• Title/Summary/Keyword: Site symmetry

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COMPARATIVE STUDY OF POSTOPERATIVE SKELETAL SYMMETRY RELATED TO SURGICAL METHODS IN UNILATERAL CONDYLAR HYPERPLASIA (CONDYLECTOMY VS RAMUS SURGERY) (편측성 하악과두증식증에서 수술방법에 의한 술후 골격구조의 대칭성에 관한 비교연구)

  • Lee, Jeong-Gu;Hong, Kwang-Jin;Min, Byeong-Jin;Lee, Won-Hak;Cho, Yoon-Joo
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.18 no.2
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    • pp.200-207
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    • 1996
  • In patients with unilateral condylar hyperplasia, increased length of the condylar neck causes deviation of the mandible to the opposite site, resulting in facial asymmetry, but the arch form and general contour of the displaced mandible is approximately symmetric. So, the unilateral condylectomy have been prefered surgical method among the surgeons. The purpose of this study is to analyze the postoperative results comparatively following two different surgical methods, condylectomy and ramus surgery, in unilateral condylar hyperplasia. Case of 6 patients with the unilateral condylar hyerplasia were analyzed in this study, 3 case of the condylectomy only, 3 cases of the ramus surgery, Clinical and radiographic evaluations were tried for comparison. In conclusion, comparative results between two groups did not show any significant difference, but we confirmed that unilateral condylectomy could be a excellent surgical methods in unilateral condylar hyperplasia thinking over the unique morphological characteristics of it.

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Bilateral Breast Reconstruction with Free TRAM Flaps (횡복직근 유리피판술에 의한 양측 유방 재건)

  • Ahn, Hee Chang
    • Archives of Reconstructive Microsurgery
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    • v.9 no.2
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    • pp.127-133
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    • 2000
  • Free TRAM flap is now increasingly suggested to patients requiring breast reconstruction after the mastectomy. This study is to introduce the experiences of bilateral free TRAM flaps for reconstruction of bilateral breasts and to suggest the way of getting the more satisfactory results. A total of 6 breasts were reconstructed in 3 patients using bilateral free TRAM flaps immediately following the mastectomy. Average operative time for bilateral breast reconstruction was 8 hours comparing to 6.5 hours for unilateral breast reconstruction. Partial or total flap loss did not occur in 6 flaps. Abdomen was repaired directly with muscle and fascia sparing technique without necessity of mesh graft. There was no complication in donor site like abdominal hernia. Bilateral breast reconstruction can achieve exceptionally good aesthetic result with low complication if it is performed with skillful technique and experience. The reason for this is that fairly good symmetry usually is obtained in the initial surgery and in most cases only minimal additional surgery is required to achieve a satisfactory aesthetic result. The one disadvantage of bilateral reconstruction with autologous tissue is the length of the surgical procedure. Although the initial bilateral breast reconstruction can be a long, tedious procedure if free flaps are used, it must be a valuable treatment option for bilaterally mastectomized patients.

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Crystal growth and dielectric properties of $La_{1/3}MO_3$ (M=Nb, Ta) by infrared floating zone method (적외선 용융대역법에 의한 $La_{1/3}MO_3$ (M=Nb, Ta) 단결정 성장 및 유전 특성)

  • Mitisuru Itoh
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.3
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    • pp.233-239
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    • 1995
  • $La_{1/3}NbO_3$ and $La_{1/3}TaO_3$ large single crystal was prepared by the infrared floating zone method and their crystal structure and dielectric properties were investigated from the viewpoint of A - site vacancy. In $La_{1/3}TaO_3$ crystal, the crystal symmetry and approximate lattice constants was tetragonal and a $\approx$ 0.397, b $\approx$ 0.397 and c $\approx$ 0.775 from the nonextinction and the reciprocal lattice point length seen on Weissenberg and Precession photographs. The jump of some $2/3La^{3+}$ ions leads to increase the moving paths due to the generation of new vacancies at middle empty sites and thus this result is confirmed to provoke the dielectric anomaly.

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Response Properties of Acupuncture Stimulation by Meridian Electrical Potential Measurement (침구경략전위 측정에 의한 침 자극 반응 특성)

  • Ryu, Yeon-Hang;Jung, Byung-Jo;Lee, Yong-Heum
    • Journal of Biomedical Engineering Research
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    • v.29 no.5
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    • pp.408-413
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    • 2008
  • Human body has a complete left and right symmetry structure, and the left and right balance by Yin and Yang. When the balance is broken, the left and right Meridian becomes abnormal condition. Acupuncture is a kind of therapy to recover from energy unbalance of the left and right Meridian to a new balance condition. In the study, we observed the electric potential along the stomach meridian (ST) in order to verify the energy consensus phenomenon by transportation of bio-energy between operator and subject during acupuncture. The acupuncture effects on opposite meridian site were investigated by comparing the electric potentials between the right and left ST sites. Meridian electrical potentials (MEPs) between operator and subject were simultaneously generated during the acupuncture and the polarity of MEPs was opposite. The results might imply the bio-energy transportation between operator and subject. In addition, we observed three different patterns of MEPs on both ST sites which might represent the condition of the related meridians because meridians in the body are organically interconnected.

Application of Thermography in Thoroughbred Horses (말에서 체열찰영술의 적용에 관한 연구)

  • 양영진;조길재;손원근;남치주
    • Journal of Veterinary Clinics
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    • v.19 no.2
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    • pp.139-146
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    • 2002
  • The purpose of this study was to construct fundamental information for the usefulness and effects of thermography in Thoroughbred horses. total 10 horses were examined to determine a normal thermal pattern before and after sedation in lower limbs and ophthalmic area, and to investigate the effects of thermography during 42 days after induced wound and arthritis. In normal horses, the range of temperature difference(${\Delta}T$) of symmetry site in lower limbs was 0.20 to $0.68^{\circ}C$ on pre-sedation, which was simillar to that of post sedation, 0.17 to $0.74^{\circ}C$, and eyeball area was 0.34 to $0.68^{\circ}C$. Thermographically, the warmest area in normal limbs were coronary band of frontal view and the region between heel bulbs of back view. And temperature difference(${\Delta}T$) after clipping in left forelimb was increased 1 to $3^{\circ}C$ more than before clipping. However, there was no significant change of the temperature difference and degree of clinical signs by the process of inflammation healing during the experiment period in the all groups. These results suggest that the thermography was especially helpful in following clinical course of a disease because the thermal pattern will return to normal with declining clinical signs and healing of the lesion.

First-principle investigations of the binding between carbon nanotubes and poly(acrylonitrile)

  • Lee, Juho
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.304-307
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    • 2015
  • Carbon nanotubes (CNTs) have been widely accepted and used as the enhancer for polymer nano-composites due to their remarkable mechanical properties. Understandably, the CNT fiber-polymer matrix interface plays a major role in determining the properties of the CNT-polymer nano-composites. Here, using the LCAODFT Lab tool available on the EDISON Nano-Physics site, we performed first-principles density-functional theory calculations to determine the atomic configurations and binding energies of the CNTs in contact with polymers. For the polymer matrixes, we chose poly(acrylonitrile) (PAN), which is one of the most well-known polymer matrixes for the carbon nanofiber nanocomposites. Different chiralities and diameters of pristine CNTs were considered, and several PAN-CNT configurations were prepared based on the atomistic positions and directions of cyano group in PAN. The most favorable configuration of PAN was obtained when the PAN bound parallel to the surface of CNT. Our finding indicates the binding configurations are determined by the direction of the cyano group dominantly rather than the atomistic position of PAN, or the symmetry of CNTs. The result of increasing the length of CNT diameter suggests that PAN is inclinable to align evenly on the surface of relatively large size of CNT with the configuration parallel to the surface. These results obtained in this study will provide the starting point for the design of improved PAN-CNT composites for the next-generation ultra-strong and ultra-light carbon nanofibers.

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Luminescence and Crystal-Field Analysis of Europium and Terbium Complexes with Oxydiacetate and 1,10-Phenanthroline

  • Kang, Jun-Gill;Kim, Tack-Jin
    • Bulletin of the Korean Chemical Society
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    • v.26 no.7
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    • pp.1057-1064
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    • 2005
  • Photoluminescence (PL) spectra of Eu(III) and Tb(III) complexes with mixed oxydiacetate (ODA) and 1,10-phenanthroline (phen) ligands and with homoleptic ODA reveal characteristic line-splitting at 10 K, depending on the site-symmetry of the lanthanide ion in the complex. The energy-level schemes of the $^7F_J$ states and the emitting levels for Eu(III) and Tb(III) ions have been proposed by simulating the line splitting in the framework of crystal-field Hamiltonian. The sets of refined crystal-field parameters for the experimentally determined sitesymmetry satisfactorily reproduce the experimental energy-level schemes. In addition, the PL quantum yield and the decay time were determined at room temperature. The PL quantum yields of [$Eu(ODA){\cdot}(phen){\cdot}4H_2O]^+$ and [Tb$(ODA){\cdot}(phen){\cdot}4H_2O]^+$ in the crystalline state (Q = 17.7 and Q = 56.6%, respectively) are much greater than those of [Eu($ODA)_3]^{3-}and\;[Tb(ODA)_3]^{3-}$(Q = 1.1 and Q = 1.3, respectively), due to the energy transfer from phen to the lanthanide ion. In the aqueous state, the relaxation of the phen moiety due to the solvent results in the reduction of the quantum yield and the shortening of the lifetime.

Formation of Pyro-products by the Pyrolysis of Monobromophenols

  • Na, Yun-Cheol;Seo, Jung-Ju;Hong, Jong-Ki
    • Bulletin of the Korean Chemical Society
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    • v.24 no.9
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    • pp.1276-1280
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    • 2003
  • Thermal behavior of bromphenols was investigated by direct pyrolysis at high temperature. The thermal degradation products formed by the pyrolysis of mono-bromophenols (o-, m-, and p-) were identified by gas chromatography-mass spectrometry. During the pyrolysis reactions, several kinds of dioxins and furans were produced, and the relative ratio of pyro-products was dependent on the substituted position of bromine in phenolic structure due to the effect of symmetry and steric hindrance. The formation of dioxins can be explained by the phenoxy radical addition and Br atom elimination at an ortho-carbon site on phenolic structure. On the other hand, the formation of furans can be explained by the ortho-ortho carbon coupling of phenoxy radicals at unsubstituted sites to form o, o'-dihydroxydiphenyl intermediate via its keto-tautomer, followed by $H_2O$ elimination. The pyrolysis temperature has also a substantial effect on the dimerized products quantities but little effect on the type of pyro-products. Moreover, the formation mechanism of pyro-products was suggested on the basis of products identified.

Metal-Insulator Transition Induced by Short Range Magnetic Ordering in Mono-layered Manganite

  • Chi, E.O.;Kim, W.S.;Hong, C.S.;Hur, N.H.;Choi, Y.N.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.5
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    • pp.573-578
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    • 2003
  • The structural, magnetic, and transport properties of a mono-layered manganite $La_{0.7}Sr_{1.3}MnO_{4+{\delta}}$ were investigated using variable temperature neutron powder diffraction as well as magnetization and transport measurements. The compound adopts the tetragonal I4/mmm symmetry and exhibits no magnetic reflection in the temperature region of 10 K ≤ T ≤ 300 K. A weak ferromagnetic (FM) transition occurs about 130 K, which almost coincides with the onset of a metal-insulator (M-I) transition. Extra oxygen that occupies the interstitial site between the [(La,Sr)O] layers makes the spacing between the [MnO₂] layers shorten, which enhances the inter-layer coupling and eventually leads to the M-I transition. We also found negative magneto resistance (MR) below the M-I transition temperature, which can be understood on the basis of the percolative transport via FM metallic domains in the antiferromagnetic (AFM) insulating matrix.

Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups

  • Denisenko, Yu.G.;Aleksandrovsky, A.S.;Atuchin, V.V.;Krylov, A.S.;Molokeev, M.S.;Oreshonkov, A.S.;Shestakov, N.P.;Andreev, O.V.
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.109-116
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    • 2018
  • $Eu_2(SO_4)_3$ was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group C2/c. In the air environment, $Eu_2(SO_4)_3$ is stable up to $670^{\circ}C$. The sample of $Eu_2(SO_4)_3$ was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of $SO_4$ tetrahedra results in the appearance of the IR inactive ${\nu}_1$ mode around $1000cm^{-1}$ and ${\nu}_2$ modes below $500cm^{-1}$. The band intensities redistribution in the luminescent spectra of $Eu^{3+}$ ions is analyzed in terms of the peculiarities of its local environment.