• Title/Summary/Keyword: Single layer

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Synthesis of Phenanthridine-Containing Conjugated Copolymer and OLED Device Properties

  • Park, Lee-Soon;Jeong, Young-Chul;Han, Yoon-Soo;Kim, Sang-Dae;Kwon, Young-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.588-591
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    • 2004
  • Polyazomethine type conjugated copolymers containing phenanthridine units, poly(PZ-PTI), were synthesized by Schiff-base reaction. This new conjugated copolymer exhibited improved solubility in common organic solvents due to the presence of alkyl side chains as well as phenanthridine groups. Double layer (ITO/poly(PZ-PTI)/$Alq_3$/Mg) light emitting diode (LED) exhibited enhanced EL emission and efficiency compared to that of single layer (ITO/poly(PZ-PTI)/Mg) LED. With increasing the thickness of $Alq_3$ layer in double layer (ITO/poly(PZ-PTI)/$Alq_3$/Mg) LED the emission peak gradually shifted to the single layer (ITO/$Alq_3$/Mg) LED, confirming good hole transporting behaviour of the synthesized conjugated copolymer.

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A Comparative Study on the Buckling Characteristics of Single-layer and Double-layer Cylindrical Space Frame (단층 및 복층 원통형 스페이스 프레임의 좌굴특성에 관한 비교연구)

  • 강민화;정환목;권영환
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1995.10a
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    • pp.50-57
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    • 1995
  • Cylindrical space frame which have a mechanic property, a functional property, a aesthetic prioerty and so on, occupies one part of sin structures and after this, the using parts will be extended. But because this structure is made of network by combination of line elements there are many nodes the structural the structural behavior is very complicated and there can be a overall collapse of structure by buckling phenomenon if the external force reaches a limitation. In design for this structure, we must determinate layer by considering above mentioned property first of all. Therefore this study aimed at the comparison and the investigation of mechanical characteristics of single-layer and double-layer cylindrical space frame on views of behavior and buckling by use of rise ratio.

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High Quality Nano Structured Single Gas Barrier Layer by Neutral Beam Assisted Sputtering (NBAS) Process

  • Jang, Yun-Sung;Lee, You-Jong;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.251-252
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    • 2012
  • Recently, the growing interest in organic microelectronic devices including OLEDs has led to an increasing amount of research into their many potential applications in the area of flexible electronic devices based on plastic substrates. However, these organic devices require a gas barrier coating to prevent the permeation of water and oxygen because organic materials are highly susceptible to water and oxygen. In particular, high efficiency OLEDs require an extremely low Water Vapor Transition Rate (WVTR) of $1{\times}10^{-6}g/m^2$/day. The Key factor in high quality inorganic gas barrier formation for achieving the very low WVTR required ($1{\times}10^{-6}g/m^2$/day) is the suppression of defect sites and gas diffusion pathways between grain boundaries. In this study, we developed an $Al_2O_3$ nano-crystal structure single gas barrier layer using a Neutral Beam Assisted Sputtering (NBAS) process. The NBAS system is based on the conventional RF magnetron sputtering and neutral beam source. The neutral beam source consists of an electron cyclotron Resonance (ECR) plasma source and metal reflector. The Ar+ ions in the ECR plasma are accelerated in the plasma sheath between the plasma and reflector, which are then neutralized by Auger neutralization. The neutral beam energies were possible to estimate indirectly through previous experiments and binary collision model. The accelerating potential is the sum of the plasma potential and reflector bias. In previous experiments, while adjusting the reflector bias, changes in the plasma density and the plasma potential were not observed. The neutral beam energy is controlled by the metal reflector bias. The NBAS process can continuously change crystalline structures from an amorphous phase to nano-crystal phase of various grain sizes within a single inorganic thin film. These NBAS process effects can lead to the formation of a nano-crystal structure barrier layer which effectively limits gas diffusion through the pathways between grain boundaries. Our results verify the nano-crystal structure of the NBAS processed $Al_2O_3$ single gas barrier layer through dielectric constant measurement, break down field measurement, and TEM analysis. Finally, the WVTR of $Al_2O_3$ nano-crystal structure single gas barrier layer was measured to be under $5{\times}10^{-6}g/m^2$/day therefore we can confirm that NBAS processed $Al_2O_3$ nano-crystal structure single gas barrier layer is suitable for OLED application.

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MICROSTRUCTURE AND TRIBOLOGY OF $TiB_2$ AND $TiB_2$-TiN DOUBLE-LAYER COATINGS

  • Yang, Yunjie;Chen, Lizhi;Zheng, Zhihong;Wang, Xi;Liu, Xianghuai
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.40-48
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    • 1995
  • $TiB_2$-TiN double-layer coating have been prepared by ion beam enhanced deposition. AES, XRD, TEM and HRTEM were employed to characterize the $TiB_2$ layer. The microhardness of the coatings was evaluated by an ultra low-load microhardness indenter system, and the tribological behavior was examined by a ball-on-disc tribology wear tester. It was found that in a single titanium diboride layer, the composition is uniform along the depth of the film, and it is mainly composed of nanocrystalline $TiB_2$ with hexagonal structure, which resulted from the ion bombardment during the film growth. The hardness of the $TiB_2$ films increases with increasing ion energy, and approaches a maximum value of the $TiB_2$ films increases with increasing ion energy, and approaches a maximum value of 39 Gpa at ion energy of 85 keV. The tribological property of the TiB2 films is also improved by higher energy of 85keV. The tribological property of the $TiB_2$ films is also improved by higher energy ion beam bombardment. There is no major disparity in the mechanical properties of double-layer $TiB_2$/TiN coatings and TiN/$TiB_2$ coatings. Both show an improved wear resistance compared with single-layer $TiB_2$ films. The adhesion of double-layer coatings is also superior to that of single-layer films.

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Hydrogen Fluoride Vapor Etching of SiO2 Sacrificial Layer with Single Etch Hole (단일 식각 홀을 갖는 SiO2 희생층의 불화수소 증기 식각)

  • Chayeong Kim;Eunsik Noh;Kumjae Shin;Wonkyu Moon
    • Journal of Sensor Science and Technology
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    • v.32 no.5
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    • pp.328-333
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    • 2023
  • This study experimentally verified the etch rate of the SiO2 sacrificial layer etching process with a single etch hole using vapor-phase hydrogen fluoride (VHF) etching. To fabricate small-sized polysilicon etch holes, both circular and triangular pattern masks were employed. Etch holes were fabricated in the polysilicon thin film on the SiO2 sacrificial layer, and VHF etching was performed to release the polysilicon thin film. The lateral etch rate was measured for varying etch hole sizes and sacrificial layer thicknesses. Based on the measured results, we obtained an approximate equation for the etch rate as a function of the etch hole size and sacrificial layer thickness. The etch rates obtained in this study can be utilized to minimize structural damage caused by incomplete or excessive etching in sacrificial layer processes. In addition, the results of this study provide insights for optimizing sacrificial layer etching and properly designing the size and spacing of the etch holes. In the future, further research will be conducted to explore the formation of structures using chemical vapor deposition (CVD) processes to simultaneously seal etch hole and prevent adhesion owing to polysilicon film vibration.

Influence of Ag Nano-buffer Layer Thickness on the Opto-electrical Properties of AZO/Ag Transparent Electrode Films (Ag 나노완충층 두께에 따른 AZO/Ag 투명전극의 전기광학적 특성 연구)

  • Eom, Tae-Young;Song, Young-Hwan;Moon, Hyun-Joo;Kim, Dae-Hyun;Cho, Yun-Ju;Kim, Daeil
    • Journal of the Korean Society for Heat Treatment
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    • v.29 no.6
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    • pp.272-276
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    • 2016
  • Al doped ZnO (AZO) single layer and AZO/Ag bi-layered films were deposited on the glass substrates by radio frequency and direct current magnetron sputtering and then the effect of Ag buffer layer on the electrical and optical properties of the films was investigated. The thicknesses of AZO upper layer was kept as 100 nm, while Ag buffer layer was varied from 5 to 15 nm. The observed results mean that opto-electrical properties of the AZO films is influenced with Ag buffer layer and AZO film with 10 nm thick Ag buffer layer show the higher opto-electrical performance than that of the AZO single layer film prepared in this study.

Characteristics of Thin Films Fabricated by Using the Layer-by-Layer Sputtering and Evaporation Method (순차 스퍼터 법과 증발 법으로 제작한 박막의 특성)

  • Cheon, Min-Woo;Park, Yong-Pil;Kim, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.571-574
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    • 2003
  • The thin films fabricated by using the layer-by-layer sputtering was compared with the thin film fabricated by using the evaporation method. Re-evaporation in the form of Bi atoms or $Bi_2O_3$ molecules easily bring out the deficiency of Bi atoms in thin film due to the long sputtering time of the layer-by-layer deposition. On the other hand, the respective atom numbers corresponding to BiSrCaCuO phase is concurrently supplied on the film surface in the evaporation deposition process and leads to BiSrCaCuO phase formation. Also, it is cofirmed that by optimizing the deposition condition, each single phase of the Bi2201 phase and the Bi2212 phase can be fabricated, the sticking coefficient of Bi element is clearly related to the changing of substrate temperature and the formation of the Bi2212 phase.

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Synthesis of large area·single layer/crystalline graphene (대면적·단일층·단결정 그래핀의 합성)

  • Choi, Byung-Sang
    • The Journal of the Korea institute of electronic communication sciences
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    • v.9 no.2
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    • pp.167-171
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    • 2014
  • Using chemical vapor deposition(CVD), the synthesis of graphene was performed on poly and single crystalline Cu substrates. The growth behavior of graphene and its characterization were shown utilizing the optical microscopic image and its image analysis. As a result in the analysis of graphene growth, it was found out the graphene is growing always in particular direction in relation to the crystalline direction of a single grain in polycrystalline Cu substrate. With the image analysis it was possible to show the characterization of graphene, such as the growth direction and the number of layers showing single, double and triple layers, within the neighboring single grains in polycrystalline Cu. In addition, the relatively large area of graphene with about $3mm^2$ on Cu(111) having high quality, single layer, and single crystalline was shown along with its characterization.

Experimental Evaluation of FREE NODE with Axial Load and Moment for Single Layer Free-Form Structures (축력과 모멘트를 동시에 받는 FREE NODE의 실험적 평가)

  • Oh, Jin-Tak;Chung, Kwang-Ryang;Kim, Do-Hyun
    • Journal of Korean Association for Spatial Structures
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    • v.14 no.1
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    • pp.51-59
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    • 2014
  • Single layer free-form structures are being highlighted in the field of architecture due to its attractive shape. In these structures, node connecting system is very important because the node must resist bending and axial stress simultaneously. So the local and global stabilities of entire structure can be determined by the stiffness of node system. In this study, therefore, various types of bending test with axial force were performed. As a result, bending capacity with axial force of a new spherical node for free-form structure could be performed and structural capacities were checked to use in real structure.

A Study on MgCaO Protective Layer and Single Crystal MgO Powder Coating to Improve the Characteristic of AC-PDP (AC-PDP 특성 개선을 위한 MgCaO 보호층과 단결정 MgO 파우더 코팅에 대한 연구)

  • Park, Se-Hun;Wi, Sung-Suk;Kim, Dong-Hyun;Lee, Hae-June;Lee, Ho-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.2
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    • pp.243-250
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    • 2012
  • In this study, we attempted to reduce firing voltage of AC-PDP by alloying MgO protective Layer with CaO. Also, spray coating of single crystal MgO powder has been used to improving Exo-electron emission characteristics and reducing the statistical discharge delay in plasma displays. The properties of discharge depending upon the single crystal MgO powder are investigated. Plasma display having powder coated MgCaO Protective Layer shows lower driving voltage and higher efficacy than of uncoated, conventional panel.