• Title/Summary/Keyword: Sludge pretreatment

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The Effect of Physico - Chemical Environmental Parameters on Early Composting of Paper - Mill Sludge Cakes (이화학적 환경변수가 제지슬러지케이크의 조기부숙에 미치는 영향)

  • 최홍림;김현태;하호성;정영윤;남상일;서형덕;정원준
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.34 no.3
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    • pp.75-84
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    • 1992
  • The paper manufactories in Sangpyeong Industrial Estates, Chinju, produce more than 80 tons of paper-mill sludge cakes every day, which costs about 840 million won for dump per year. Since the paper-mill sludge is biodegradable, the sludge can he utilized as an organic fertilizer if it is properly decomposed. This may lead to not only dramatic cut of the treatment cost but prevention from secondary environmental contamination due to dump. The primary objective of the study was to explore the quantitative range of major enviromental parameters influencing early composting of paper-mill cakes, naturally pretreated in warn and cold weather. The automatically-controlled reactor was designed, manufactured, and operated for nine days to decompose about 2201 of raw sludge cakes. Four tests(Test 1-Test 4) were implemented for the study of Phase I. Treatments of two levels of initial temperature (40˚C and 28˚C) and two levels of water content + C/N ratio (35% + 40 and 63% + 80) were made to test the significance of their parameters for decomposition of raw sludge cakes pretreated in warm weather. Another four tests (Test 5- Test 8) were implemented for the study of Phase II. Treatments of initial temperature and water content(W/C) + C/N ratio of raw sludge pretreated in cold weather were made to 16˚C and 13% +58 for Test 5, 6˚C and 53% +55 for Test 6, 7˚C and 36% +81 for Test 7, 31˚C and 30% +81 for Test 8. Natural weater condition(pretreatment condition) revealed the importance m composting of the paper-mill sludge cakes. Combination of water content adjustment to about 30% with C/N ratio amendment of about 20 and initial temperature of 30~40˚C was concluded to be the best for early composting of paper-mill sludge cakes with aeration rate and pH fixed. Temperature and C/N ratio were adapted as judging variables for composting degree. In addition, tests for microbial activity were performed to validate the experimental results. Since the temperature and C/N ratio did not coincide in some tests as judging variables for the maturity of the composting sludges, taking one of these parameters could mislead the concept of the maturity (composting conceptually new criterion to provide more reliable information for early composting of paper-mill sludge cakes.

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An Investigation of the Solubilization of Primary Sewage Sludge using Lactic Acid Bacteria Cultured in a Glucose and Yeast Extract Medium (Glucose와 Yeast Extract를 이용하여 배양된 유산균을 이용한 하수 일차 슬러지의 가용화)

  • Lee, Sang Min;Choi, Han Na;Shin, Jung Hun;Lee, Eun Young
    • Microbiology and Biotechnology Letters
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    • v.40 no.4
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    • pp.424-429
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    • 2012
  • The intention of this research was to investigate the solubilization of primary sewage sludge using lactic acid bacteria cultured in a glucose and yeast extract medium. Glucose as the carbon source and yeast extract as the source of nitrogen were chosen as an economic medium with the potential for the mass production of lactic acid bacteria. The optimal concentrations of the medium were 3% (w/v) glucose and 2% (w/v) yeast extract. In this study, in order to improve field applications for the solubilization of sludge at sewage treatment plants, a powdered form of lactic acid bacteria was produced. The optimal inoculum of the powder for the maximum efficiency of solubilization was 1% (w/v). In that condition, the SCOD value increased from 8600 (mg/L) at the beginning of experiment to 10290 (mg/L) at 96 h, with the highest solubilization rate (20.6% DDCOD) and 11.2% (SCOD). Also, the TVFAs of the lactic acid bacteria inoculation group were produced more than that of the control group. In particular, acetic acid was produced 5 times more in the experimental group than in the control group. In this research, the potential of lactic acid bacteria in the pretreatment of primary sewage sludge as a solubilizer, and as an energy source producer for microbial fuel cells was revealed.

Corrosion Protection of Automotive Steels by Novel Water-borne Primer Systems

  • Ooij, William J. van;Puomi, Paula
    • Corrosion Science and Technology
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    • v.6 no.5
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    • pp.239-244
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    • 2007
  • Corrosion protection of automotive steels has traditionally been assured by using a zinc phosphate metal pretreatment followed by the deposition of a cathodic electrocoat system. This system has been developed and optimized over the years into a highly robust and dependable system with a high performance. However, in terms of efficiency and use of resources and energy, the need is now felt to develop a simpler system with fewer steps, shorter lines, less energy requirements (curing and e-coat deposition) and less stringent waste disposal requirement (phosphate sludge). We report here on the development of a one-step system that can possibly replace both the zinc phosphate and the e-coating processes. Such a system is based on the so-called superprimer concept that we have recently developed for the replacement of chromate pretreatment and chromate-containing primers in the aerospace industry. With some modifications, such systems can also be adapted for use in the automotive industry.

Eveluation of Comparable Removal Efficiency of Organics and Color for the Dyeing Wastewater by Fenton Oxidation and Ozonation (펜톤산화와 오존산화 조합에 따른 염색폐수의 유기물질 및 색도 처리효율 비교 평가에 관한 연구)

  • Kim, Sun Hee;Lee, Sang Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.6
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    • pp.778-784
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    • 2004
  • Dyeing wastewater contains recalcitrant organics which can not be easily treated by conventional biological treatment. Therefore it has to be treated by other advanced oxidation process in order to remove COD and Color more efficiently. Fenton oxidation process is one of the most commonly applied processes in removal of COD and color for the dyeing wastewater. However it increase the treatment cost and the production of sludge by the use of the excessive chemical reagent. Ozonation is not suitable in Single treatment process because it is not effective in organics removal compared with Color removal. The purpose of this research in order to evaluate the comparable removal efficiency of COD and color by the combination of advanced oxidation processes for the dyeing wastewater. The sequential treatment processes of Fenton process and ozonation was more effective to remove organics and color than ozonation and Fenton process. The result of Fenton process for the pretreatment presented as the 81% removal of organics whereas ozonation process for the pretreatent presented as the 22.1% removal of organics. The removal of colour was higher as 81.3% for the ozonation as the pretreatment than 77.7% for the Fenton process as the pretreatment.

A Study on the Sludge Reduction and Biogas Production through a Two-phase Anaerobic Digestion Process (이상 혐기성 소화 공정을 통한 슬러지 발생량 저감과 바이오가스 생산에 관한 연구)

  • Woo, Mi-Hee;Han, Gee-Bong
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.9
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    • pp.894-899
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    • 2010
  • We coordinated the experiments with ozone pretreatment and two-phase anaerobic digestion using solid-liquid separation to raise the efficiency of sludge volume reduction and obtained the following results. The pre-treatment with ozone reduced the solid concentration in the average of TSS $8.3{\pm}2.0%$ TSS and $9.2{\pm}}2.8%$ VSS. Of the organic material, TCOD decreased $5.1{\pm}2.4%$, but SCOD showed $72{\pm}6.5%$ increased, which was due to destruction of the cell wall and dissolution of icell media by the powerful oxidative stress of ozone. During the two-phase anaerobic digestion process, we achieved the reduction of $21.5{\pm}3.4%$ TSS, $20.2{\pm}8.4%$ VSS, $32.1{\pm}7.9%$ TCOD and $22.1{\pm}7.2%$ SCOD in average. The maximum methane gas production were 177.6 mL per g TSS, 210.8 mL per g VSS, 127.0 mL per g TCOD and 1452.0 mL per g SCOD, respectively. Solid material reduction through the two-phase anaerobic digestion and MLE (Modified Ludzack-Ettinger) processes were 93.8% of TSS and 92.0% of VSS. We concluded that suggested two-phase anaerobic digestion and MLE process could achieve the reasonable production of biogas and a maximum reduction of the sludge volume.

A Study on the pretreatment of Activated Sludge for Bio-hydrogen Production process (생물학적 수소생산 공정 개발을 위한 오니 슬러지 전처리에 대한 연구)

  • Kim Dong Kkun;Kim Ji Seong;Kim Ho Il;Lee Yu Na;Pak Dae Won
    • 한국생물공학회:학술대회논문집
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    • 2004.07a
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    • pp.21-33
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    • 2004
  • In this study, Anaerobic sewage sludge in a batch reactor operating at $35^{\circ}C$ was used as the seed to investigate the effect of pretreatments of waste activated sludge and to evaluate its hydrogen production potential by anaerobic fermentation. Various pretreatments including physical, chemical and biological means were conducted to utilize for substrate. As a result, SCODcr of alkali and mechanical treatment was 15 and 12 times enhanced, compared with a supernatant of activated sludge. And SCODcr was 2 time increase after re-treatment with biological hydrolysis. Those were shown that sequential hybridized treatment of sludge by chemical & biological methods is most efficient process for sludge treatment. The pre-treatment activated sludge was tested to conform hydrogen production potential in batch experiments. When buffer solution was added to the activated sludge, hydrogen production potential increased as compare with no addition.

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Characterization of Granular Fertilizer Produced by Fly Ash from a Sewage Sludge Incinerator (하수슬러지 소각 비산재를 이용한 입상비료 조립 및 특성분석)

  • Kim, Seong-beom;Lee, Wontae
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.10
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    • pp.574-579
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    • 2016
  • This study assessed feasibility of making granular fertilizer with fly ash from a sewage sludge incinerator in Korea. Composition, characteristics, strength, and heavy metal contents of the granular fertilizers were investigated. Due to its high contents of phosphorus, fly ash from a sewage sludge incinerator could be used to make fertilizers. Granulation rates (2-4 mm granules) over 80% could be achieved as the fly ash contents were 15% or less of the fertilizer. Leaching tests of the fertilizers, based upon the Korean Standard Methods for Solid Wastes, showed the concentrations of heavy metals less than the risk limits. However, contents analysis of the fertilizers, based upon the Korean Standard Methods for Soils, experienced higher levels of heavy metals than the risk limits as the fly ash content exceeded 7% of the fertilizer. Thus, the fly ash needs to be added less than 7% of the fertilizer if there is no pretreatment to remove heavy metals.

The relation between sewage sludge solubilization and extracellular polymeric substances (하수슬러지 가용화와 체외고분자물질(EPS)간의 관계)

  • Jeon, Byeong-Cheol;Nam, Se-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.4
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    • pp.43-49
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    • 2019
  • In order to investigate the relation between sewage sludge solubilization and extracellular polymeric substances(EPS) during alkaline-ultrasonic pretreatment, SCOD/TCOD ratio, solubilization rate, VSS/TS ratio, VSS reduction rate, LB-EPS(Loosely-Bound EPS) and TB-EPS(Tightly-Bound EPS) were measured. At the condition of TS 1.0% and pH 12, solubilization rate increased by 27.7%, LB-EPS as Carbohydrate and Protein increased by 14.6 and 13.3 mg/L/g TS, respectively. Withal, VSS decreased by 26.7% and TB-EPS as Carbohydrate and Protein were extracted by 15.7 and 21.9 mg/L/g TS, respectively. Consequently, the concentrations of organic matter and LB-EPS increased and the trends appeared similarly. In addition, the concentrations trend of decreasing solid matter and extracted TB-EPS also appeared similarly.

Study on Removal of DOC for Effluent from Nitrification and Denitrification Process with Zeolite by Combined Process of Coagulation and UF Membrane (제올라이트를 첨가한 질산화 탈질공정에서 응집과 UF공정을 이용한 처리수내 용존 유기물질 제거 연구)

  • Han, Jang Hyuk;Yoon, Tai Il;Cho, Kyung Chul;Song, Jea Yong
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.537-546
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    • 2005
  • This study was carried out to evaluate EPS and SMP variation of sludge and effluent in nitrification and denitrification process with zeolite addition, a possible reduction of effluent DOC by URC(Ultra Rapid Coagulation) process. As a biological wastewater treatment result, EPS formation of both aeration and anoxic sludges are not affect by SRT variation. However, EPS concentration of sludges is higher in aeration tank than in anoxic tank by 6~8 mg EPS/ g VSS. Linear relationship between SMP to DOC indicates that SMP of bulk solution contributes to most of the biological treatment effluent DOC. DOC and turbidity removal efficiency was more improved with URC process than in a conventional coagulation. For pretreatment of UF filtration DOC removal was advanced by URC process than only UF filtration.

Development of a Low-cost Automatic Water Quality Diagnosis System for Cooling Towers (저가형 냉각탑 자동 수질 진단 시스템 개발)

  • Kim, Jung Hwan;Park, Han-Bin;Kang, Taesam;Park, Jungkeun
    • Journal of Sensor Science and Technology
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    • v.23 no.1
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    • pp.58-65
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    • 2014
  • We developed a low-cost automatic diagnosis system for water quality in cooling towers to measure the concentrations of key ingredients such as $Ca^{2+}$, $Cl^-$, $PO{_4}^{3-}$, and $Fe^{2+}$. $Ca^{2+}$, and $Cl^-$ are the main factors that cause the generation of scale, corrosion, and sludge in water pipes. $PO{_4}^{3-}$ prevents corrosion, sludge and scale by inhibiting the ions (i.e., $Ca^{2+}$, $Cl^-$) from sticking to the pipes. $Fe^{2+}$ is an indicator of pipe corrosion. The proposed system consists of a microprocessor, a specimen container and heater, a precision pump, relays and valves, LED optical sources, and photo detectors. It automatically collects water samples and carries out pretreatment for determining the concentration of each chemical, and then estimates the concentration of each ion using low-cost LED optical sources and detectors. Experimental results showed that the accuracy of the proposed system is sufficiently high for water quality diagnosis and management of cooling towers, demonstrating the possibility of the proposed system's wide usage in real environments.