• Title/Summary/Keyword: Single cavity

Search Result 465, Processing Time 0.033 seconds

Synthesis and Crystal Structure of Lead Iodide in the Sodalite Cavities of Zeolite A (LTA)

  • Kim, Seok-Han;Lim, Woo-Taik;Kim, Ghyung-Hwa;Lee, Heung-Soo;Heo, Nam-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.27 no.5
    • /
    • pp.679-686
    • /
    • 2006
  • The positions of $PbI _2$ molecule synthesized into the molecular-dimensioned cavities of $\mid K_6 (Pb _4I_2)(PbI_2) _{0.67}-(H_2O)_2\mid [Si _{12}Al _{12}O _{48}]$-LTA have been determined. A single crystal of $\mid Pb _6\mid [Si _{12}Al _{12}O _{48}]$-LTA, prepared by the dynamic ion-exchange of $\mid Na _{12}\mid [Si _{12}Al _{12}O _{48}]$-LTA with aqueous 0.05 M $Pb _(NO _3)_2$ and washed with deionized water, was placed in a stream of flowing aqueous 0.05 M KI at 294 K for three days. The resulting crystal structure of the product $( \mid K_6 (Pb _4I_2)(PbI_2) _{0.67}(H_2O)_2\mid [Si _{12}Al _{12}O _{48}]$-LTA, a = 12.353(1) $\AA$) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm3 m. It was refined with all measured reflections to the final error index $R_1$ = 0.062 for 623 reflections which $F_o$ > 4$\sigma$($F_o$). 4.67 $Pb ^{2+}$ and six $K^+$ ions per unit cell are found at three crystallographically distinct positions: 3.67 $Pb ^{2+}$ and three $K^+$ ions on the 3-fold axes opposite six-rings in the large cavity, three $K^+$ ions off the plane of the eight-rings, and the remaining one $Pb ^{2+}$ ion lies opposite four-ring in the large cavity. 0.67 $Pb ^{2+}$ ions and 1.34 $I^-$ ions per unit cell are found in the sodalite units, indicating the formation of a $PbI _2$ molecule in 67% of the sodalite units. Each $PbI _2$ (Pb-I = 3.392(7) $\AA$) is held in place by the coordination of its one $Pb ^{2+}$ ion to the zeolite framework (a $Pb ^{2+}$ cation is 0.74 $\AA$ from a six-ring oxygens) and by the coordination of its two $I^-$ ions to $K^+$ ions through six-rings (I-K = 3.63(4) $\AA$). Two additional $I^-$ ions per unit cell are found opposite a four-ring in the large cavity and form $Pb _2K_2I^{5+}$ and $Pb _2K_2I^{3+}$ moieties, respectively, and two water molecules per unit cell are also found on the 3-fold axes in the large cavity.

Synthesis and Crystal Structure of Ag4Br4 Nanoclusters in the Sodalite Cavities of Fully K+-Exchanged Zeolite A (LTA)

  • Lim, Woo-Taik;Choi, Sik-Young;Kim, Bok-Jo;Kim, Chang-Min;Lee, In-Su;Kim, Seok-Han;Heo, Nam-Ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.26 no.7
    • /
    • pp.1090-1096
    • /
    • 2005
  • $Ag_4Br_4$ nanoclusters have been synthesized in about 75% of the sodalite cavities of fully $K^+$-exchanged zeolite A (LTA). An additional KBr molecule is retained in each large cavity as part of a near square-planar $K_4Br^{3+}$ cation. A single crystal of $Ag_{12}$-A, prepared by the dynamic ion-exchange of $Na_{12}$-A with aqueous 0.05 M $AgNO_3$ and washed with $CH_3OH$, was placed in a stream of flowing 0.05 M KBr in $CH_3OH$ for two days. The crystal structure of the product ($K_9(K_4Br)Si_{12}Al_{12}O_{48}{\cdot}0.75Ag_4Br_4$, a = 12.186(1) $\AA$) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm m. It was refined with all measured reflections to the final error index $R_1$ = 0.080 for the 99 reflections for which $F_o\;{\gt}\;4_{\sigma}\;(F_o)$. The thirteen $K^+$ ions per unit cell are found at three crystallographically distinct positions: eight $K^+$ ions in the large cavity fill the six-ring site, three $K^+$ ions fill the eight-rings, and two $K^+$ ions are opposite four-rings in the large cavity. One bromide ion per unit cell lies opposite a four-ring in the large cavity, held there by two eight-ring and two six-ring $K^+$ ions ($K_4Br^{3+}$). Three $Ag^+$ and three $Br^-$ions per unit cell are found on 3-fold axes in the sodalite unit, indicating the formation of nano-sized $Ag_4Br_4$ clusters (interpenetrating tetrahedra; symmetry $T_d$; diameter ca. 7.9 $\AA$) in 75% of the sodalite units. Each cluster (Ag-Br = 2.93(3) $\AA$) is held in place by the coordination of its four $Ag^+$ ions to the zeolite framework (each $Ag^+$ cation is 2.52(3) $\AA$ from three six-ring oxygens) and by the coordination of its four $Br^-$ ions to $K^+$ ions through six-rings (Br-K = 3.00(4) $\AA$).

A comparative analysis of the total window thermal transmittance simulation result according to the evaluation method of effective conductivity(λeff) of frame cavity - Focused on unventilated frame cavity simulation results of single window - (창틀 공기층의 유효 열전도율(λeff) 산정방법 차이가 창 전체 열관류율(Uw) 시뮬레이션 결과에 미치는 영향에 대한 비교 분석 - 단창 창틀의 비환기 공기층에 대한 시뮬레이션을 중심으로 -)

  • Lee, Yong-jun;Oh, Eun-joo;Kim, Sa-kyum;Choi, Gyeong-seok;Kang, Jae-sik
    • KIEAE Journal
    • /
    • v.16 no.2
    • /
    • pp.79-85
    • /
    • 2016
  • Purpose: It is difficult to calculate frame U-value because of the two reason. First is selection of air properties in cavity. Second is calculation method in window frame. For this reason, it is important to decide cavity properties in window frame. However, international standards offered different method(ISO 15099, ISO 10077) and air properties was changed according to the two methods. The aim of this study was to suggest method for deriving accurate frame U-value using international standard methods and CFD simulation. Method: First, this study conducted analysis calculation method of ISO 15099 and ISO 10077. And, CFD simulation conducted based on same condition. Finally, ISO calculation and CFD simulation results were verified through comparison with real experiment results. Result: The results show that effective conductivity of ISO 15099 was the highest value. ISO 10077 and CFD result followed. The convergent values of ISO 10077 was the highest. ISO 15099 and CFD followed. ISO calculation reflecting CFD simulation results will reduce error with experimental results.

Surgical management of idiopathic bone cavity: case series of consecutive 27 patients

  • You, Myoung-Sang;Kim, Dong-Young;Ahn, Kang-Min
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
    • /
    • v.43 no.2
    • /
    • pp.94-99
    • /
    • 2017
  • Objectives: Idiopathic bone cavity (IBC) is an uncommon intra-osseous cavity of unknown etiology. Clinical features of IBC are not well known and treatment modalities of IBC are controversial. The purpose of this study was to investigate the clinical characteristics of 27 IBC patients who underwent surgical exploration. Materials and Methods: A total of 27 consecutive patients who underwent surgery due to a jaw bone cavity from April 2006 to February 2016 were included in this study. Nine male and 18 female patients were enrolled. Patients were examined retrospectively regarding primary site, history of trauma, graft material, radiographic size of the lesion, presence of interdental scalloping, erosion of the inferior border of the mandible, complications, results of bone graft, and recurrence. Results: Female dominance was found. Maxillary lesion was found in one patient, and bilateral posterior mandibular lesions were found in two patients. The other patients showed a single mandibular lesion. The posterior mandible (24 cases) was the most common site of IBC, followed by the anterior mandible (5 cases). Two patients with anterior mandibular lesion reported history of trauma due to car accident, while the others denied any trauma history. Radiographic cystic cavity length over 30 mm was found in 10 patients. Seven patients showed erosion of the mandibular inferior border. The operations performed were surgical exploration, curettage, and bone or collagen graft. One bilateral IBC patient showed recurrence of the lesion during follow-up. Grafted bone was integrated into the native mandibular bone without infection. One patient reported necrosis of the mandibular incisor pulp after operation. Conclusion: Differential diagnosis of IBC is difficult, and IBC is often confused with periapical cyst. Surgical exploration and bone graft are recommended for treating IBC. Endodontic treatment of involved teeth should be evaluated before operation. Bone graft is recommended to reduce the healing period.

Numerical Investigation of Serration Effect on the Helmholtz Resonance (헬름홀츠 공진에서 톱니 효과에 대한 수치적 연구)

  • Lee, Seungsoo;Jeon, Minu;Lee, Soogab
    • Transactions of the Korean Society for Noise and Vibration Engineering
    • /
    • v.26 no.1
    • /
    • pp.13-19
    • /
    • 2016
  • The flow-excited Helmholtz resonance phenomenon was investigated numerically using Reynolds averaged Navier-Stokes approach. The fundamental cause of the Helmholtz resonance phenomenon is known as shedding of a single discrete vortex from orifice edge that travels during one period of the oscillation. In this study, serrated deflector, which is biomimetic design of the owl's feather, is used to split a single vortex into small vortices. Rectangular deflector and serrated deflector are compared with numerical results of pressure and streamline inside the cavity. Consequently, the serration breaks the shedding period of vortex core and eliminates the resonance. Also, it changes the flow pattern in according to the location of different serration height. By making inflows and outflows occur simultaneously in spanwise direction in the cavity, the period of Helmholtz resonance disappears. Comparing between rectangular deflector and serrated deflector, the serrated deflector can deal with the Helmholtz resonance more effectively.

A study on the $TEM_{00}$ mode of the pulsed Nd:YAG laser with a single elliptical cavity (단일 타원 펄스형 Nd:YAG 레이저의 $TEM_{00}$ 모드화)

  • Lee, D.H.;Moon, J.K.;Kwak, B.G.;Kim, H.J.;Cho, J.S.;Park, C.H.
    • Proceedings of the KIEE Conference
    • /
    • 1996.07c
    • /
    • pp.1759-1761
    • /
    • 1996
  • Md:YAG laser has been used in many applications such as micromachining, nonlinear optical experiments, holography, and rangefinding. These applications quite often require operation of the laser at the $TEM_{00}$ mode since this mode produces the smallest beam divergence, the highest power density, and, hence, the highest brightness. In this study, a pinhole is put between a rod and a half mirror to make the $TEM_{00}$ mode, and then we measured the intensity distribution of the output beam as reducing the diameter of the pinhole from 6mm to 1.5mm. As a result, the optimum size of the pinhole fixed in a resonator to make the $TEM_{00}$ mode was obtained, and we found out that the output beam of the pulsed Nd:YAG laser with a single elliptical cavity has a Gaussian distribution.

  • PDF

Experimental Study of Heating Surface Angle Effects on Single Bubble Growth

  • Kim, Jeong-Bae;Kim, Hyung-Dae;Lee, Jang-Ho;Kwon, Young-Chul;Kim, Jeong-Hoon;Kim, Moo-Hwan
    • Journal of Mechanical Science and Technology
    • /
    • v.20 no.11
    • /
    • pp.1980-1992
    • /
    • 2006
  • Nucleate pool boiling experiments were performed using pure R11 for various surface angles under constant heat flux conditions during saturated pool boiling. A 1-mm-diameter circular heater with an artificial cavity in the center that was fabricated using a MEMS technique and a high-speed controller were used to maintain the constant heat flux. Bubble growth images were taken at 5000 frames per second using a high-speed CCD camera. The bubble geometry was obtained from the captured bubble images. The effects of the surface angle on the bubble growth behavior were analyzed for the initial and thermal growth regions using dimensional scales. The parameters that affected the bubble growth behavior were the bubble radius, bubble growth rate, sliding velocity, bubble shape, and advancing and receding contact angles. These phenomena require further analysis for various surface angles and the obtained constant heat flux data provide a good foundation for such future work.

The Anatomy and Histoarchitecture of the Olfactory Organ in the Korean Flat-Headed Goby Luciogobius guttatus (Pisces; Gobiidae)

  • Kim, Hyun-Tae;Park, Jong-Young
    • Applied Microscopy
    • /
    • v.46 no.1
    • /
    • pp.51-57
    • /
    • 2016
  • The histology and anatomy of the olfactory organ in Luciogobius guttatus was investigated using a light microscopy and scanning electron microscopy. The paired olfactory organs in the dorsal part of the snout are situated in between the upper lip and the eyes. They consist of two nostrils, one anterior and the other posterior openings, and a single olfactory cavity. The anterior nostril, an incurrent opening, forms a short tubular structure from the skin. The posterior nostril, an excurrent opening, forms a circular structure opened to the exterior. The distributional pattern of the sensory epithelium is a continuous type. The sensory epithelium with numerous-motile cilia is made up of receptor cells, supporting cells, basal cells, and mucous cells. In contrast, the non-sensory epithelium is comprised of stratified epithelial cells and two types of mucous cells, acidic and neutral cells. The cilia number of the receptor cell is in range of 3 to 4 units. Such results in L. guttatus may reflect its ecological habit and microhabitat in the tidal zone with a periodic tide.

Two new records of free-living marine nematodes of the family Ironidae de Man, 1876 (Nematoda: Enoplida) from Korea

  • Hyo Jin Lee;Heegab Lee;Hyun Soo Rho
    • Journal of Species Research
    • /
    • v.12 no.1
    • /
    • pp.55-67
    • /
    • 2023
  • Two new records of marine nematodes, belonging to the family Ironidae de Man, 1876, are reported based on the specimens collected from intertidal sediments from the west coast of Korea. Conilia sinensis is characterized by a relatively long body length, a well-developed buccal cavity with three claw-like teeth, the presence of a single spicule with transverse striations, the presence of rib-shaped telamons, and single precloacal supplement. Pheronous donghaiensis is distinguished from other species of the genus by a well-developed buccal cavity with four claw-like solid teeth and minute denticles, relatively short and thick spicules with the central septum, the presence of 8-9 curved tubular-shaped precloacal supplements, and a sharp pointed tail with three small tubular supplements arranged into two rows in males. In this report, we provide a taxonomic description and illustrations of two unrecorded species of the family Ironidae by differential interference contrast microscopy. This is the first taxonomic report on the species of the family Ironidae from Korea.