• 분석과학
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• 제6권2호
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• pp.181-195
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• 1993

SUS(Stainless Steel) 분말을 이용하여 기존의 고가 내마모 소결부품을 대체할 수 있는 새로운 내마모재의 개발 가능성을 조사하였다. SUS 조성의 분말에 Cu, ZrC, C 및 Ti 등의 합금원소를 첨가하여 소결체의 밀도, 소결시의 수축률 및 경도의 변화를 조사하였다. 이러한 첨가원소의 영향 중에서 가장 뛰어난 기계적 성질을 나타낸 것은 Ti을 첨가한 SUS재였으며, 3% Ti 첨가시 기존의 내마모 소결 부품을 대체할 수 있는 수축률(6.5%), 밀도($7.35g/cm^3$) 및 경도(43HRC)를 보여 주었다.

• 한국분말재료학회지
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• 제10권3호
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• pp.172-175
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• 2003

Mechanically-alloyed NiAl powder was sintered by Spark-Plasma Sintering (SPS) process. Densification and behavior mechanical property were determined from the experimental results and analysis ,such as changes in linear shrinkage, shrinkage rate, microstructure, and phase during sintering process, Victors hardness, and transver.ie-rupture-strength (TRS). Above 97% relative density was obtained after sintering at 115$0^{\circ}C$ for 5 min. Crystallite size determined by the Scherrer method was approximately 50 nm. From the X-ray diffraction analysis it was confirmed that the sintered bodies were composed mainly of NiAl phase together with Ni$_3$Al phase. Measured Vickers hardness and TRS value were 555$\pm$10 $H_v$ and 1393$\pm$75 MPa , respectively.

• 한국신뢰성학회지:신뢰성응용연구
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• 제15권3호
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• pp.216-221
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• 2015

Sintering behavior of 3%yttria-stabilized zirconia was comparatively studied using a spray-dried powder produced by a domestic and global company. Quality of the sintered block was analysed in terms of relative density, shrinkage rate, grain growth, hardness, and fracture toughness. Relative density, shrinkage rate, and hardness value of the finally sintered block was similar between domestic and global zirconia powder, respectively. But, flexural strength of the domestic powder specimen was about 70% of the sintered block produced by using a global powder. The poor sintering quality of the domestic powder was discussed in relation with compressibility of the spray-dried granule-type powder and the amount of monoclinic phase in the as-received powder.

• 한국세라믹학회지
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• 제29권6호
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• pp.419-430
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• 1992

Fabrication possibility of low-shrinkage alumina without oxidation and wetting agent was presented on the basis of observation about oxidation behavior, microstructure and physical characteristics of such reaction agents free Al2O3-Al system. The composition less than Al 10w/o where Al can act as a sintering agent for Al2O3 was excluded. Under the condition of present experiments oxidation of Al2O3-Al system was dependent not on holding time but mainly on oxidation temperature. In thes case of Al powder not comminuted effectively during powder mixing of Al2O3-Al, columnar structure which would act as a hindrance to the densification during sintering developed more during oxidation with higher Al contents, and which made the fabrication of low-shrinkage Al2O3 ceramics impossible. If Al powder was comminuted effectively due to co-mixed Al2O3 characteristics, densification was improved because of no columnar structure and made the fabrication of sintered body with -2.7% dimensional change and 81% relative density possible. As a result, it is possible to fabricate dense low-shrinkage Al2O3 ceramics without oxidation and wetting agent under conditions such as smaller particle size of Al, Al contents below 50v/o, higher green density of Al2O3-Al compact and the use of Al2O3 powder used for high-density ceramics.

• 대한치과기공학회지
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• 제39권3호
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• pp.145-152
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• 2017

Purpose: This study sought to identify changes in the mechanical characteristics and color of zirconia according to different sintering temperatures of the substance. Methods: This study processed some specimens of zirconia into those of $8mm(H){\times}10mm(W){\times}50mm(L){\pm}0.1$ each, and sintered them at $1450{\sim}1600^{\circ}C$ on a $50^{\circ}C-interval$ basis in order to examine how their mechanical characteristics and color are changed. Each specimen sintered using the spectral colorimetric apparatus (Easyshade, VITA, Germany) was observed for each of the color change by sintering temperature. Results: When those specimens were sintered at $1450{\sim}1600^{\circ}C$, they were 0% in absorption ratio and porosity, 20% in shrinkage ratio and $6.10g/cm^3$ in specific gravity. Absorption ration, porosity, shrinkage ratio and specific gravity all didn't vary depending on the sintering temperature. The fracture strength of the specimens was highest or 1037MPa at the sintering temperature of $1550^{\circ}C$ and a little lower or 989MPa at that of $1600^{\circ}C$. No variation in L* value was found depending on the sintering temperature of the specimens, while c* value was highest at that of $1450^{\circ}C$. In addition, h* value was highest when the specimens was sintered at $1550^{\circ}C$. Conclusion: This study could determine how zirconia shows changes in mechanical characteristics and color in accordance with different temperatures of its sintering. It is necessary to supplement the physical data of colored transparent zirconia block which is expected to be widely used in clinical practice.

• 한국세라믹학회지
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• 제56권2호
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• pp.130-145
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• 2019

Widespread commercialization of solid oxide fuel cells (SOFCs) is expected to be realized in various application fields with the advent of cost-effective fabrication of cells and stacks in high volumes. Cost-reduction efforts have focused on production yield, power density, operation temperature, and continuous manufacturing. In this article, we examine several issues associated with processing for SOFCs from the standpoint of the bimodal packing model, considering the external constraints imposed by rigid substrates. Optimum compositions of composite cathode materials with high volume fractions of the second phase (particles dispersed in matrix) have been analyzed using the bimodal packing model. Constrained sintering of thin electrolyte layers is also discussed in terms of bimodal packing, with emphasis on the clustering of dispersed particles during anisotropic shrinkage. Finally, the structural transition of dispersed particle clusters during constrained sintering has been correlated with the structural stability of thin-film electrolyte layers deposited on porous solid substrates.

• 한국세라믹학회지
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• 제16권1호
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• pp.31-37
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• 1979

The middle point of composition within the system $MgO-Al_2O_3-SiO_2$ has been studied for applicability as ceramics dielectrics. A Kyul Sung Tale of high purity, magnesia clinker of Sam-wha chemical company, C.P. aluminium oxide, calcium carbonate, red lead, barium carbonate which was made into frit were used the raw materials. A number of steatite ceramics were prepared under carefully controlled condition and the water absorption, linear shrinkage, power factor, dielectric constant and dielectric loss were measured at elevated temperature. When we used magnesia clinker as flux, the quantity of this flux was 0.05mole, sintering temperature was continued for 2 hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose power factor was 0.142%, water absorption was zero, linear shrinkage was 8.76%, dielectric constant was 5.63, dielectric loss was 0.00799. When we used red lead as flux, the quantity of this flux was 0.033mole and 0.066mole, sintering temperature was continued for 2hrs. at 1, 26$0^{\circ}C$. From this conditions, we could get the data whose water absorption was zero, linear shrinkage was 8.03%, and 8.48%, power factor was 0.136% and 0.062%, dielectric loss was 0.0072 and 0.0037. When we used barium carbonate made into frit as flux, the quantity of this flux was 0.02mole, sintering temperature was continued for 2hrs. at 1, 27$0^{\circ}C$. From this conditions, we could get the data whose water absoption was zero, linear shrinkage was 8.44%, power factor was 0.138%, dielectric constant was 5.69, dielectric loss was 0.0074.

• 한국세라믹학회지
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• 제22권1호
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• pp.60-66
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• 1985

Hard shaped bodies are made by sintering a cold-pressed compact of a boron carbide compound which contains a densification aid. Titanium diboride and carbon were used as a densification aid in a range of 1% to 10% by weight. The effects of sintering temperature and additives on linear shrinkage porosity hardness bend strength and microstructure were examined. The initial partical size dependence on the sintered density was also discussed.

• 한국세라믹학회지
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• 제31권11호
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• pp.1265-1270
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• 1994

Ultra-fine hydroxyapatite powder were synthesized by the hydrothermal reaction at 10 atm, 3 hrs of Ca(OH)2 suspension with (NH4)2HPO4 solution, and were characterized sintering behavior. Sintered bodies of hydroxyapatite powders which synthesized by hydrothermal reaction method has less weight loss, less sintering shrinkage and superior mechanical property, and was more dense than sintered bodies of hydroxyapatite powder which synthesized by wet method. Sintered bodies were hydroxyapatite single phase. When soack in Ringer's solution for 2 weeks, hydroxyapatite powders preserved hydroxyapatite and sintered body absorbed trace of Ca2+ ion with soaked time.

• 한국세라믹학회지
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• 제31권9호
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• pp.957-968
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• 1994

Manufacturing process of porous glass by the filler method was studied. Commercial soda-lime-silicate glass powder was mixed with inorganic salt as the filler such as KCl, K2SO4, Na2SO4. Sintering shrinkages of mixed powders with the variation of sintering temperature were compared, and the effects of the fillers to shrinkages of mixed powder were increased in the order of Na2SO4${\mu}{\textrm}{m}$ of pore diameter were manufactured when the filler sizes 100~200 ${\mu}{\textrm}{m}$. The open pore volume of porous glass is determined by the quantity of filler and porous glasses having open pore volume between 30 and 70 vol% are available. Available sintering temperature range for preparation of porous glass is from the softening temperature of the glass powder to eutectic melting temperature of DTA curve of mixed powder.