• Title/Summary/Keyword: Sodium Sulfate

Search Result 1,285, Processing Time 0.026 seconds

Colour Removal from Aqueous Solutions by Flotation Process (부상공정에 의한 수용액으로부터 색 제거)

  • Roh, Sung-Hee;Yun, Young-Jae;Kim, Jin-Hwan;Kim, Sun-Il
    • Applied Chemistry for Engineering
    • /
    • v.10 no.4
    • /
    • pp.576-580
    • /
    • 1999
  • The removal of colours from aqueous solution and/or dispersions has been studied by dispersed-air flotation, in a semi-batch column. Two colours were used for the experiments: Basic Yellow 28(basic) and Direct Orange 31(basic). All two effectively removed by flotation within 8 min. Sodium dodecyl sulfate, sodium oleate and amines were found to be effective as collectors in the removal of colour, which was found to be related to the pH of the solution and the amount of collector added to it, with high collector dosages causing the process to become pH-independent.

  • PDF

Enhancement by Surfactant on Release of $\alpha$-Amylase and Phosphatase in Submerged Culture of Rhizopus oryzae (계면활성제 첨가배양에 따른 Rhizopus oryzae의 $\alpha$-Amylase와 Phosphatase분비촉진)

  • 윤희주;최영길
    • Microbiology and Biotechnology Letters
    • /
    • v.13 no.4
    • /
    • pp.403-408
    • /
    • 1985
  • Enhancement of surfactant on release of secretory enzyme, such as $\alpha$-amylase, acid phosphatase and alkaline phosphatase, was investigated during submerged culture of Rhizopus oryzae. Morphological changes of colony was occured; small pelletal form in 0.18mM of sodium dodecyl sulfate, pulpy form in 0.48mM of sodium deoxycholate, and filamentous form in absence of surfactant. It. Supplement of sodium dodecyl sulfate induced 9 times increasing activity of $\alpha$-amylase and that of acid phosphatase 25 times in cultural fluids. Alkaline phosphatase was increased 11 times in cultural fluid and also stimulated in cytoplasm with supplement of sodium deoxycholate.

  • PDF

Synthesis of nano Cerium(IV) oxide from recycled Ce precusor (재생 세륨 전구체로부터 나노산화세륨(IV)합성)

  • Kang, Tae-Hee;Koo, Sang-Man;Jung, Choong-Ho;Hwang, Kwang-Taek;Kang, Woo-Kyu
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.23 no.2
    • /
    • pp.101-107
    • /
    • 2013
  • Cerium compounds such as Cerium hydroxide ($Ce(OH)_3$), Cerium chloride ($CeCl_3{\cdot}nH_2O$), Cerium carbonate hydrate ($Ce_2(CO_3)_3{\cdot}8H_2O$), Cerium oxide ($CeO_2$) were synthesized using recycled Ce precursor. Cerium(IV) oxide of nanoparticles were obtained by Ultra-sonication. Cerium-sodium- sulfate compound was synthesized through acid-leaching and addition of sodium sulfate from 99 wt% purity of Ce precursor as a starting material that was recycled from the waste polishing slurry. Moreover Cerium hydroxide was obtained from Cerium-sodium-sulfate compound by adding to sodium hydroxide solution. Then Cerium chloride was synthesized by adding of hydrochloric acid to Cerium hydroxide. Needle-shaped Cerium carbonate hydrate was synthesized in the continuous process and Cerium(IV) oxide with 30~40 nm size was subsequently obtained by the calcinations and dispersion.

Evaluation on the Sulfate Attack Resistance of Cement Mortars with Different Exposure Conditions (노출조건에 따른 시멘트 모르타르의 황산염침식 저항성 평가)

  • Lee, Seung Tae
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.32 no.6A
    • /
    • pp.427-435
    • /
    • 2012
  • In order to evaluate the effects of exposure conditions on the resistance to sulfate attack of normal and blended cement mortars, several mechanical characteristics of the mortars such as expansion, strength and bulk density were regularly monitored for 52 cycles under sodium sulfate attack. The mortar specimens were exposed to 3 different types of exposure conditions; 1) continuous full immersion(Exposure A), continuous half-immersion(Exposure B) and cyclic wetting-drying(Exposure C). Experimental results indicated that the maximum deterioration was noted in OPC mortar specimens subjected to Exposure B, showing the wide cracks in the portions where attacking solution is adjacent to air. Additionally, the beneficial effect of ground granulated blast-furnace slag and silica fume was clearly observed showing a superior resistance against sodium sulfate attack, because of its lower permeability and densified structure. Thus, it is suggested that when concrete made with normal cement is exposed to sulfate environment, proper considerations on the exposure conditions should be taken.

Sulfate Resistance of Cement Matrix Containing Limestone Powder

  • Moon Han-Young;Jung Ho-Seop;Lee Seung-Tae;Kim Jong-Pil
    • Journal of the Korea Concrete Institute
    • /
    • v.16 no.3 s.81
    • /
    • pp.433-440
    • /
    • 2004
  • In order to improve the performance of concrete, generally, modern cements often incorporate several mineral admixtures. In this study, the experimental included the flow value, air content of mortar containing limestone powder and length change and compressive strength of mortar specimen immersed in sulfate solutions. From the experimental results, the limestone powder cement matrices improved the physical properties and sulfate resistance of cement matrices at $10\%$ replacement ratio of limestone powder. The $30\%$ replacement ratio of limestone powder was significantly deteriorated in sodium sulfate solution. Irrespective of fineness levels of limestone powder, length change and SDF of mortar specimens with only $10\%$ replacement was much superior to the other replacements.

Sulfate Attack on the Cation Type Accompanying $SO_4^{2-}$ (황산이온과 결합하는 양이온의 종류에 따른 황산염침식)

  • Moon, Han-Young;Kim, Seong-Soo;Jung, Ho-Seop;Lee, Seung-Tae;Kim, Jong-Pil;Koh, Joon-Ho
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2006.05b
    • /
    • pp.221-224
    • /
    • 2006
  • This paper reports a study carried out to investigate sulfate attack caused by cation type(sodium, magnesium) accompanying $SO_4^{2-}$ ions in sulfate solutions. The sulfate attack of mortar specimens was evaluate using the visual appearance, compressive strength loss and expansion. In addition, at the end of 360 days, the products of sulfate attack and the mechanism of attack were investigated through x-ray diffraction.

  • PDF

Optimal Synthesis Conditions of Barium Sulfate (황산바륨의 최적합성조건)

  • 신화우;최광식
    • YAKHAK HOEJI
    • /
    • v.46 no.5
    • /
    • pp.364-368
    • /
    • 2002
  • Optimal synthetic conditions of barium sulfate were investigated from the viewpoint of yield and bulkiness according to a randomized complete block design proposed by Box and Wilson. Barium chloride and Sodium sulfate were utilized as reactants in order to prepare barium sulfate in this study. The optimum Synthesis conditions of barium sulfate obtained from this study are as follows; Reactant temperature; 60~75$^{\circ}C$ (viewpoint of yield) and 60~71$^{\circ}C$ (viewpoint of bulkiness). Concentration of two reactants; 12.7~14.4% (viewpoint of yield) and 5~10.5% (viewpoint of bulkiness). Mole ratio of two reactants, [BaCl$_2$]/[Na$_2$SO$_4$]; 1.62~1.96 (viewpoint of yield) and 2.0 (viewpoint of bulkiness). Reacting time; 13~15 minutes (viewpoint of yield) and 12~14 minutes (viewpoint of bulkiness). Drying temperature of product; 86~10$0^{\circ}C$ (viewpoint of yield) and 6$0^{\circ}C$ (viewpoint of bulkiness).

Effects of Magnesium and Sulfate Ions on the Sulfate Attack Resistance of Alkali-activated Materials (알칼리 활성화 결합재 모르타르의 황산염 침식 저항성에 미치는 마그네슘 및 황산 이온의 영향)

  • Park, Kwang-Min;Cho, Young-Keun;Shin, Dong-Cheol
    • Journal of the Korea Concrete Institute
    • /
    • v.29 no.4
    • /
    • pp.415-424
    • /
    • 2017
  • The purpose of this study is to investigate the effect of sulfate (${SO_4}^{2-}$) and magnesium ($Mg^{2+}$) ions on sulfate resistance of Alkali-activated materials using Fly ash and Ground granulated blast furnace slag (GGBFS). In this research, 30%, 50% and 100% of GGBFS was replaced by sodium silicate modules ($Ms(SiO_2/Na_2O)$, molar ratio, 1.0, 1.5 and 2.0). In order to investigate the effects of $Mg^{2+}$ and ${SO_4}^{2-}$, compression strength, weight change, lengh expansion of the samples were measured in 10% sodium sulfate ($Na_2SO_4$), 10%, 5% and 2.5% magnesium sulfate ($MgSO_4$), 10% magnesium nitrate ($Mg(NO_3)_2$), 10% [magnesium chloride ($MgCl_2$) + sodium sulfate ($Na_2SO_4$)] and 10% [magnesium nitrate $(Mg(NO_3)_2$ + sodium sulfate ($Na_2SO_4$)] solution, respectively and X-ray diffraction analysis was conducted after each experiment. As a result, when $Mg^{2+}$ and ${SO_4}^{2-}$ coexist, degradation of compressive strength and expansion of the sample were caused by sulfate erosion. It was found that the reaction of $Mg^{2+}$ with Calcium Silicate Hydrate (C-S-H) occurred and $Ca^{2+}$ was produced. Then the Gypsum ($CaSO_4{\cdot}2H_2O$) was formed due to reaction between $Ca^{2+}$ and ${SO_4}^{2-}$, and also Magnesium hydroxide ($Mg(OH)_2$, Brucite) was produced by the reaction between $Mg^{2+}$ and $OH^-$.

Purification and Characterization of a Bacteriolytic Enzyme from Alkalophilic Bacillus sp.

  • Jung, Myeong-Ho;Kang, In-Soo;Bai, Dong-Hoon;Yu, Ju-Hyun
    • Journal of Microbiology and Biotechnology
    • /
    • v.1 no.2
    • /
    • pp.102-110
    • /
    • 1991
  • Alkalophilic Bacillus sp. YJ-451, which was isolated from soil at several area in Korea, produced a novel type of bacteriolytic enzyme (cell wall peptidoglycan hydrolase) extracellulary. The cell wall hydrolytic activity was identified as a clear zone on sodium dodecyl sulfate polyacrylamide gel electrophoresis containing 0.2% (w/v) cell wall of Bacillus sp. as substrate. This enzyme was successively purified 66 fold with 3.2% yield in culture broth by ammonium sulfate precipitation, CM-cellulose column chromatography, and gel filtration, followed by hydroxylapatite column chromatography. The molecular weight of the purified enzyme was estimated to be 27,000 by sodium dodecyl sulfate polyacrylamide gel electrophoresis and gel filtration column chromatography. The optimum pH and temperature for the activity of the enzyme were pH 10.0 and $50^{\circ}C$, respectively. The enzyme was stable between pH 5.0 and 10.0 and up to $40^{\circ}C$. Among the microorganisms used in this experiment the enzyme was active against most of gram negative strains and the genus Bacillus such as B. megaterium, B. licheniformis, B. circulans, B. pumilus, B. macerans, B. polymyxa. The release of dinitrophenylglutamic acid but not reducing group from cell wall peptidoglycan digested by the enzyme suggested that the enzyme is a kind of peptidase which hydrolyzes the peptide bond at the amino group of D-glutamic acid in the peptidoglycan.

  • PDF