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A Study on Photocatalytic Decomposition of Methylene Blue by Crystal Structures of Anatase/Rutile $TiO_2$ (아나타제/루틸 $TiO_2$ 결정 구조에 의한 메틸렌 블루 광분해 특성 연구)

  • Hwang, Moon-Jin;Nguyen, Thanh Binh;Ryu, Kwang-Sun
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.148-152
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    • 2012
  • Anatase and anatase/rutile $TiO_2$ samples were prepared at $HNO_3$/TTIP molar ratio of 0.1, 0.5, 1.0, and 1.5 to study the effects of the physical properties of $TiO_2$ on photocatalytic decomposition of methylene blue. The physical properties of the samples were measured with XRD, SEM, TEM, BET, FT-IR, and UV-vis spectroscopy. Anatase phase was observed at $HNO_3$/TTIP of 0.1 and anatase/rutile phases were observed at $HNO_3$/TTIP of 0.5~1.5. Rutile crystal phase, mesopore size between $TiO_2$ nanoparticles, and surface OH group on $TiO_2$ sample were gradually increased with increasing the molar ratio of $HNO_3$/TTIP and the residual methylene blue concentration before UV irradiation decreased from 78.0 to 53.3%. After UV irradiation, the residual methylene blue concentrations of the samples prepared at $HNO_3$/TTIP of 0.1, 0.5, 1.0, and 1.5 were 20, 14, 11, and 23%, respectively, and the sample prepared at $HNO_3$/TTIP of 1.0 showed the best photocatalytic ability.

Occurrence of Gray Mold on Yacon Caused by Botrytis cinerea (Botrytis cinerea에 의한 야콘 잿빛곰팡이병의 발생)

  • Kim, Jeom-Soon;Lee, Young-Gyu;Kim, Su-Jeong;Hong, Sung-Kee;Choi, Hyo-Won
    • Research in Plant Disease
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    • v.16 no.3
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    • pp.316-319
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    • 2010
  • The gray mold disease occurred on tuberous roots of yacon in storage facilities in Gangneung, Korea, in March 2010. Symptoms typically appeared as in the form of dark brown discoloration on the surface of tuberous roots and water-soaked brown lesions in cross sections of the affected portions. A total of five isolates of Botrytis sp. were obtained from the symptomatic portions. All isolates on potato-dextrose agar (PDA) produced abundant conidia which were pale brown, one-celled, mostly ellipsoid or ovoid in shape and $8.2{\sim}14.8{\times}6.5{\sim}9.9\;{\mu}m$ in size. Large numbers of round to irregular, smooth, black, hard sclerotia were produced on PDA over time. The optimal temperature for mycelial growth and sclerotia formation of the fungal isolates was $20^{\circ}C$. On the basis of morphological and cultural characteristics, all the fungal isolates were identified as Botrytis cinerea. Pathogenicity test on host plants showed that the fungus could infect not only tuberous roots but also leaves and petioles of yacon. This is the first report on gray mold of yacon (Smallanthus sonchifolius) caused by Botrytis cinerea in Korea.

Structural analysis of expressed sequence tags inimmature seed of Oryza sativa L. (벼 미숙종자의 발현유전자 구조특성분석)

  • Yoon, Ung-Han;Lee, Gang-Seob;Lee, Jung-Sook;Hahn, Jang-Ho;Kim, Chang-Kug;Kikuch, Shoshi;Satoh, Kouji;Kim, Jin-A;Lee, Jeong-Hwa;Lee, Tae-Ho;Kim, Yong-Hwan
    • Journal of Plant Biotechnology
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    • v.36 no.2
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    • pp.130-136
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    • 2009
  • Rice (Oryza sativa) is the most important staple crop in Korea. With its small genome size of 389Mb, rice is a model plant for genome research. We analyzed expressed sequence tag (EST) clones from immature seeds of rice (cv. Ilpum) at 20 days after heading. The 25,668 EST clones were clustered by using SeqMan program and 7,509 clones were selected as unique clones. We compared the 7,509 unique genes with KOME database including the 32,127 FL-cDNA in rice. Finally, 4,990 clones were homologous and 2,519 clones non-homologous to FL-cDNA clones. In addition, we mapped the 7,509 cDNA clones by using TIGR rice pseudomolecule version 5. Ultimately, 7,347 clones were matched to be significant clones related to the TIGR rice pseudomolecules, but 162 clones were unmapped. For the clustering of orthologous group genes, we further analyzed the 7,509 EST clones from immature seeds using NCBI clusters of orthologous groups database. Among the clones, 4,968 clones were categorized into information storage and processing, cellular processes and signaling, metabolism and poorly characterized genes, proportioning 799 (14.89%), 1,536 (28.3%), 1,148 (21.2%) and 1,936 (35.7%) clones to the previous four categories, respectively.

Fabrication and Catalysis of $SiO_2$-Coated Ag@Au Nanoboxes

  • Lee, Jae-Won;Jang, Du-Jeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.588-588
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    • 2013
  • Nanoscale noble-metals have attracted enormous attention from researchers in various fields of study because of their unusual optical properties as well as novel chemical properties. They have possible uses in diverse applications such as devices, transistors, optoelectronics, information storages, and energy converters. It is well-known that nanoparticles of noble-metals such as silver and gold show strong absorption bands in the visible region due to their surface-plasmon oscillation modes of conductive electrons. Silver nanocubes stand out from various types of Silver nanostructures (e.g., spheres, rods, bars, belts, and wires) due to their superior performance in a range of applications involvinglocalized surface plasmon resonance, surface-enhanced Raman scattering, and biosensing. In addition, extensive efforts have been devoted to the investigation of Gold-based nanocomposites to achieve high catalytic performances and utilization efficiencies. Furthermore, as the catalytic reactivity of Silver nanostructures depends highly on their morphology, hollow Gold nanoparticles having void interiors may offer additional catalytic advantages due to their increased surface areas. Especially, hollow nanospheres possess structurally tunable features such as shell thickness, interior cavity size, and chemical composition, leading to relatively high surface areas, low densities, and reduced costs compared with their solid counterparts. Thus, hollow-structured noblemetal nanoparticles can be applied to nanometer-sized chemical reactors, efficient catalysts, energy-storage media, and small containers to encapsulate multi-functional active materials. Silver nanocubes dispersed in water have been transformed into Ag@Au nanoboxes, which show highly enhanced catalytic properties, by adding $HAuCl_4$. By using this concept, $SiO_2$-coated Ag@Au nanoboxes have been synthesized via galvanic replacement of $SiO_2$-coated Ag nanocubes. They have lower catalytic ability but more stability than Ag@Au nanoboxes do. Thus, they could be recycled. $SiO_2$-coated Ag@Au nanoboxes have been found to catalyze the degradation of 4-nitrophenol efficiently in the presence of $NaBH_4$. By changing the amount of the added noble metal salt to control the molar ratio Au to Ag, we could tune the catalytic properties of the nanostructures in the reduction of the dyes. The catalytic ability of $SiO_2$-coated Ag@Au nanoboxes has been found to be much more efficient than $SiO_2$-coated Ag nanocubes. Catalytic performances were affected noteworthily by the metals, sizes, and shapes of noble-metal nanostructures.

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Manufacture of Processed Foods and its Quality Characteristics from Kumquats, a Citrus Variety Produced in Cheju (금감 가공식품(加工食品)의 제조(製造)와 품질특성(品質特性))

  • Koh, Jeong-San;Kim, Chan-Shick;Ko, Myung-Soo;Yang, Young-Tack
    • Korean Journal of Food Science and Technology
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    • v.25 no.1
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    • pp.33-38
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    • 1993
  • In order to utilize Kumquats as a processed products, a Citrus varieties produced in Cheju island, physicochemical properties of Kumquats, sensory evaluation of frozen Kumquats, sensory evaluation and texture parameter of Kumquats processed foods were investigated. Fruit size, weight, peel ratio, peel thickness, and Brix/acid ratio of Youngpa Kumquats cultivated in green house were 29.5 mm, 16.10g, 4.63 mm and 20.0 respectively, and it was suitable for as raw-eating and processing materials. Kumquats juice consisted of 58.27% citric acid, 32.49% malic acid, 9.14% tartaric acid and 0.08% maleic acid of total organic acids. Organic acid contents of Kumquats juice was very different from Citrus unshiu juice in malic acid content. Sensory evaluation on frozen Kumquats stored at $-18^{\circ}C$ for 6 month was good for appearance, taste and texture as summer commodity. Vitamin C content of frozen Kumquats was 74.94 mg/100g, and its content was decreased slightly during fronzen storage. Hardness on Kumquats jam was lowered from 1,294 to 355 g-force as the ratio of Kumquats juice content was increased, but the changes of other texture parameter were not so large. Kumquats jam contained $40{\sim}60%$ orange juice was evaluated as superior to orange jam for panelists.

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Physicochemical Characterization and Changes in Nutritional Composition of Onions Depending on Type of Freezing Process (냉동 조건에 따른 양파의 이화학적 특성 및 영양성분 변화)

  • Jang, Min-Young;Jo, Yeon-Ji;Hwang, In-Guk;Yoo, Seon-Mi;Choi, Mi-Jung;Min, Sang-Gi
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.7
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    • pp.1055-1061
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    • 2014
  • Innovative freezing technology is currently applied to preserve foodstuffs for long-term storage. Generally, the quality of frozen food is closely related to the types of freezing and thawing processes. In this study, we characterized the physicochemical properties of onions depending on freezing rate. When onions were frozen at $-40^{\circ}C$, freezing rates were 0.1, 0.5, and $0.7^{\circ}C/min$ depending on air-blast quick freezer mode. Onions were thawed by microwave irradiation at 400 W. Hardness of onion dramatically decreased after freezing and thawing compared with blanched onion. However, the fastest freezing rate did not affect hardness. Thawing loss of onion decreased with a faster freezing rate. For morphological observation, onion frozen at a faster rate showed a smaller ice-crystal size. Vitamin C content decreased upon blanching or freezing, but there was no significant difference according to freezing rate. Although free sugar content also decreased upon blanching and freezing, its highest content was at $0.7^{\circ}C/min$ freezing. Among organic acids, malic acid content was highest at $0.7^{\circ}C/min$ freezing. Based on this study, it could be suggested that a faster freezing rate is effective to improve frozen food quality in accordance with preventing tissue damage or minimizing destruction of nutrients.

Comparative Evaluation on Collision and Particle Separation Efficiency between CO2 Bubbles and Air Bubbles Using Contact Zone Model of Flotation Process (부상분리 공정의 접촉영역 모델을 이용한 이산화탄소와 공기 기포의 충돌 및 입자 분리효율 비교 평가)

  • Yang, Jong-Won;Choi, Yong-Ho;Chae, In-Seok;Kim, Mi-Sug;Jeong, Yong-Hoon;Kim, Tae-Geum;Kwak, Dong-Heui
    • Journal of Korean Society on Water Environment
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    • v.35 no.1
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    • pp.64-71
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    • 2019
  • In recent years, carbon dioxide ($CO_2$) bubbles emerged as the most widely applied material with the recycling of sequestrated storage to decrease global warming. Flotation using $CO_2$ as an alternative to air could be effective in overcoming the high power consumption in the dissolved air flotation (DAF) process. The comparison of DAF and DCF system indicated that, the carbon dioxide flotation (DCF) system with pressurized $CO_2$ only requires 1.5 ~ 2.0 atm, while the DAF system requires 3.0 ~ 6.0 atm. In a bid to understand the characteristics of particle separation, the single collector collision (SCC) model was used and a series of simulations were conducted to compare the differences of collision and flotation between $CO_2$ bubbles and air bubbles. In addition, laboratory experiments were sequentially done to verify the simulation results of the SCC model. Based on the simulation results, surfactant injection, which is known to decrease bubble size, cloud improved the collision efficiency of $CO_2$ bubbles similar to that of air bubbles. Furthermore, the results of the flotation experiments showed similar results with the simulation of the SCC model under anionic surfactant injection. The findings led us to conclude that $CO_2$ bubbles can be an alternative to air bubbles and a promising material as a collector to separate particles in the water and wastewater.

Efficient Management of Moving Object Trajectories in the Stream Environment (스트림 환경에서 이동객체 궤적의 효율적 관리)

  • Lee, Won-Cheol;Moon, Yang-Sae;Rhee, Sang-Min
    • Journal of KIISE:Databases
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    • v.34 no.4
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    • pp.343-356
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    • 2007
  • Due to advances in position monitoring technologies such as global positioning systems and sensor networks, recent position information of moving objects has the form of streaming data which are updated continuously and rapidly. In this paper we propose an efficient trajectory maintenance method that stores the streaming position data of moving objects in the limited size of storage space and estimates past positions based on the stored data. For this, we first propose a new concept of incremental extraction of position information. The incremental extraction means that, whenever a new position is added into the system, we incrementally re-compute the new version of past position data maintained in the system using the current version of past position data and the newly added position. Next, based on the incremental extraction, we present an overall framework that stores position information and estimates past positions in the stream environment. We then propose two polynomial-based methods, line-based and curve-based methods, as the method of estimating the past positions on the framework. We also propose three incremental extraction methods: equi-width, slope-based, and recent-emphasis extraction methods. Experimental results show that the proposed incremental extraction provides the relatively high accuracy (error rate is less than 3%) even though we maintain only a little portion (only 0.1%) of past position information. In particular, the curve-based incremental extraction provides very low error rate of 1.5% even storing 0.1% of total position data. These results indicate that our incremental extraction methods provide an efficient framework for storing the position information of moving objects and estimating the past positions in the stream environment.

Sterilization of Yakju(Rice Wine) Using a Batch-type High Voltage Pulsed Electric Field System (고전장펄스를 이용한 약주의 회분식 살균)

  • Kim, Su-Yeon;Park, Young-Seo;Mok, Chul-Kyoon
    • Korean Journal of Food Science and Technology
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    • v.31 no.5
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    • pp.1247-1253
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    • 1999
  • Yakju(rice wine) was sterilized with high-voltage pulses of short time on a batch pulsed electric field(PEF) system. The initial microbial counts of Yakju were 7.52 X $10^4\;CFU/mL$ for total aerobes, 2.20 X $10^4\;CFU/mL$ for lactic acid bacteria and 7.08 X $10^4\;CFU/mL$ for yeasts. The pH, acidity and electric conductivity of Yakju were 3.36, 0.462% and 1.24 mS/cm, respectively. Yakju was treated with 2-250 of pulses exponential-wave formed electric pulses under the field strength of 12.5-25 kV/cm. The critical strengths of the electrical field for the sterilization of Yakju were 7.5 kV/cm for total aerobes, 8.5 kV/cm for lactic acid bacteria and 6.5 kV/cm for yeasts. Logarithmic survival rates decreased linearly at low pulse number, but curvilinearly at high pulse number. The PEF sterilization kinetics of Yakju could be analysed by In s = In A-k In (n) and the sterilization rate constant increased with electric field strength and the size of target microorganisms. No changed in pH, acidity, and the growth of microorganisms were found in the PEF treated Yakju during the storage for 6 weeks at both $4^{\circ}C$ And $30^{\circ}C$.

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On-line Handwriting Chinese Character Recognition for PDA Using a Unit Reconstruction Method (유닛 재구성 방법을 이용한 PDA용 온라인 필기체 한자 인식)

  • Chin, Won;Kim, Ki-Doo
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.39 no.1
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    • pp.97-107
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    • 2002
  • In this paper, we propose the realization of on-line handwritten Chinese character recognition for mobile personal digital assistants (PDA). We focus on the development of an algorithm having a high recognition performance under the restriction that PDA requires small memory storage and less computational complexity in comparison with PC. Therefore, we use index matching method having computational advantage for fast recognition and we suggest a unit reconstruction method to minimize the memory size to store the character models and to accomodate the various changes in stroke order and stroke number of each person in handwriting Chinese characters. We set up standard model consisting of 1800 characters using a set of pre-defined units. Input data are measured by similarity among candidate characters selected on the basis of stroke numbers and region features after preprocessing and feature extracting. We consider 1800 Chinese characters adopted in the middle and high school in Korea. We take character sets of five person, written in printed style, irrespective of stroke ordering and stroke numbers. As experimental results, we obtained an average recognition time of 0.16 second per character and the successful recognition rate of 94.3% with MIPS R4000 CPU in PDA.