• Title/Summary/Keyword: Soda lime

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The effect of Sodium on the property of CIGS solar cell absorber (CIGS 태양전지 광흡수층에 미치는 나트륨의 영향)

  • Park, Tae-Jung;Ahn, Byung-Tae
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.16-18
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    • 2009
  • CIGS 박막태양전지는 박막태양전지 중 최고 효율(20%)을 보이는 태양전지로 각광받고 있다. 이러한 고효율 태양전지는 Soda-lime glass 를 기판으로 사용한 경우로 기판과 CIGS층의 열팽창계수가 비슷하고 또 나트륨이 CIGS 성장시 확산하여 광흡수층에 유익한 영향을 준다고 알려져 있다. 본 실험에서는 나트륨이 함유된 소다라임유리와 거의 포함하고 있지 않은 코닝유리를 기판으로 사용하여 CIGS 광흡수층의 차이를 분석하였다. SIMS, SEM분석결과 소다라임유리의 CIGS Mo 부근과 표면부위에 Na 농도가 높으며, grain 크기가 코닝에 비해 작음을 알 수 있었다. 전기적 특성은 소다라임유리기판의 경우 p-type 농도가 코닝유리기판에 비해 약 $10^5{\sim}10^6$천배가량 높음을 확인하였다. 셀특성또한 코닝 11%, SLG는 16%로 효율차이가 발생하였으며 이는 나트륨으로 p-type 전도도가 향상되어 효율이 개선되는 것으로 판단된다.

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Effects of Processed Slag as Glassmaking Raw Material (on Soda-Lime Glass) (개질 고로 슬래그에 관한 연구 (유리 제조에 관한 연구))

  • 양중식
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.112-118
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    • 1981
  • A study was made on the processing of domestic blast furnace slag by flotation and chemical purification for the use of slag as a raw material in making soda lime glasses. Feasibility study has been made for the use of reprocessing slag as a source material for both coloring and chemical components (such as CaO, $Al_2O_3$, MgO and etc.) in the glass making process. Chemical composition of chemically purified slags ranges; $SiO_2$ 34.5~37.5, $Al_2O_3$, 16.2~14.1, $Fe_2O_3$ 0.33~0.14, CaO 34.5~38.8, MgO 4.0~5.2, NmO 0.16~0.39, $TiO_2$ 0.23~0.35, S 0.08~0.42, ignition loss 3.3~8.4 and others 0.48~0.51%. It was found that either amber or greenish color could be easily obtained with the addition of salg up to 24%, however the slag addition to glass batches much impaired the transmitancy of glass products, thus a glass made with 7% slag addition showed 82% in transmitancy value at 510 nm.

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Prevention of Exit Crack in Mirco-drilling of Soda-lime Glass (유리의 미세구멍 가공시 출구 크랙 발생 방지)

  • 박병진;최영준;주종남
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.04a
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    • pp.1052-1055
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    • 2001
  • In micro-drilling of brittle materials including glass, cracks occur at the exit surface. In drilling glass, the main type of crack is cone crack. Cone crack is generated by thrust force acting at the bottom surface of the workpiece. Cone crack size could be reduced by changing cutting conditions, but cone crack still existed. Two methods were proposed to prevent crack formation and perfect hole shapes were obtained. One method is attaching two glass plates with water and the other method is constraining two glass plates. The proposed methods eliminated tensile stress acting on the exit surface of glass and prevented crack propagation.

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The Elastic Modulus of the Sintered Glass Frit (Glass Frit 소결체의 탄성계수)

  • 이병철;김명정;류봉기
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1138-1140
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    • 2003
  • To investigate the relation between the sintering degree and the elastic modulus of sintered glass, ball-milled commercial soda-lime-silica glass were used. It was heat-treated at various temperatures and for various times, and then the density and elastic modulus of sintered glass frit were measured. The experimental results showed a strong correlation between them.

Influence of Molten KNO3 Flow Conditions on Mechanical Properties during Fabrication of Chemically-Toughened Glass

  • Kim, Dong-Hwan;Maeng, Jee-Hun;Kim, Dami;Choi, Sung-Churl;Kim, Hyeong-Jun
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.137-139
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    • 2015
  • In this study, we examined the influence of molten $KNO_3$ flow on mechanical properties and their deviation when a chemical toughening process was applied to soda lime silicate glass ($Na_2O-CaO-SiO_2$). $KNO_3$ melt flow was controlled using three methods: (1) glass tray rotation, (2) impeller stirring, and (3) natural convection. DOL and hardness were found to be enhanced by tray rotation because this rotation was able to maintain the concentration around the glass surface, in contrast to other methods. However, there did not appear to be a statistically significant difference in the 3-point bending strength for the three flow conditions due to the ground edge condition.

Removal of Hardness Ions by Crossflow Ceramic Ultrafiltration Process with Adding Lime-soda Ash (석회-소다회를 주입한 십자흐름 세라믹 한외여과공정을 이용한 경도 이온 제거)

  • Park, Jin-Yong;Park, Bo-Reum
    • Membrane Journal
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    • v.17 no.3
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    • pp.191-196
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    • 2007
  • In the study, excess of lime-soda ash(L-S) was added to groundwater for chemical precipitation of hardness ions. After formation of the coagulated flocs, sedimentation step was replaced with crossflow ultrafiltration(UF) process using tubular ceramic membrane. As results, our treated water was below total hardness(TH) 10 mg/L as $CaCO_3$ from groundwater using washing water in a soymilk factory. Then, we investigated the change of permeat flux(J) and dimensionless permeate flux($J/J_0$) during experiments for variations of TMP(Trans-membrane pressure) or flow rate, to see effect of TMP or flow rate on membrane fouling by the coagulated Inorganic flocs. In the result, membrane fouling and rejection rate of total hardness were not affected by TMP and flow rate variations in the range of our experiments.

Effect of Alumina contents in Feldspar and cullet for the Soda-lime glass manufacturing (Soda-Lime Glass에서 Cullet과 장석의 첨가에 따른 Alumina 변화가 제조공정에 미치는 영향)

  • No, Gwang-Hong;Kim, Jong-Ok
    • The Journal of Engineering Research
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    • v.6 no.1
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    • pp.15-27
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    • 2004
  • The first aim of mass product of glass in Automatic bottle glass industry is to decrease the cost and to increase the quality. Second, the cullet is how widely used to save the energy and reducing of ecomaterials. However the physical and chemical properties of Soda-lime glass would be come true at the lower than 2% $Al_2 O_3$. Unfortunately the $Al_2 O_3$ contents of domestic silica is greater than 4% Since small glass class than 200ml bottle is made in domestic silica the producting efficiency would be decreased due to the defect such as cord, knot, devitrite, pore etc. There are many problems such as devitrifiacation and deteriorated effect on production in glass industry became of increasing of plate glass cullet. It is tried to solve these kinds of problems using various analysing methods in this experiments.

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Blackening of Inner Glass Surface in Fluorescent Lamps for LCD Backlight (LCD 백라이트용 형광램프의 흑화 현상)

  • Hwang, Ha-Chung;Jeong, Jong-Mun;Kim, Jung-Hyun;Kim, Dong-Jun;Bong, Jae-Hwan;Chung, Jae-Yoon;Koo, Je-Huan;Cho, Guang-Sup
    • Journal of the Korean Vacuum Society
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    • v.17 no.6
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    • pp.481-486
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    • 2008
  • The different degrees of blackening were observed at the inner surface of borosilicate, soda-lime, and aluminosilicate glass tubes having different sodium (Na) contents. The sodium contents ($Na_2O$) within the borosilicate, soda-lime, and aluminosilicate glass tubes were found to be 4%, 14%, and 0.06%, respectively. The degree of blackening was shown to increase as the sodium content within the glass of the fluorescent lamp containing Ne+Ar+Hg gas mixture. Higher degree of blackening was observed from the inner surface of the glass tube coated with $Y_2O_3$. The blackening was found to be originated from the amalgam of $NaHg_2$ generated by the chemical reaction between the mercury ions within the discharge gas and sodium within the glass tube during operation.