• 대한금속재료학회지
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• 제49권11호
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• pp.845-852
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• 2011

The Spark Plasma Sintering(SPS) method offers a means of fabricating a sintered-body having high density without grain growth through short sintering time and a one-step process. A titanium compact having high density and purity was fabricated by the SPS process. It can be used to fabricate a Ti sputtering target with controlled parameters such as sintering temperature, heating rate, and pressure to establish the optimized processing conditions. The compact/target(?) has a diameter of ${\Phi}150{\times}6.35mm$. The density, purity, phase transformation, and microstructure of the Ti compact were analyzed by Archimedes, ICP, XRD and FE-SEM. A Ti thin-film fabricated on a $Si/SiO_2$ substrate by a sputtering device (SRN-100) was analyzed by XRD, TEM, and SIMS. Density and grain size were up to 99% and below $40{\mu}m$, respectively. The specific resistivity of the optimized Ti target was $8.63{\times}10^{-6}{\Omega}{\cdot}cm$.

• 에너지공학
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• 제19권3호
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• pp.163-170
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• 2010

소결버너를 이용한 표면점화는 제철공정에서 철광석의 소결을 위한 중요한 공정 중 하나이다. 본 연구에서는 듀얼 타입 소결 버너의 연소 특성을 분석하기 위하여 실험실적 규모의 실험과 전산 해석을 수행하였다. 라디칼 측정을 통해 연소특성을 파악하였으며, 열전대를 이용한 실험과 전산 해석 결과를 검증하였다. 검증된 전산 해석 모델을 바탕으로 싱글타입 소결 버너와 듀얼 타입 소결버너의 연소를 비교하였으며, 노즐 간격과 각도가 연소에 미치는 영향을 분석하기 위하여 3가지 노즐 간격 및 4개의 노즐 각도에 대한 전산해석을 수행하였다. 듀얼 타입이 싱글 타입 소결 버너보다 넓고 균일한 화염 폭을 형성함을 확인하였으며, 45도 비대칭 노즐 간격이 소결 베드 표면 점화를 위한 최적의 화염 폭을 형성함을 확인할 수 있었다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2006년도 춘계학술대회 논문집
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• pp.197-198
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• 2006

In the solid freeform fabrication (SFF) system using selective laser sintering (SLS), polyamide-12 powder is currently recognized as general material. In this study, some kinds of polyamide-6 powders with different shape and particlesize were fabricated to investigate the formability, the microstructure and mechanical properties. Also, to develop a more elaborate and rapid system, this study employs a new SLS device with a 3-axis dynamic focusing scanner system instead of the existing fe lens used in commercial SLS. Polyamide-6 powders having the average size of 100 m were treated thermally in order to keep the spherical symmetry in shape. These polyamide-6 powders were mixed with polyamide-12 powders having the average size of 50 m to give the bimodal distribution of size. These mixed powders showed the better fabrication in the selective laser sintering process because the smaller particles of polyamide-11 played an important role in the compact packing of powders by filling the void space between the large particles of polyamide-6. Also, Experiments have performed to evaluate the effect of a scanning path and sintering parameters by fabricating the various 3D objects.

• 한국세라믹학회지
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• 제50권5호
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• pp.333-340
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• 2013

To fabricate spherical lithium titanate ($Li_2TiO_3$) pebbles which are used for a breeder material in fusion reactor, titanium oxide ($TiO_2$) granules were used as a starting material. The granules were pre-sintered, and then aqueous lithium nitrate solution infiltrated into the granules at vacuum condition. The granules were crystallized to $Li_2TiO_3$ after sintering under the control of process parameters. In this study, the concentration of lithium in the solution, as well as the number of penetration times and sintering temperature affected the final crystallite phase and the microstructure of the pebbles. In particular, the sphericity and size of the pebbles were effectively controlled by a technical rolling process. The useful spherical $Li_2TiO_3$ pebbles which have 10~20% porosity and 60~120 N compressive strength were obtained through the sintering at $1000{\sim}1100^{\circ}C$ in the multi-times infiltration process with 50 wt% solution. The physical properties of pebbles such as density, porosity and strength, can be controlled by a selection of $TiO_2$ powders and control of processing parameters. It can be thought that the lithium penetration method is a useful method for the fabrication of mass product of spherical $Li_2TiO_3$ pebbles.

• Nuclear Engineering and Technology
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• 제56권7호
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• pp.2584-2594
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• 2024

A novel approach to incorporating oxide formers into ferritic ODS production has been developed using the co-precipitation technique. This method enables the tailored design of complex nano-oxides, integrated during Mechanical Alloying (MA) and precipitated during Spark Plasma Sintering (SPS) consolidation. Findings illustrate that co-precipitation effectively produces nano-powders with customised compositions, enriching Y, Ti, and Zr in the ferritic grade to condition subsequent oxide precipitation. While the addition of Y-Ti-Zr-O nano-oxides did not prevent the formation of Y-Al-O and Al-containing nano-oxides, these were refined thanks to the presence of well-dispersed Zr. Additionally, the Spark Plasma Sintering (SPS) parameters were optimised to tailor the bimodal grain size distribution of the ODS steels, aiming for favourable strength-to-ductility ratios. Comprehensive microstructural analyses were performed using SEM, EDS, EBSD, and TEM techniques, alongside mechanical assessments involving microtensile tests conducted at room temperature and small punch tests carried out at room temperature, 300 ℃, and 500 ℃. The outcomes yielded promising findings, showcasing similar or better performance with conventionally manufactured ODS steels. This reinforces the effectiveness and success of this innovative approach.

• Advances in concrete construction
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• 제13권4호
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• pp.291-305
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• 2022

The present investigation deals with the production of the innovative lightweight fly ash angular aggregates (FAA) first time in India using local class 'F' fly ash, its characterization, and exploring the potential for its utilization as alternative coarse aggregates in structural concrete applications. Two types of aggregates are manufactured using two different kinds of binders. The manufacturing process involves mixing fly ash, binder, and water, followed by the briquetting process, sintering and crushing them into suitable size aggregates. Tests are conducted on fly ash angular aggregates to measure their physical properties such as crushing value, impact value, specific gravity, water absorption, bulk density, and percentage of voids. Study shows that the physical parameters are significantly enhanced as compared to commercially available fly ash pellets (FAP). The developed FAA are used in concrete vis-à-vis conventional granite aggregates and FAP to determine their compressive, split tensile and flexural strengths. Although being lightweight, the strength parameters for concrete containing FAA are well compared with conventional concrete. This might be due to the high pozzolanic reaction between fly ash angular aggregates and cement paste. Also, RCC beams are cast and the load-deflection behaviour and ultimate load carrying capacity signify that FAA can be suitably used for RCC construction. Hence, the utilization of fly ash as angular aggregates can reduce the dead load of the structure and at the same time serves as a solution for fly ash disposal and mineral depletion problem.

• 한국세라믹학회지
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• 제49권5호
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• pp.427-431
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• 2012

The $TiO_2$ foam synthesized using freeze-casting is a promising photocatalyst and photovoltaic electrode for a variety of energy applications, because the freeze-casting technique is easy to use, cheap, and suitable for mass-production. Despite its several advantages, little scientific information is available on the processing and morphology of the $TiO_2$ foams processed by freeze-casting. In particular, no systematic study has been performed on the microstructural evolution and morphological change of the rutile-phase $TiO_2$ foams during sintering. Therefore, in the present study, several $TiO_2$ foam samples were produced using the freeze-casting technique, which were then sintered at a relatively high temperature of $1200^{\circ}C$ for 1, 2, and 4 h to compare the morphological changes in the microstructure and to understand the effects of processing parameters of the rutile-phase $TiO_2$ foams. The foam ligament size increased near linearly with increasing sintering time whereas the average pore size decreased only slightly with increasing sintering time, with changes in particle morphology from sphere to rod and complete phase transformation from anatase to rutile.

• 한국결정성장학회지
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• 제7권4호
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• pp.619-625
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• 1997

$Si_3N_4$에 2 wt% $Al_2O_3$와 6 wt% $Y_2O_3$을 첨가한 분말을 가스압소결 방법으로 시편을 제조하였다. 이때 소결시 조건(온도, 압력, 시간) 변화에 대한 기계적 특성 변화를 비교하였다. 이때 나타난 결과에 의하면 $1900^{\circ}C$, 3 MPa에서 1시간 동안 유지시켰을 때 최적의 조건을 갖는다는 것을 보여주었다. 이는 온도를 높여 주거나 유지 시간을 길게 하였을 때 입자 조대화에 의해 기계적 특성이 떨어지는 것을 볼 수 있었다. 그러나 압력을 증가시킬 때에는 미세한 조직을 가지므로 기계적 특성은 좋아짐을 나타내지만 파괴 인성이 떨어지는 것을 볼 수 있었다. 이로 인해 소결시 최적의 조건을 찾는 것이 중요함을 알 수 있었다.

• 한국생산제조학회지
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• 제22권1호
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• pp.173-177
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• 2013

The purpose of this paper is to investigate the influences on mechanical properties of two-stroke cycle motor pistons manufactured by casting, conventional forging and powder forging, through the comparison of characteristics, merits and disadvantages of each forming technology. For each forming technology, the optimal process parameters were determined through the experiments for several conditions, and microstructure, hardness, tensile strength and elongation of pistons are compared and analyzed. In conventional forging process, material temperature was $460^{\circ}C$ and the die temperature was $210^{\circ}C$ for the Al 4032. The optimal condition was found as solution treatment under $520^{\circ}C$ for 5 hours, quenching with $23^{\circ}C$ water, and aging under $190^{\circ}C$ for 5 hours. In powder forging process, the proper composition of material was determined and optimal sintering conditions were examined. From the experiment, 1.5% of Si contents on the total weight, $580^{\circ}C$ of sintering temperature, and 25 minutes of sintering time were determined as the optimal process condition. For the optimal condition, the pistons had 76.4~78.3 [HRB] of hardness, and 500 [MPa] of tensile strength after T6 heat treatment.

• 한국세라믹학회지
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• 제32권6호
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• pp.748-760
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• 1995

Pyroelectric properties, figure of merits, and the other properties of the Pb(Zn1/3Nb2/3)O3-Pb(Fe1/2Nb1/2)O3 system, as expected to have excellent pyroelectric properties in the operating temperature range of pyroelectric type infrared sensor, were investigated. In the Pb(Zn1/3Nb2/3)O3-Pb(Fe1/2Nb1/2)O3 system, suppression of the pyrochlore phase depended on sintering condition, as like sintering temperature, holding time, sintering atmosphere. The specimen, sintered by the same composition atmosphere powder at 105$0^{\circ}C$ for 1.5h, possessed the best physical property. It was found that the piezoelectric parameters were mainly depended on the amount of spontaneous polarization and then the 0.2PZN-0.8PFN showed the best pyro- and piezoelectric properties. In terms of the experimental method, two pyroelectric-testing methods, i.e. static and dynamic methods, had a same tendency. Also the result of pyroelectric testing by the static method indicated that the diffuse phase transitiion resulted in the temperature difference of phase transition between dielectric constant and pyroelectric coefficient.