodium dodecyl benzene sulfonate (SDBS). The experimental conditions that affected CL intensity were carefully optimized and the CL reaction mechanism was briefly discussed. Under the optimum conditions, the relative CL intensity was proportional to the concentration of balofloxacin in the range of $7.0{\times}10^{-11}$ to $3.0{\times}10^{-7}g\;mL^{-1}$. The detection limit was $2.7{\times}10^{-11}g\;mL^{-1}$ and the relative standard deviation was 2.1% for $7.0{\times}10^{-10}g\;mL^{-1}$ balofloxacin (n = 13). The proposed method was successfully applied to the determination of balofloxacin in pharmaceutical formulations and biological fluids.

Study on the Preparation Process and Properties of Magnetorheological Fluid Treated by Compounding Surfactants

  • Wu, Xiangfan;Xiao, Xingming;Tian, Zuzhi;Chen, Fei
    • Journal of Magnetics
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    • v.21 no.2
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    • pp.229-234
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    • 2016
  • Aiming to prepare high performance magnetorheological fluid, firstly, oleic acid and sodium dodecyl benzene sulfonate are chosen as surfactants. And then, the mechanical stirring process including stirring time, stirring temperature and stirring speed are optimized by measuring sedimentation ratio and zero-field viscosity. Finally, the properties of prepared magnetorheological fluid are elaborated. The results indicate that the compounding of oleic acid and sodium dodecyl benzene sulfonate can improve the properties of magnetorheological fluid distinctively, and the optimistic compounding content is 4g:4g or 5g:5g. The surfactants adding orders and the second stirring time have little effect on the properties of magnetorheological fluid, while obviously of the first stirring time, temperature and speed. Moreover, the sedimentation ratio of prepared magnetorheological fluid is less than 5.2% in two weeks, the zero-field viscosity is smaller than $0.6Pa{\cdot}s$ at $20^{\circ}C$, and the maximum yield stress is higher than 50 kPa.

Stability of concentrated Colloidal Liquid Aphrons containing a quaternary ammonium salt in the continuous phase (사차 암모늄 염을 함유하는 농축된 콜로이드 액상 에이프런의 연속상에서의 안정성)

  • Hahm, Hyung Chul;Hong, Won Hi;Lee, Choul Ho
    • Clean Technology
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    • v.7 no.4
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    • pp.291-297
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    • 2001
  • In this study, the stability of concentrated colloidal liquid aphrons (CLAs) containing Aliquat 336 was measured. CLAs in the continuous phase are stabilized by water-soluble surfactant and oil-soluble surfactant. To compare the stability of CLAs, half-life was introduced. According to the change of state of solution, the rate of break-up of concentrated CLAs changed rigorously at critical coagulation concentration. Critical coagulation concentration was measured with changing pH. The effects of ionic strength and concentration of Sodium Dodecyl Benzene Sulfonate (SDBS) on the stability of concentrated CLAs in the continuous phase were also investigated.

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Plasma Treatment Effect of Organic/Organic Core-Shell Acrylic Adhesive Binder (II) (Organic/Organic Core-Shell 아크릴 접착바인더의 플라즈마 처리영향 (II))

  • Seul, Soo-Duk
    • Polymer(Korea)
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    • v.34 no.2
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    • pp.89-96
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    • 2010
  • Adhesive binders with core-shell structure of organic/organic pair were prepared by emulsion polymerization of acrylic monomers, such as methyl methacrylate(MMA), ethyl acrylate(EA), n-butyl acrylate(BA), and styrene(St). Ammonium persulfate (APS) was used as an water soluble initiator in the presence of an anionic surfactant, sodium dodecyl benzene sulfonate (SDBS). Non-woven fabric and leather were impregnated with the adhesive binder. The surface of the impregnated fabric and leather were treated with plasma technique and then kinetics analysis and mechanical properties were measured. The conversions of the polymerization of core-shell binder (MMA/EA, MMA/BA) were greater than 90%. When the core-shell binder was prepared at equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the impregnated and plasma-treated non-woven/non-woven fabric has the order of MMA/St, EA/BA, BA/MMA, EA/St, and EA/MMA. When the core-shell binder was prepared at non-equimolar conditions, the increasing effect of the core-shell binder on the state peel strength of the non-woven fabric/leather has the order of MMA/BA, BA/EA, MMA/EA, St/MMA, and EA/St.

Extraction of Cd and Pb from Soil by Anionic Surfactant and Ligand NaI (NaI 리간드화 계면활성제에 의한 토양내 Cd과 Pb 추출 연구)

  • Heo, Jung-Hyun;Jeong, Seung-Woo
    • Journal of Soil and Groundwater Environment
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    • v.13 no.5
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    • pp.74-80
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    • 2008
  • Heavy metals, Cd and Pb, in soil were extracted by using anionic surfactants such as AOS (alpha olefin sulfonate), SDS (sodium dodecyl sulfate), and LAS (linear alkyl benzene sulfonic acid). Metal extractability from soil was affected by the carbon number and solution pH of surfactants. LAS showed higher metal extractability due to the acidic solution condition. Although SDS has a fewer carbon number than AOS, it would produce smaller micelles and resulted in more efficient extraction of metals by increased soil contact. Cd extractability of surfactant was twice enhanced by adding NaI as a ligand. However, Pb extractability of surfactant was sometimes reduced by adding NaI. Those ligand effects were dependent on solubility of metal-ligand. The column experiment also showed that SDS having smaller micelles resulted in higher metal extractability than AOS.