• Journal of the Korea Institute of Building Construction
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• v.17 no.1
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• pp.47-54
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• 2017

Cement industry is typical carbon-emission industry. If the industrial by-products(granulated blast-furnace slag (GGBFS), fly ash, etc.) are used a large amount, it might be able to reduce cement consumption and mitigate carbon emissions. In this case, however, decrease of early strength is relatively large. Therefore, there is a limitation in increase of the amount of substitute. Considering these circumstances, it would be a good solution to reduce carbon emissions in cement industry to improve the performances of mixed cement through proper alkali-activation in Portland blended cement using GGBFS or fly ash. Therefore, this study prepared concrete in ready-mixed concrete manufacturing facilities with an addition of a binder which used 2.0% modified alkali sulfate activator after mixing Portland cement, GGBFS and fly ash in the ratio of 4:4:2 and assessed its basic properties. The results found the followings: The use of modified alkali-sulfate activator slightly reduced slump and shortened setting time. As a result, bleeding capacity decreased while early strength improved. In addition, there is no big difference in carbonation resistance. It appears that there should be continued experiments and analyses on the related long-term aged specimens.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04a
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• pp.161-166
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• 1998

The main object of this study is to examine the basic properties of fresh concrete as well as hardened concrete using several types of cement such as ordinary portland cement, sulphate resisting portland cement, blast furnace slag cement, ternary blended cement. In addition, effects of each cement on the durability including drying shrinkage, freeze-thawing resistance, resistance of chloride ion penetration, carbonation of concrete were investigated. As the results of this study, it was proved that most of the properties of concrete using each cement were similar, but there were some differences in bleeding, setting time, resistance of chloride ion penetration and carbonation.

• Advances in concrete construction
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• v.3 no.1
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• pp.1-14
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• 2015

China accounts for nearly half of the global steel production. As a waste material or a by-product in the manufacture process, a large amount of blast furnace slag is generated every year. The majority of recycled blast furnace slag is used as an additive in low-grade blended cement in China (equivalent to the UK CEM II or CEM III depending on the slag content). The cost of using ground granulated blast furnace slag (GGBS) in such low-grade applications may not be entirely reimbursed based on market research. This paper reports an on-going project at Xi'an Jiaotong-Liverpool University (XJTLU) which investigates the feasibility of using GGBS in long-span concrete structures by avoiding/reducing the use of crack control reinforcement. Based on a case study investigation, with up to 50% of CEM I cement replaced with GGBS, a beneficiary effect of reduced thermal contraction is achieved in long-span concrete slabs with no significant detrimental effect on early-age strengths. It is believed that this finding may be transferable from China to other Asian countries with similar climates and economic/environmental concerns.

• Journal of the Korean Ceramic Society
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• v.34 no.10
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• pp.1027-1036
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• 1997

The reology and several physical properties of cements are studied by varying the different mineral composition and particle size distribution(PSD) of cements with closed circuit ball mill for high workability, low heat of hydration, and high strength. In this study, we found that the workability of concretes is related to the viscosity of cement, and affects to strength. Here, this workability is affected by mineral composition (C3A) and the PSD. Especially, rosin-rammer index and 44${\mu}{\textrm}{m}$ residue in the PSD of cements are affected to water demand, casting property, slump loss, strength of cements. From the above results, the conditions of cement for high workability, low heat of hydration and high strength are to use low C3A clinker, 5-10% slag addition, and to grind cement below 0.7 rosin-rammer index, above 3.5-4.5% 44 ${\mu}{\textrm}{m}$ residue, 4000$\pm$100 $\textrm{cm}^2$/g blaine. Such cements are, therefore, supurior to super low heat cement and slag-blended cement in comparing the physical properties of strength, slump, slump-flow, adiabetic temperature, etc.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.148-153
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• 1996

Concrete with ground granulated blast-furnace slag can be affected by frost attack because the reaction of hydration is slow at the early age. In this study, therefore, the freezing and thawing test has been carried out to investigate the freezing and thawing resistance on concrete with ground granulated blast-furnace slag. The freezing and thawing test has been performed on concrete a blended cement, which was substituted by ground granulated blast-furnace slag with 4 kinds of ratio (non-admixture, 20%, 40% and 60%). And also tested on concrete added the AE agents to the concrete of same mix proportion to search the improvement effects about the resistance. As a result, the freezing and thawing resistance showed a tendency of reduction in proportion to the increase of the substitution ratio. For non-AE concrete, resistances of the freezing and thawing were very poor as the durability index indicated less than 5.8%. For AE concrte, resistance of the freezing and thawing were excellent as the durability index indicated more than 80.9%.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.293-298
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• 1997

Corrosion of steel reinforcing in concrete deteriorated by freezing/thawing and carbonation was characterized. Concrete specimens were prepared using various kinds of cements such as ordinary portland cement (type I), low heat portland cement (type IV, belite rich cement), sulphate resistance portland cement (type V), blast furnace slag portland cement and ternary blended cement. Of various cements, type V and type IV with lower $C_3A$ content revealed better steel corrosion resistance after freezing/thawing and carbonation. $C_3A$ content in cement might affect freezing/thawing resistance in sea water.

• Journal of the Korea Concrete Institute
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• v.16 no.1 s.79
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• pp.1-9
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• 2004

This paper represents the permeability of chloride ions and the corrosion performance in the concrete blended with granulate blast furnace slag exposed to chloride environment. An ordinary cement (type I ) and sulfate resisting cement(type V) were used for the experiment. The two cements were combined with $0\%$, $25 \%$, $40\%$, and $55\%$ of the granulated blast furnace slag. The accelerated permeability tests of chloride ions were performed in accordance with ASTM C1202, and the accelerated corrosion tests of steel were carried out by using the method of immersion/drying cycles. After water curing 28 days, 56 days and 91 days, these tests were conducted until 30 cycles. In every cycle, test specimens were wetted in $3\%$ NaCl solution for three days and dried again in $60^{\circ}C$ air for four days. As an experimental results, the diffusion coefficient of chloride ions of the ordinary cement Concrete Combined granulated blast furnace slag was much lower than that of non granulated blast furnace slag concrete. Moreover, the diffusion coefficient of chloride ions of sulfate resisting cement concrete was higher than that of ordinary cement concrete. On the basis of the results of accelerated corrosion tests, corrosion resistance of the concrete mixed with granulated blast furnace slag shows good to corrosion resistance, however, the concrete with sulfate resisting cement shows bad to corrosion resistance.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.05a
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• pp.271-276
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• 2003

This study is about the rheological properties of cement slurry using admixtures. The variables are the type of cement(Type I, II, IV, V) and the substitution ratio of admixtures such as fly ash and slag. As a result of measuring the fluidity of various types of cement slurry at the early stage, type 2, type 4 and type 5 showed the similar property. The fluidity of type 1 and ternary blended cement was low. it is thought that it is because of the high $C_3$A content. The cement slurries containing mineral admixtures were superior in the property of fluidity retention.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.565-566
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• 2009

Supplementary cementing materials (SCM), such as silica fume, slag, and low-calcium fly ash, have been widely used as mineral admixtures in high strength and high performance concrete. Due to the chemical and physical effect of SCM on hydration, compared with Portland cement, hydration process of cement incorporating SCM is much more complex. This paper presents a numerical hydration model which is based on multi-component concept and can simulate hydration of cement incorporating SCM. The proposed model starts with mixture proportion of concrete and considers both chemical and physical effect of SCM on hydration. Using this proposed model, this paper predicts the following properties of hydrating cement-SCM blends as a function of hydration time: reaction ratio of SCM, calcium hydroxide content, heat evolution, porosity, chemically bound water and the development of the compressive strength of concrete. The prediction results agree well with experiment results.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.5
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• pp.133-142
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• 2008

This paper studies the early-aged chloride binding capacity of various blended concretes including OPC(ordinary Portland cement), PFA(pulversied fly ash), GGBFS(ground granulated blast furnace slag) and SF(silica fume) cement paste. Cement pastes with 0.4 of a free water/binder ratio were cast with chloride admixed in mixing water, which ranged from 0.1 to 3.0% by weight of cement and different replacement ratios for the PFA, GGBFS and SF were used. The content of chloride in each paste was measured using water extraction method after 7 days curing. It was found that the chloride binding capacity strongly depends on binder type, replacement ratio and total chloride content. An increase in total chloride results in a decrease in the chloride binding, because of the restriction of the binding capacity of cement matrix. For the pastes containing maximum level of PFA(30%) and GGBFS(60%) replacement in this study, the chloride binding capacity was lower than those of OPC paste, and an increase in SF resulted in decreased chloride binding, which are ascribed to a latent hydration of pozzolanic materials and a fall in the pH of the pore solution, respectively. The chloride binding capacity at 7 days shows that the order of the resistance to chloride-induced corrosion is 30%PFA > 10%SF > 60%GGBFS > OPC, when chlorides are internally intruded in concrete. In addition, it is found that the binding behaviour of all binders are well described by both the Langmuir and Freundlich isotherms.