• Title/Summary/Keyword: Size stability

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Hydrolytic Stability of Cured Urea-Melamine-Formaldehyde Resins Depending on Hydrolysis Conditions and Hardener Types

  • Park, Byung-Dae;Lee, Sang-Min
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.672-681
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    • 2015
  • As a part of abating the formaldehyde emission of amino resin-bonded wood-based composite panels, this study was conducted to investigate hydrolytic stability of urea-melamine-formaldehyde (UMF) resin depending on various hydrolysis conditions and hardener types. Commercial UMF resin was cured and ground into a powdered form, and then hydrolyzed with hydrochloric acid. After the acid hydrolysis, the concentration of liberated formaldehyde in the hydrolyzed solution and mass loss of the cured UMF resins were determined to compare their hydrolytic stability. The hydrolysis of cured UMF resin increased with an increase in the acid concentration, time, and temperature and with a decrease in the smaller particle size. An optimum hydrolysis condition for the cured UMF resins was determined as $50^{\circ}C$, 90 minutes, 1.0 M hydrochloric acid and $250{\mu}m$ particle size. Hydrolysis of the UMF resin cured with different hardener types showed different degrees of the hydrolytic stability of cured UMF resins with a descending order of aluminum sulfate, ammonium chloride, and ammonium sulfate. The hydrolytic stability also decreased as the addition level of ammonium chloride increased. These results indicated that hardener types and level also had an impact on the hydrolytic stability of cured UMF resins.

Evaluation of thermal stability of quasi-isotropic composite/polymeric cylindrical structures under extreme climatic conditions

  • Gadalla, Mohamed;El Kadi, Hany
    • Structural Engineering and Mechanics
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    • v.32 no.3
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    • pp.429-445
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    • 2009
  • Thermal stability of quasi-isotropic composite and polymeric structures is considered one of the most important criteria in predicting life span of building structures. The outdoor applications of these structures have raised some legitimate concerns about their durability including moisture resistance and thermal stability. Exposure of such quasi-isotropic composite/polymeric structures to various and severe climatic conditions such as heat flux and frigid climate would change the material behavior and thermal viability and may lead to the degradation of material properties and building durability. This paper presents an analytical model for the generalized problem. This model accommodates the non-linearity and the non-homogeneity of the internal heat generated within the structure and the changes, modification to the material constants, and the structural size. The paper also investigates the effect of the incorporation of the temperature and/or material constant sensitive internal heat generation with four encountered climatic conditions on thermal stability of infinite cylindrical quasi-isotropic composite/polymeric structures. This can eventually result in the failure of such structures. Detailed critical analyses for four case studies which consider the population of the internal heat generation, cylindrical size, material constants, and four different climatic conditions are carried out. For each case of the proposed boundary conditions, the critical thermal stability parameter is determined. The results of this paper indicate that the thermal stability parameter is critically dependent on the cylinder size, material constants/selection, the convective heat transfer coefficient, subjected heat flux and other constants accrued from the structure environment.

Preparation and Evaluation of Mutivitamin Emulsion (복합비타민 유제의 제조와 평가)

  • Lee, Moon-Seok;Cho, Hea-Young;Lee, Yong-Bok
    • Journal of Pharmaceutical Investigation
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    • v.32 no.1
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    • pp.13-19
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    • 2002
  • Water-lipid soluble multivitamin formulations were widely used to reduce the disease and stress of animals as husbandry has made a remarkable progress in recent. But the efficiency of these formulations is far from satisfactory. So, this study was attempted to develop the physically and chemically stable and useful multivitamin o/w emulsion. Multivitamin o/w emulsion composed of water, soybean oil (10%, v/v), vitamin A, D, E, K, $B_2,\;B_6,\;B_{12}$ and panthenol. To make a stable o/w emulsion, the egg lecithin (2%, w/v) and glycerin (2.5%, w/v) were used for emulsifier and thickening agent, respectively. The oil in water emulsion system was manufactured by microfluidizer and the physicochemical stability of this emulsion was evaluated. The average particle size and interfacial tension were measured. From the result of interfacial tension tested, critical micelle concentration of the egg lecithin was 0.5% (w/v) and optimal concentration for the preparation of emulsion was 2% (w/v). The mean particle size was about $0.6\;{\mu}m$ which was suitable for injections. Short-term accelerated stability as physical stability study was tested by centrifuging and freeze-thawing the emulsion samples. The additions of vitamins resulted in the increment of particle size and reduction of physical stability of emulsion. But it is not an enormous problem for the stability of emulsion. Also, we have performed the long-period preservation stability test for the vitamins. All vitamins were analysed by HPLC. The result of storage under $4^{\circ}C$ and dark conditions demonstrated that all vitamins were maintained stable at least 16 weeks, except for vitamin $B_{12}$.

The Numerical Analysis of Pillar Stability with Multiple, Irregular Openings (다수의 불규칙 공동을 갖는 광주의 안정성에 관한 수치해석)

  • Min, Hyung-Ki;Lim, Han-Uk
    • Journal of Industrial Technology
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    • v.24 no.A
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    • pp.139-155
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    • 2004
  • A room and pillar mining method has been adopting at the Jeungsun limestone mine. To check stability of pillar with multiple and irregular openings, the size, shape and spacing of rib pillar were first designed using some empirical suggestions. The Finite Difference Method(FDM)was used to analyze the pillar stability. Twelve different cases with the variation of K(horizontal/vertical stress)values, different height and different spacing of pillar were used in this study. Finally Mohr-Coulomb criterion was adopted to calculate the safety factors. Horizontal and vertical displacement, maximum and minimum principal stresses, range of plastic zone and safety factors were calculated at each case. As a result of analysis, the size of one block is 160m long, 70m wide, 40m high with 20m wide rib pillar and 20m square column pillar. The overall recovery at this case can be estimated about 40%.

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An Experimental Study on Optimal Size of Core Material in Rubble Mould Breakwater (사석 방파제에서 내부사석의 적정규격에 관한 실험적 연구)

  • 민석진;배종철;김성득
    • Journal of Ocean Engineering and Technology
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    • v.18 no.1
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    • pp.16-21
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    • 2004
  • In general, core materials of rubble mound breakwater are used at a restricted range of 0.015㎥~0.03㎥. However, it is not satisfied with the standard design in over fifty percent of the cases. In this study, model tests and numerical analysis are employed to examine the range of core material that has no problem with capacity maintenance and stability of rubble mound breakwater. Model tests measure the porosities that are mixed in various ratios, to classify core materials by three parameters. The slope stability of rubble mound breakwater is investigated, using numerical analysis, with a friction angle and a unit weight. The change of unit weight, which is followed by the mixed rate of size core material, has no large affect on slope stability, and there is no problem with ensuring slope stability of the rubble mound breakwater.

A numerical and computer simulation for dynamic stability analysis of 3-unknown graded porous nanoplates using a Chebyshev-Ritz-Bolotin method

  • Wei, Dong
    • Structural Engineering and Mechanics
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    • v.78 no.4
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    • pp.379-386
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    • 2021
  • A numerical and computer simulation for dynamic stability analysis of graded porous nanoplates has been provided using a Chebyshev-Ritz-Bolotin approach. The nanoplate has been formulated according to the nonlocal elasticity and a 3-unkown plate model capturing neutral surface location. All of material properties are assumed to be dependent of porosity factor which determines the amount or volume of pores. The nano-size plate has also been assumed to be under temperature and moisture variation. It will be shown that stability boundaries of the nanoplate are dependent on static and dynamical load factors, porosity factor, temperature variation and nonlocal parameter.

A Study on the Elementary School Teachers' Perceptions of Classroom Environments (초등학교 교사의 교실환경 인식에 관한 연구)

  • Suk, Min-Chul;Shin, Na-Min;Rieu, Ho-Seoup
    • Journal of the Korean Institute of Educational Facilities
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    • v.20 no.6
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    • pp.21-30
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    • 2013
  • This study aimed to identify elementary school teachers' perceptions of various aspects of physical environments of a classroom. For the purpose, a survey questionnaire was administered to 982 classroom teachers(female 82.2%) working at 67 elementary schools(Seoul 55%) located in Seoul and Busan. According to the analyses of the survey data, 50.8% of the respondent teachers suggested 20-25 as an optimum class size. Also, 57% of the teachers were positive about the current size of a classroom($67.5m^2$), but evaluations of a classroom size were divided between the teachers who had more and less than 30 students in class. Furthermore, three factors, labelled as 'uniqueness', 'residential stability' and 'visually pleasing', were extracted from a factor analysis of the Semantic Differential Scale consisting of 24 adjectives evaluating a classroom environment. Teachers from Busan tended to rate higher in the uniqueness domain while female teachers scored higher in the domain of residential stability, respectively, compared to their counterparts. Overall, the teachers perceived their classrooms having no particular characteristics, but rated highly in terms of stability. In addition, it was found out that the teachers' requests for the improvement of a classroom environment were not so much as the increased size of a classroom as a reduced class size as well as educational facilities that are corresponding to a variety of instructional methods. In summary, this study confirmed that elementary school teachers' perceptions of a classroom environment varied according to such factors as sex, teaching career, grade of their concerned class, and class size.

THE STRONG STABILITY OF ALGORITHMS FOR SOLVING THE SYMMETRIC EIGENPROBLEM

  • Smoktunowicz, Alicja
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.7 no.1
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    • pp.25-31
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    • 2003
  • The concepts of stability of algorithms for solving the symmetric and generalized symmetric-definite eigenproblems are discussed. An algorithm for solving the symmetric eigenproblem $Ax={\lambda}x$ is stable if the computed solution z is the exact solution of some slightly perturbed system $(A+E)z={\lambda}z$. We use both normwise approach and componentwise way of measuring the size of the perturbations in data. If E preserves symmetry we say that an algorithm is strongly stable (in a normwise or componentwise sense, respectively). The relations between the stability and strong stability are investigated for some classes of matrices.

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Ostwald Ripening Stability of Curcumin-Loaded MCT Nanoemulsion: Influence of Various Emulsifiers

  • Kim, Sun-Hyung;Ji, Yeun-Sun;Lee, Eui-Seok;Hong, Soon-Taek
    • Preventive Nutrition and Food Science
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    • v.21 no.3
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    • pp.289-295
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    • 2016
  • Curcumin is a flavonoid found in the rhizome of the turmeric plant (Curcuma longa L.) and has recently attracted interest because it has numerous biological functions and therapeutic properties. In the present study, we attempted to incorporate curcumin into medium-chain triglyceride (MCT) nanoemulsions (0.15 wt% curcumin, 10 wt% MCT oil, and 10 wt% emulsifiers) with various emulsifiers [polyoxyethylene (20) sorbitan monolaurate (Tween-20), sorbitan monooleate (SM), and soy lecithin (SL)]. The physicochemical properties of the nanoemulsions including the Ostwald ripening stability were investigated. The initial droplet size was found to be 89.08 nm for the nanoemulsion with 10 wt% Tween-20 (control), and when Tween-20 was partially replaced with SM and SL, the size decreased: 73.43 nm with 4 wt% SM+6 wt% Tween-20 and 67.68 nm with 4 wt% SL+6 wt% Tween-20 (prepared at 15,000 psi). When the nanoemulsions were stored for 28 days at room temperature, the droplet size increased as the storage time increased. The largest increase was observed for the control nanoemulsion, followed by the 4 wt% SL+6 wt% Tween-20 and 4 wt% SM+6 wt% Tween-20 systems. The Turbiscan dispersion stability results strongly supported the relationship between droplet size and storage time. The time-dependent increase in droplet size was attributed to the Ostwald ripening phenomenon. Thus, the Ostwald ripening stability of curcumin-loaded MCT nanoemulsions with Tween-20 was considerably improved by partially replacing the Tween-20 with SM or SL. In addition, curcumin may have acted as an Ostwald ripening inhibitor.

Effect of Pt Particle Size on the Durability of PEMFC (연료전지 촉매의 입자크기가 내구성에 미치는 영향)

  • Min, Kyoung-Won;Kim, Hyun-Jong;Han, M.K.;U, Yu-Tae;Kim, Mok-Soon;Chu, Young-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.313-318
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    • 2008
  • The influence of the particle size of platinum(Pt) on the stability and activity was studied. The particle size of platinum was controlled in the range of $3.5{\sim}9\;nm$ by heat treatment of commercial Pt/C and confirmed by XRD and TEM. An accelerated degradation test was performed to evaluate the stability of platinum catalysts. Oxygen reduction reaction was monitored for the measurement of activity. As increasing the Pt particle size, the stability of Pt/C electrode was enhanced and the activity was reduced. It was confirmed that the stability of Pt/C electrode was in inverse proportion to the activity. PtCo/C alloy catalyst was used to improve the activity and stability of large-sized platinum particle. The maximum power density of commercial Pt/C was $507.6\;mV/cm^2$ and PtCo/C alloy catalyst was $585.8\;mV/cm^2$. The decrement of electrochemical surface area showed Pt/C(60%) and PtCo/C alloy catalyst(24%). It was possible to enhance both of stability and activity of catalyst by the combination of particle size control and alloying.