• Applied Chemistry for Engineering
• /
• v.20 no.3
• /
• pp.317-321
• /
• 2009

In order to analyze the high temperature phase formation and the sinterability of super ionic conductor $K^+-{\beta}/{\beta}"-Al_2O_3$ which is commonly used as a solid oxide electrolyte, the pure $K^+-{\beta}/{\beta}"-Al_2O_3$ powder in the ternary system $K_2O-LiO_2-Al_2O_3$ was synthesized by solid state reaction and formed to tube and disk using slip casting method and cold isostatic pressing (CIP), respectively. The slip casting was conducted in an alumina mold with the slurry containing 40 wt% of solid contents and the CIP was carried out under 20 MPa. The samples were sintered at $1600^{\circ}C$, $1700^{\circ}C$ and $1750^{\circ}C$, respectively, and their phase formation and the sintering density were investigated according to the forming method. The samples produced by CIP showed far higher ${\beta}"-Al_2O_3$ fraction as compared with those by slip casting. On the other hand, the samples by slip casting showed slightly higher sintering density. The relative density reached to about 83% at $1750^{\circ}C$ and for 1 h, independent of the forming method. In the case of 90 min socking time, the density was decreased owing to the exaggerated grain growth and the pores by $K_2O$ evaporation.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.3
• /
• pp.14-20
• /
• 2018

Electric vehicles are environmentally friendly because they emit no exhaust gas, unlike gasoline automobiles. However, since they are driven by the electric power from batteries, the distance they can travel based on a single charge depends on their energy density. Therefore, the lithium-ion battery having a high energy density is a good candidate for the batteries of electric vehicles. Since the electrode is an essential component that governs their efficiency, the electrode manufacturing process plays a vital role in the entire production process of lithium-ion batteries. In particular, the coating process is a critical step in the manufacturing of the electrode, which has a significant influence on its performance. In this paper, we propose an innovative process for improving the efficiency and productivity of the coating process in electrode manufacturing and describe the equipment design method and development results. Specifically, we propose a design procedure and development method in order to improve the core plate coating quality by 25%, using a technology capable of reducing the assembly margin due to its high output/high capacity and improving the product capacity quality and assembly process yield. Using this method, the battery life of the lithium-ion battery cell was improved. Compared with the existing coating process, the target loading level is maintained and dispersed to maintain the anode capacity (${\pm}0.4{\rightarrow}{\pm}0.3mg/cm^2r$ reduction).

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.4
• /
• pp.409-414
• /
• 2008

Porous carbon electrode for electrosorption was prepared by a wet phase inversion method. Carbon slurry that was a mixture of activated carbon powder(ACP) and PVdF solution was cast directly upon a graphite sheet by means of a casting knife. Porous carbon electrodes were fabricated by immersing the cast film in pure water as a non solvent. Physical and electrochemical properties of carbon electrodes prepared with various ACP contents(50.0, 75.0, 83.3, 87.5, 90.0 wt %). From the SEM images we can verify that the electrode was porous. The average pore sizes determined for the electrodes fabricated with various ACP contents ranged from 72.7 to 86.4 nm and the size decreased as the ACP content increased. The electrochemical properties were characterized by cyclic voltammetry(CV) method. All of the voltammograms showed typical behavior of an electric double layer charging/discharging on the carbon surface. The capacitance increased with the ACP content and the values ranged from 2.18 F/cm$^2$ for 50 wt% ACP to 4.77 F/cm$^2$ for 90 wt% ACP.

• International Journal of Highway Engineering
• /
• v.17 no.2
• /
• pp.55-62
• /
• 2015

Cracking is an inevitable fact of asphalt concrete pavements and plays a major role in pavement deterioration. Pavement cracking is one of the main factors determining the frequency and method of repair. Cracks can be treated with a number of preventative maintenance actions, including overlay surface treatments such as slurry sealing, crack sealing, or crack filling. Pavement cracks can show up as one or all of the following types: transverse, longitudinal, fatigue, block, reflective, edge, and slippage. Crack sealing is a frequently used pavement maintenance treatment because it significantly extends the pavement service life. However, crack sealant often fails prematurely due to a loss of adhesion. Because current test methods are mostly empirical and only provide a qualitative measure of the bond strength, they cannot accurately predict the adhesive failure of the sealant. This study introduces a laboratory test aimed at assessing the bonding of hot-poured crack sealant to the walls of pavement cracks. A pneumatic adhesion tensile testing instrument (PATTI) was adopted to measure the bonding strength of the hot-poured crack sealant as a function of the curing time and temperature. Based on a limited number of test results, the hot-poured crack sealants have very different bonding performances. Therefore, this test method can be proposed as part of a newly developed performance-based standard specification for hot-poured crack sealants for use in the future. PURPOSES : The purpose of this study was to evaluate both the adhesion and failure performance of a crack sealant as a function of its curing time and curing temperature. METHODS: A pneumatic adhesion tensile testing instrument (PATTI) was adopted to measure the adhesion performance of a crack sealant as a function of the curing time and curing temperature. RESULTS: With changes in the curing time, curing temperature, and sealant type, the bond strengths were found to be significantly different. Also, higher bond strengths were measured at lower temperatures. Different sealant types produced completely different bond strengths and failure behaviors. CONCLUSIONS: The bonding strength of an evaluated crack sealant was shown to differ depending on various factors. Two sealant types, which were composed of different raw materials, were shown to perform differently. The newly proposed test offers the possibility of evaluating and differentiating between different crack sealants. Based on alimited number of test results, this test method can be proposed as part of a newly developed performance-based standard specification for crack sealants or as part of a guideline for the selection of hot-poured crack sealant in the future.

• International Journal of Advanced Culture Technology
• /
• v.3 no.1
• /
• pp.21-30
• /
• 2015

Ceramic foams are prepared as positive images corresponding to a plastic foam structure which exhibits high porosities (85-90%). This structure makes the ceramic foams attractive as a catalyst in a dry reforming process, because it could reduce a high pressure drop problem. This problem causes low mass and heat transfers in the process. Furthermore, the reactants would shortly contact to catalyst surface, thus low conversion could occur. Therefore, this research addressed the preparation of dry reforming catalysts using a sol-gel catalyst preparation via a polymeric sponge method. The specific objectives of this work are to investigate the effects of polymer foam structure (such as porosity, pore sizes, and cell characteristics) on a catalyst performance and to observe the influences of catalyst preparation parameters to yield a replica of the original structure of polymeric foam. To accomplish these objectives industrial waste foams, polyurethane (PU) and polyvinyl alcohol (PVA) foams, were used as a polymeric template. Results indicated that the porosity of the polyurethane and polyvinyl alcohol foams were about 99% and 97%. Their average cell sizes were approximate 200 and 50 micrometres, respectively. The cell characteristics of polymer foams exhibited the character of a high permeability material that can be able to dip with ceramic slurry, which was synthesized with various viscosities, during a catalyst preparation step. Next, morphology of ceramic foams was explored using scanning electron microscopy (SEM), and catalyst properties, such as; temperature profile of catalyst reduction, metal dispersion, and surface area, were also characterized by $H_2-TPR$ and $H_2-TPD$ techniques, and BET, respectively. From the results, it was found that metal-particle dispersion was relatively high about 5.89%, whereas the surface area of ceramic foam catalysts was $64.52m^2/g$. Finally, the catalytic behaviour toward hydrogen production through the dry reforming of methane using a fixed-bed reactor was evaluated under certain operating conditions. The approaches from this research provide a direction for further improvement of marketable environmental friendly catalyst production.

• Journal of Animal Environmental Science
• /
• v.18 no.sup
• /
• pp.73-80
• /
• 2012

Nitrogen included in animal manure can be used as organic fertilizer if it is treated properly but it may cause serious air and water pollution without proper management. Significant amount of nitrogen losses happen in the form of ammonia when the manure staying in animal house and storage facilities and being composted and applied to the field. In order to maximize the manure nitrogen utilization, it is important to understand the mechanisms of nitrogen loss during the diverse manure handling and treatment procedures. The plant available nitrogen portion of total nitrogen in excreted manure was evaluated based on animal type, animal manure collection system, manure treatment process, and application method. About 27% of nitrogen included in excreted pig manure could be plant available if it is applied to the filed after composting process. The plant available nitrogen portion varies from 29% (surface application) to 54% (solid injection) based on application method of digestated piggery slurry. Plant can use 18% of manure nitrogen if the composted cattle and poultry manure applied to the field using surface application method. Manure treatment and application methods need to be carefully selected to control and utilize the manure nitrogen properly.

• Journal of the Korea Institute of Building Construction
• /
• v.9 no.5
• /
• pp.63-70
• /
• 2009

This study is part of an ongoing research project on the development of a sound-absorbing lightweight foamed concrete manufactured by a hydro-thermal reaction between silica and calcium. As the silica source, pulverized bottom ash was used, and as several cementitious powders of ordinary portland cement, alumina cement and calcium hydroxide were used. Manufacture of foamed concrete was accomplished using the pre-foaming method to make a continuous pore system, which is the method of making the foam by using a foaming agent, then making the slurry by mixing the foam, water, and powders. The experiment factors are W/B, foam agent dilution ratio, and foam ratio, and test items are compressive strength, dry density, void ratio, and absorption rate, as evaluated by NRC. The experiment results showed that the sound absorption of lightweight foamed concrete satisfied NRC requirements for the absorbing materials in most of the experiments. It is thus concluded that foam ratio was the most dominant factor, and significantly affected all properties of lightweight foamed concrete in this study. W/B rarely affected total void ratio and continuous void ratio as well as compressive strength, and dry density and foam agent dilution ratio also had little effect onalmost all properties. The analysis of the correlation between NRC, absorption time, continuous void ratio, and absorption time showed that the interrelationship of the continuous void ratio was high.

• Journal of the Korean Geosynthetics Society
• /
• v.14 no.2
• /
• pp.95-103
• /
• 2015

In this study, the causes and countermeasures for the leakage of a sea dyke under construction are analyzed. In general, the seabed ground is clearly divided from the embankment but a lot of parts show abnormal zones with low resistivity from the results of electric resistivity survey. Hence the causes of the leakage are considered as following: three-dimensional shear strain behavior, irregular compulsory replacement of the soft seabed ground with low strength and quality deterioration of the waterproof sheets during the closing process. The improvement method is determined by considering the constructability in the seawater and its velocity condition, durability, economic feasibility, similar application cases and so on. Consequently, a combination of low slump mortar and slurry grouting and injection method is selected as an optimum combination. Mixing ratio and improvement pattern are determined after drilling investigation and pilot test. The improvement boundary is separated into general and intense leakage area. The construction is performed with each pattern and the improvement effects are confirmed. The confirmed effects with various tests after completion show tolerable ranges for all of the established standards. Finally, various issues such as prediction of length of the waterproof sheet, installation of it against seawater velocity, etc. should be considered when sea dykes are designed or executed around the western sea which has high tide difference.

• 한국신재생에너지학회:학술대회논문집
• /
• 2005.06a
• /
• pp.306-309
• /
• 2005

One of the most critical issues in sol id oxide fuel cell (SOFC)running on hydrocarbon fuels is the risk of carbon formation from the fuel gas. The simple method to reduce the risk of carbon formation from the reactions is to add steam to the fuel stream, leading to the carbon gasification react ion. However, the addition of steam to fuel is not appropriate for the auxiliary power unit (APU) and potable power generation (PPG) systems due to an increase of complexity and bulkiness. In this regard, many researchers have focused on so-called 'direct methane' operation of SOFC, which works with dry methane without coking. However, coking can be suppressed only by the operation with a high current density, which may be a drawback especially for the APU and PPG systems. The single chamber fuel cell (SC-SOFC) is a novel simplification of the conventional SOFC into which a premixed fuel/air mixture is introduced. It relies on the selectivity of the anode and cathode catalysts to generate a chemical potential gradient across the cell. Moreover it allows compact and seal-free stack design. In this study, we fabricated honeycomb type mixed-gas fuel cell (MGFC) which has advantages of stacking to the axial direction and increasing volume power density. Honeycomb-structured SOFC with four channels was prepared by dry pressing method. Two alternative channels were coated with electrolyte and cathode slurry in order to make cathodic reaction sites. We will discuss that the anode supported honeycomb type cell running on mixed gas condition.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.56 no.2
• /
• pp.140-145
• /
• 2011

In order to establish the application method of slurry composting & biofilteration liquid fertilizer (SCB LF) in rice cultivation, experiments were studied on split application method of it and effects of it on soil chemical properties and rice yields. Land leveling by rotary tillage within 2 days after application of SCB LF, $NH_4$-N concentration in soil was maintained uniformly in all paddy field. Initial concentrations of $NH_4$-N and $NO_3$-N in soil were high at standard fertilization and 100% application of SCB LF as basal fertilization, however, after tillering stage they maintained similar concentrations in all experimental plots. $NO_3$-N content in infiltration water was slightly lower at 70% application of SCB LF as basal fertilization and 30% application of SCB LF as fertilization at panicle initiation stage than at standard fertilization. Yields of rice by split application of SCB LF were lower at 100% application of SCB LF as basal fertilization, however, those of the other application of SCB LF were similar with that of standard fertilization. In case of rice quality, perfect kernel rates were high and protein contents were lower at non-application and 100% application of SCB LF. Rice quality of 70% application of SCB LF as basal fertilization and 30% application of SCB LF as fertilization at panicle initiation stage were similar with that of standard fertilization.