• Title/Summary/Keyword: Size and shape effect

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Effect of the Ni Catalyst Size and Shape on the Variation of the Geometries for the As-grown Carbon Coils

  • Jang, Chang-Young;Kim, Sung-Hoon
    • Journal of the Korean institute of surface engineering
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    • v.46 no.4
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    • pp.175-180
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    • 2013
  • Carbon nanofilaments (CNFs) could be synthesized using $C_2H_2/H_2$ as source gases and $SF_6$ as an incorporated additive gas under thermal chemical vapor deposition system. Ni powders were used as the catalyst for the formation of the CNFs. During the initial deposition stage, the initiation of the CNFs on the Ni catalyst was investigated. The geometries of the as-grown CNFs on Ni catalyst were strongly dependent on the size and/or the shape of Ni catalyst. Small size catalyst (<150 nm in diameter) gives rise to the unidirectional growth of the CNFs. On the other hand, large size catalyst (150~500 nm), the bidirectional growth of the CNFs could be observed. Particularly, the well faceted parallelogram-shaped Ni catalyst could give rise to the bidirectional growth of the CNFs having the symmetrically opposite direction. Eventually, these bidirectional growths of CNFs were understood to form the well-developed carbon microcoils (CMCs). Based on these results, the optimal shape and the size of the Ni catalyst to form the CMCs were discussed.

Morphological Effect of Dispersed Phase on Gas Separation Properties through Heterophase Polymer Membrane: Theoretical and Experimental Approaches.

  • Park, Cheolmin;Jo, Won-Ho;Kang, Yong-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.04a
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    • pp.55-56
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    • 1996
  • Heterophase polymer system has been attractive for a potential applicability to gas separation membrane material. It has been known that there is a trade-off between gas permeability and its selectivity in common polymers. Therefore, the heterophase polymer can be an alternative for a gas separation membrane material because its transport properties can be readily controlled by blending of two different polymers. The transport properties of immiscible polymer blends strongly depend upon the intrinsic transport properties of corresponding polymers. Another important factor to determine the transport properties is their morphology: volume fraction, size and shape of dispersed phase. Although the effect of the volume fraction of the dispersed phase on the transport properties has been widely investigated, the size and shape effects have been paid attention very much. In an immiscible polymer blend of two polymers, its morphology is primarily controlled by its volume fraction of dispersed phase. Therefore, the effect of the size of the dispersed phase can be hardly seen. Therefore, a block copolymer has been commonly employed to control their morphology when each block is miscible with one or the other phase. In this work, gas transport properties will be measured by varying the morphology of the heterophase polymer membrane. The transport properties will be interpreted in terms of their morphology. The effect of the volume fraction of the PI phase and, in particular, its size effect will be investigated experimentally and theoretically.

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Cutout shape and size effects on response of quasi-isotropic composite laminate under uni-axial compression

  • Singh, S.B.;Kumar, Dinesh
    • Structural Engineering and Mechanics
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    • v.35 no.3
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    • pp.335-348
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    • 2010
  • Cutouts are often provided in structural and aircraft components for ventilation, for access, inspection, electric lines and fuel lines or sometimes to lighten the structure. This paper addresses the effects of cutout shape (i.e., circular, square, diamond, elliptical-vertical and elliptical-horizontal) and size on buckling and postbuckling response of quasi-isotropic (i.e., $(+45/-45/0/90)_{2s}$) composite laminate under uni-axial compression. The finite element method is used to carry out the investigation. The formulation is based on first order shear deformation theory and von Karman's assumptions are used to incorporate geometric nonlinearity. The 3-D Tsai-Hill criterion is used to predict the failure of a lamina while the onset of delamination is predicted by the interlaminar failure criterion. It is observed that for the smaller size cutout area there is no significant effect of cutout shape on load-deflection response of the laminate. It is also concluded that the cutout size has substantial influence on the buckling and postbuckling response of the laminate with elliptical-horizontal cutout, while this effect is observed to be the least in case of laminate with elliptical-vertical cutout.

Effect of Heat Treatment Temperature on Amount of Stress-Induced ${\varepsilon}$ Martensite in an Fe-Mn Baesd Alloy (Fe-Mn계 합금에서 응력유기 ${\varepsilon}$ 마르텐사이트의 양에 미치는 열처리 온도의 영향)

  • Jee, K.K.;Han, J.H.;Jang, W.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.17 no.6
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    • pp.342-345
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    • 2004
  • In this work, a new method of measuring volume fraction of deformation-induced ${\varepsilon}$ martensite is proposed using endothermic heat on reverse transformation. As grain size increases, the amount of ${\varepsilon}$ martensite forming on cooling increases. However, with a decrease in grain size, more ${\varepsilon}$ is induced by deformation, improving shape memory effect.

Effect of the Shape of Absorbing Revetment on Wave Overtopping Rate (소파호안의 형상이 월파량에 미치는 영향)

  • Hur, Dong-Soo;Choi, Dong-Seok;Choi, Sun-Ho
    • Journal of Ocean Engineering and Technology
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    • v.22 no.6
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    • pp.7-12
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    • 2008
  • The present study numerically investigates the effect of the shape of absorbing revetment on wave overtopping rate under regular and irregular incident waves. At first, the numerical model developed by Hur and Choi(2008), which considers the flow through a porous medium with inertial, laminar and turbulent resistance terms, directly simulates Wave-Structure-Sandy seabed interaction and can determine the eddy viscosity with LES turbulent model in 2-Dimensional wave field (LES-WASS-2D), is validated when compared to experimental data. Numerical simulations are then performed to examine the effect of the shape of absorbing revetment and incident wave conditions on wave overtopping rate. The numerical result shows that the wave overtopping rate decreases with the slope gradient of absorbing revetment under both regular and irregular waves. In addition, the effects of mean grain size and porosity of absorbing revetment, incident wave period and crest height on wave overtopping rate are discussed.

Affective Design for the Frame Size and Shape of Wide LCD Monitors (Wide LCD 모니터의 프레임 형태에 따른 감성 선호도 연구)

  • Lee, Han-Na;Jung, Eui-S.;Choe, Jae-Ho
    • Journal of the Ergonomics Society of Korea
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    • v.28 no.4
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    • pp.61-69
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    • 2009
  • With increasing needs for affective design, it became an essential part in a product development process to look up quantitative ergonomic data that reflects customers' preferences on design factors in various products. This study looked at wide LCD monitors and analyzed customers' affective preferences regarding monitor's bezel frame size and shape. The monitor's bezel frame depth, size and ratio were selected as independent variables among many design parameters. As dependent variables, customer's subjective preferences were measured. A statistical analysis revealed that monitor's bezel frame depth, size and ratio had significant effects on customer's preferences. Also, it was possible to find a different tendency on affective variables and their levels for 19" and 24" wide LCD monitors. In general, experiments revealed that customers reacted more sensitively in 24" wide LCD monitors to all variables. In 19" wide LCD monitors, only the lower frame bezel size had a significant effect, otherwise, lower, upper and side frame bezels appeared to be effective variables in 24" monitors. In order to reflect customer's affective preferences to new design of wide LCD monitors, this study is expected to provide quantitative ergonomic data and guidelines for the design of wide LCD monitor's bezel frame depth and size.

Size and Shape Effect of Metal Oxides on Hydrocarbon Selective Catalytic Reduction of Nitrogen Oxides (금속 산화물 촉매의 크기와 형태에 따른 질소산화물의 탄화수소 선택적 촉매환원 특성)

  • Ihm, Tae-Heon;Jo, Jin-Oh;Hyun, Young Jin;Mok, Young Sun
    • Journal of the Korean Institute of Gas
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    • v.19 no.5
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    • pp.20-28
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    • 2015
  • This work investigated the size and shape effect of ${\gamma}$-alumina-supported metal oxides on the hydrocarbon selective catalytic reduction of nitrogen oxides. Several metal oxides including Ag, Cu and Ru were used as the catalysts, and n-heptane as the reducing agent. For the Ag/${\gamma}$-alumina catalyst, the $NO_x$ reduction efficiency in the range of $250{\sim}400^{\circ}C$ increased as the size of Ag decreased (20 nm>50 nm>80 nm). The shape effect of metal oxides on the $NO_x$ reduction was examined with spherical- and wire-shape nanoparticles. Under identical condition, higher catalytic activity for $NO_x$ reduction was observed with Ag and Cu wires than with the spheres, while spherical- and wire-shape Ru exhibited similar $NO_x$ reduction efficiency to each other. Among the metal oxides examined, the best catalytic activity for $NO_x$ reduction was obtained with Ag wire, showing almost complete $NO_x$ removal at a temperature of $300^{\circ}C$. For Cu and Ru catalysts, considerable amount of NO was oxidized to $NO_2$, rather than reduced to $N_2$, leading to lower $NO_x$ reduction efficiency.

Effect of Surface Roughness of Rheometer on the Slip Phenomenon in the Viscosity Measurement of PIM Feedstock (분말사출재의 점도 측정 시 측정기 표면 조도가 미끄럼 현상에 미치는 영향)

  • 이병옥;민상준
    • Journal of Powder Materials
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    • v.9 no.4
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    • pp.251-260
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    • 2002
  • In the viscosity measurement of PIM feedstock, slip correction methods require a number of experiments and produce a high level of error. In this study, a rotational rheometer with a parallel-discs configuration having different surface roughness was tried to minimize the effect of the slip phenomenon. Disc surface was prepared in 3 different roughness conditions - a smooth and 2 roughened surfaces. Results with the roughened surfaces were compared with the results obtained with a slip correction method. Relationship between powder characteristics such as size and shape and a surface roughness of the disc was examined for feedstock of 4 different powders with a same binder. As results, the effect of the slip phenomenon could be sufficiently minimized on the roughened surface in most cases. However, the effect of the slip phenomenon could not be sufficiently minimized for feedstock of a round-particular-shape powder and in the case of very narrow gap size.

Fabrication of Porous TiNi Alloys by Self-propagating High-temperature Synthesis (자전연소반응에 의한 TiNi 다공체 합금 제조에 관한 연구)

  • 이상진;권대환;배승열;안인섭;김유영
    • Journal of Powder Materials
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    • v.9 no.2
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    • pp.96-102
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    • 2002
  • In the present study, equiatomic porous TiNi shape-memory alloys have been successfully prepared by self-propagating high-temperature synthesis (SHS) using elemental titanium and nickel powders. The porous TiNi alloys thus obtained have an open porous structure with about 64 vol.% porosity, and the pore size is about 1.8 mm. The effect of preheating temperature on the microstructure have been investigated. It is found that the pore size increases with increasing preheating temperature. Moreover, the preheating temperature was shown to have a significant effect on the microstructrue of the SHS-synthesized porous TiNi shape memory alloys.

The effect of micro pore on the characteristics of crack tip plastic zone in concrete

  • Haeri, Hadi;Sarfarazi, V.
    • Computers and Concrete
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    • v.17 no.1
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    • pp.107-127
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    • 2016
  • Concrete is a heterogeneous material containing many weaknesses such as micro-cracks, pores and grain boundaries. The crack growth mechanism and failure behavior of concrete structures depend on the plastic deformation created by these weaknesses. In this article the non-linear finite element method is used to analyze the effect of presence of micro pore near a crack tip on both of the characteristics of crack tip plastic zone (its shape and size) and crack growth properties (such as crack growth length and crack initiation angle) under pure shear loading. The FE Code Franc2D/L is used to carry out these objectives. The effects of the crack-pore configurations and the spacing between micro pore and pre-excising crack tip on the characteristics of crack tip plastic zone and crack growth properties is highlighted. Based on the obtained results, the relative distance between the crack tip and the micro pore affects in very significant way the shape and the size of the crack tip plastic zone. Furthermore, crack growth length and crack initiation angle are mostly influenced by size and shape of plastic zone ahead of crack tip. Also the effects of pore decrease on the crack tip by variation of pore situation from linear to perpendicular configuration. The critical position for a micro pore is in front of the crack tip.