• Title/Summary/Keyword: Size-characterization

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EFFECTS OF TRACE METALS ON PARTICULATE MATTER FORMATION IN A DIESEL ENGINE: METAL CONTENTS FROM FERROCENE AND LUBE OIL

  • Lee, D.G.;Miller, A.;Park, K.H.;Zachariah, M.R.
    • International Journal of Automotive Technology
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    • v.7 no.6
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    • pp.667-673
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    • 2006
  • Diesel particulate matter(DPM) often contains small amounts of metal as a minor component but this metal may contribute to adverse health effects. Knowledge of the mechanism for particle formation as well as the size preference of the trace metals is critical to understanding the potential for health concerns. To achieve this, the size and the composition of each particle should be optimally measured at the same time. Single particle mass spectrometer(SPMS) would be the best tool for this objective. In this paper, we therefore will introduce new findings about the mechanism and distribution of the trace metals in DPM, derived from a study where an SPMS was used to analyze freshly emitted DPM.

Approach to Characterization of a Diode Type Corona Charger for Aerosol Size Measurement

  • Intra Panich;Tippayawong Nakorn
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.5
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    • pp.196-203
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    • 2005
  • A semi-empirical method to determine the electrostatic characteristics of a diode type corona aerosol charger based on ion current measurement and electrostatic charging theory was presented. Results from mathematical model were in agreement with those from experimental investigation of the charger. Current-voltage characteristics, $N_{i}t$ product and charge distribution against aerosol size were obtained. It was shown that the space charge was significant and must be taken into account at high ion number concentration and low flow rate. Additionally, significant particle loss was evident for particles smaller than 20 nm in diameter where their electrical mobility was high. Increase in charging efficiency may be achieved by introducing surrounding sheath flow and applying AC high voltage. Overall, the approach was found to be useful in characterizing the aerosol charger.

Preparation and Characterization of CdTe Quantum Dots (CdTe 양자점 합성과 물리적 특성 분석)

  • Kim, Hyun-Suk;Song, Hyun-Woo;Cho, Kyung-Ah;Kim, Sang-Sig
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.195-197
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    • 2002
  • CdTe quantum dots(QDs) were synthesized in aqueous solution by colloidal method. Photoluminescence(PL) spectra of the synthesized CdTe QDs revealed the intensity of PL peaks was stronger as the condensation time was longer. This result was thought because annealing effect by thermal energy transferred during condensation eliminated defects which act as traps and recombination centers in CdTe particle. PL intensity has stron dependence of Te precursor concentration. It confirmed the ratio of Te ion to Cd ion added during synthesis affected the particle size and size distribution of the CdTe QDs. Finally, the synthesized CdTe QDs were identified to be cubic structured CdTe quantum dots by X-ray diffraction(XRD).

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Characterization of Mullite Whiskers Synthesized with Compostion of Al(OH)3-SiO2-AlF3 (Al(OH)3-SiO2-AlF3 조성으로 합성된 뮬라이트 휘스커의 특성평가)

  • Lee, Hong-Lim;Kang, Jong-Bong
    • Journal of the Korean Ceramic Society
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    • v.43 no.5 s.288
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    • pp.320-326
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    • 2006
  • Mullite whiskers were synthesized by a vapor-solid reaction with $Al(OH)_3-SiO_2-AlF_3$. The heat treatment temperature did not affect the shape of mullite whisker but the composition change resulted in different sizes. The first one was $30-50{\mu}m$ in size with the aspect ratio of 60 and above, and the second one was $600{\mu}m$ and below in size with the aspect ratio of 15 and below. The $Al_2O_3$ content in formed mullite whisker was 73.57-80.29 wt%, which is high $Al_2O_3$ content composition. The Young's modulus and the hardness measured by nano-indentation method were 136.7 GPa and 19.81 GPa, respectively.

유기실리카와 나노기공형성 수지의 상용성 변화에 의한 나노기공의 구조 변화

  • 차국헌;최연승;김상율;진문영
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.52-52
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    • 2002
  • Recently, nanoporous low-k materials using porogen (pore generating material) template method have gained much attraction due to the feasible advantage of dielectric constant decrease with the increase of porogen content, which is burning out and making air void by thermal curing. In nanoporous thin films, further, control of pore size and its distribution is very important to retain suitable thermal, mechanical and electrical properties. In this study, nanoporous low-k films were prepared with MTMS-BTMSE copolymer and porogen. The effect of interaction of copolymer matrix and porogen on pore size and distribution was comparatively to investigate with molecular structure and end functional group. The characterization of nanoporous thin film prepared was also performed using various techniques including NMR, GPC, Ellipsometer, FE-SEM, TGA, and FT-IR.

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Use of Ultra Fine Cement Particles as Crack Repair Materials (균열주입재로서 초미립자 시멘트의 이용)

  • 이종열;정연식;이웅종;양승규;채재홍
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1205-1210
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    • 2000
  • In this research we made the mean cement particle size 4 $\mu\textrm{m}$ which can penetrate even minor cracks based on the theory of J.K. Michel who reported particles can penetrate the crack of width up to 3 times of maximum particle size. The cement slurries were produced by adding super plasticizer. The slurries were tested with slurry characterization methods and its rheological properties were characterized. The early hydrated phenomena of ultra fine cement were observed by SEM, XRD and DSC during 24 hours. Mechanical properties of hardened slurry with JIS molds were also tested in 3, 7 and 28 days. The cracked specimens which were repaired with slurries produced various conditions were tested after 3, 7 and 28 days curing in the air and adhesion properties were characterized.

Characterization of Emulsion Properties for Modified Amino Polysiloxanes (아미노 변성 폴리실록산의 유화 특성)

  • 하윤식;서무룡;이정경;박경일;장윤호
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.61-67
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    • 1999
  • Silicone oil has organic and inorganic properties, and its skeleton is polysiloxane bonding that silicon is bonded hydrogen or organic group. Silicone compounds are very smooth and lubricant properties by low surface tension, low temperature dependence, and nonadhesive properties. Because of these properties, silicone compounds are used as many parts of chemicals, softener, smooth and libricant agents, water-repellent agent, and defoaming agent, etc. Emulsion was prepared with the inversion emulsification method which adopted the agent-in-oil method dissolving the polyoxyethylene(7) tridecyl ether(HLB 12.2) into methoxy terminated poly(dimethyl-co-methyl amino) siloxane and hydroxy terminated poly(dimethyl-co-methyl amino) siloxane in water. At this time, processed emulsion was almost microemulsion. When ratio of emulsifier increases, emulsion is stable bacuause microemulsion is solubilized by emulsion drop size and zeta-potential are decreased. But, when amount of electrolyte is increase, emulsion became unstable because emulsion drop size is increased.

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Preparation of Monodispersed, Sheperical Al2O3 and Mg-doped Al2O3 Powder and Sintering Characterization of These Powders (구형의 단분산 Alumina 및 Mg-doped Alumina의 합성과 소결에 관한 연구)

  • 이중윤;부재필;최상흘
    • Journal of the Korean Ceramic Society
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    • v.31 no.1
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    • pp.1-10
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    • 1994
  • Monodispersed alumina and Mg-doped alumina fine particles were prepared by controlled hydrolysis of alkoxides. Aluminium alkoxide and magnesium alkoxide were dissolved into complex solvent which was composed of hydrophobic n-octanol and hydrophilic acetonitrile. Hydroxypropyl cellulose(HPC) was used as a dispersant for the alumina particles. The size of these prepared powders was approximately 0.3 ${\mu}{\textrm}{m}$. In the case of sintering above 100$0^{\circ}C$, most of these prepared powders were transformed to $\alpha$-alumina. The relative density of the sintered body of these prepared powders at 1$600^{\circ}C$ was 98%. The sintered body of the Mg-doped alumina powder had more uniform grain size than that of the undoped alumina podwer.

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Characterization of Alumina Gel Prepared by Hydrolysis of Al(OC3H7i)3 (Al(OC3H7i)3의 가수분해로부터 얻어진 Al2O3 겔의 특성에 관한 연구)

  • 이서우;문종수;조성백
    • Journal of the Korean Ceramic Society
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    • v.25 no.2
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    • pp.89-94
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    • 1988
  • Alumina gel was prepared by the hydrolysis of aluminum isopropoxide Al(OC3H7i)3 at low temperature. Sample were calcined at the various temperatures for 10 houres in the electric furnace, respectively. In order to investigate the various propertis-thermal properties, pore size and distribution, and the transition of crystals, infrared spectroscopy, thermal analysis, particle size analysis, scanning electron microscopy, and porosimetry were employed. Transparent alumina gel was opalized at 1200$^{\circ}C$. Porosity was about 87% with pores below 0.7$\mu\textrm{m}$ and 55% at 1200$^{\circ}C$. The gel was transformed along the rising of temperature as follows; Boehmite\longrightarrow$\delta$-Al2O3\longrightarrow$\theta$\longrightarrowAl2O3\longrightarrow${\alpha}$-Al2O3.

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Image and Display Quality Evaluation

  • Ha, Yeong-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1224-1227
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    • 2009
  • When evaluating the quality of images and displays, it is important to combine the characteristics as perceived by the human visual system and measured by equipment using subjective and objective methods, respectively. In the case of objective methods, the quality of a display is measured using colorimetric or radiometric devices according to existing standards covering the color temperature, gamut size, gamma characteristic, and device characterization. Meanwhile, subjective methods assess the quality of an image using the human visual system based on a comparison with a reference or counterpart using such metrics as the sharpness, noise, contrast, saturation, and color accuracy. Objective and subjective methods are usually used together in comparison, as ultimately it is observers watching images on a display. In addition to existing objective methods, a new image quality metric is also introduced as regards the JPEG compression ratio that is reflected in the relationship between the gamut size and the color fidelity in CIELAB color space.

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