• Title/Summary/Keyword: Simulated solution

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Corrosion resistance performance of arc thermal sprayed Al and Al/epoxy dual metal polymeric coating in 3.5 wt.% NaCl-contaminated concrete pore solution (3.5 wt.% NaCl로 오염된 콘크리트 기공 용액에서 아크 용사 Al 및 Al/에폭시 이중 금속 고분자 코팅의 내식성 성능)

  • Singh, Jitendra Kumar;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.119-120
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    • 2023
  • Corrosion of the steel rebar in coastal environment caused huge economical loss of the globe. Therefore, coating on the steel rebar being used to mitigate the corrosion. In the present study, we have applied epoxy coating on arc thermal sprayed Al coating (a dual metal/polymeric coating) vis-à-vis compared with as coated one (Al coating). The corrosion studies were performed in simulated concrete pore solution with 3.5 wt. % NaCl solution. The morphology of the dual epoxy/Al coating is smooth while Al coating shows rankle and defects. Due to defects, Al coating is susceptible to corrosion while dual epoxy/Al coating has performed excellent compared to as coated one at extended period of immersion.

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Dispersion Characteristics of Carbon Black Particles in a High Viscous Simulated Solution (고점성 모사용액 내 Carbon Black 입자의 분산특성)

  • Jeong, Kyung-Chai;Eom, Sung-Ho;Kim, Yeon-Ku;Cho, Moon Sung
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.165-170
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    • 2013
  • An external gelation method in place of an internal gelation method applied to the fabrication process of an intermediated compound of Uranium Oxy-Carbide (UCO) kernel spheres for Very High Temperature Reactor (VHTR) fuel preparation is under development in Korea. For the preliminary experiments of the UCO kernel sphere preparation using an external gelation method, the carbon black dispersion experiments were carried out using a simulated broth solution. From the selection experiments of various kinds of carbon black through dispersion experiments in a viscous metal salt solution, Cabot G carbon black was selected owing to its dispersion stability, and the homogeneous dispersing state of carbon black particles in our system. For the effective dispersion of nano-size aggregated carbon black particles in a high viscous liquid, the carbon black particles in a metal salt solution were first de-aggregated with ultrasonic force. The mixed solution was then dispersed secondly by the use of the extremely high-speed agitation with a mechanical mixer of 6000 rpm after feeding the Poly Vinyl Alcohol (PVA) in the solution. This results in the broth solution with good stability and homogeneity alongside no further changes in physical properties.

Development of A Computer Simulation Program of Emitter Discharges for Trickle Application (점적 급액 방식에서의 양액 공급량 예측 프로그램의 개발)

  • 오길근;류관희;홍순호
    • Journal of Biosystems Engineering
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    • v.20 no.4
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    • pp.390-396
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    • 1995
  • This study was conducted to develop a computer simulation program for trickle application of nutrient solution. A computer simulation program using finite element method was developed to evaluate discharges of emitters on trickle application. The uniformity of application for two different lateral line lengths and three application methods was evaluated by the computer simulation program. The results of this study are as follows. 1. A computer simulation program was developed to determine emitter discharges from a trickle application system and pressures at emitter positions by finite element method and to design a uniform trickle application system. 2. The simulation program developed was verified by experiment. The root mean square error between experimental data and simulated data was 1.1% on the average discharge and it was found that the computer simulation program was an effective tool for the design of a trickle application system of nutrient solution. 3. The uniformity of trickle application system was evaluated for three different methods of supplying nutrient solution with different lateral line lengths. The best uniformity was obtained from the method, which supplies nutrient solution from both ends alternatively for the same period of time.

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Fabrication of Flow Cell Using Carbon Fiber and Electrochemical Decomposition Characteristics for Organic Dyes (탄소섬유전극을 이용한 흐름형 전기분해조 제작 및 유기염료의 전기화학적 분해 연구)

  • Park, Deog-Su
    • Journal of Environmental Science International
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    • v.21 no.11
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    • pp.1371-1377
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    • 2012
  • The simulated dyes solution containing Basic Red 46(BR 46), Yellow 21(Y 21), and Maxilon Blue 30(MB 30) were electrochemically oxidized using carbon fiber as an anode. The electrolyses were performed in a electrolytic flow cell constructed by Vycor glass tube. The carbon fiber was positioned in the inside of Vycor glass tube and platinum wire coiled around outside of tube as a cathode. Several operating variables, such as current, time, pH and flow rate of solution were studied. Increasing current density would lead to a corresponding increase in the dye removal efficiency 99.2 % at a 200 mA. The electrolyses time could also improve and removal efficiency was about 99 % after 1.5 hours of electrolyses. The removal efficiency was increased with the increase of flow rate of solution and optimum flow rate was 5 mL/min. THe pHs of solution affect the removal efficiency. The removal efficiency was decreased with the increase of pH of solution and optimum pH was 5.05 (0.1 M $KNO_3$).

A Z-map Update Method for Linearly Moving tools (직선 운동하는 공구에 대한 Z-맵의 갱신 방법)

  • 맹승렬;백낙훈;신성용;최병규
    • Korean Journal of Computational Design and Engineering
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    • v.7 no.4
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    • pp.219-232
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    • 2002
  • In numerically controlled(NC) machining simulation, a Z-map has been used frequently for representing a workpiece. Since the Z-map is usually represented by a set of Z-axis aligned vectors, the machining process can be simulated through calculating the intersection points between the vectors and the surface swept by a machining tool. In this paper, we present an efficient method to calculate those intersection points when an APT-type tool moves along a linear tool path. Each of the intersection points can be expressed as the solution of a system of non-linear equations. We transform this system of equations into a single-variable equation, and calculate the candidate interval in which the unique solution exists. We prove the existence of a solution and its uniqueness in this candidate interval. Based on these characteristics, we can effectively apply numerical methods to finally calculate the solution of the non-linear equations within a given precision. The whole process of NC simulation can be achieved by updating the Z-map properly. Our method can provide more accurate results with a little more processing time, in comparison with the previous closed-form solution.

Experimental and computational insights into the adsorption of a hydrazone-based heterocyclic compound on steel rebar in synthetic concrete pore solution (합성 콘크리트 공극 솔루션에서 철근에 히드라존 기반 헤테로고리 화합물의 흡착에 대한 실험 및 계산 통찰력)

  • Lgaz, Hassane;Karthick, Subbiah;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.73-74
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    • 2022
  • The corrosion inhibitive effect of a new hydrazone-based heterocyclic compound for steel in simulated concrete pore solution with 3.5 wt.% sodium chloride was investigated by experimental and computational techniques. Electrochemical studies, up to 30 days of immersion, and surface analysis (X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), and scanning electron microscope (SEM)) were performed to assess the corrosion protection abilities of investigated compound for steel rebar. Results showed that adding the organic compound to the chloride contaminated concrete pore solution decreased the corrosion rate of the steel rebar thanks to the effective adsorption of inhibitor molecules. After 30 days of immersion of steel rebar in inhibited chloride contaminated synthetic concrete pore solution, the inhibition efficiency exceeded 80% at low concentration of 1 mmol/L. Computational studies by Density Functional based Tight Binding (DFTB) method revealed the formation of covalent bonds between the hydrazone molecule and the iron surface.

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NMR Studies on N-terminal Domain of DNA2

  • Jung, Young-Sang;Lee, Kyoung-Hwa;Jung, Jin-Won;Lee, Weontae
    • Journal of the Korean Magnetic Resonance Society
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    • v.4 no.2
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    • pp.74-81
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    • 2000
  • Saccharomyces cerevisiae Dna2 protein has biochemical activities: DNA-dependent ATPase, DNA helicase and DNA nuclease and is essential for cell viability. Especially, Pro$\^$504/ is determined as an important residue in ATPase, helicase, and nuclease activity. We synthesized and determined the three-dimensional solution structure of N-terminal domain comprising residues of Val$\^$501/ -_Phe$\^$508/ (Dna2$\^$pep/) using two-dimensional $^1$H-NMR and dynamical simulated annealing calculations. On the basis of a total of 44 experimental restraints including NOEs, $^3$J$\_$$\alpha$$\beta$/ and $^3$J$\_$$\alpha$$\beta$/ coupling constants, the solution structures of Dna2$\^$epe/ were calculated with the program CNS. The 23 lowest energy structures were selected out of 50 final simulated-annealing structures. The atomic RMSDs of the final 23 structures fur the individual residues were calculated with respect to the average structure. The mean RMSDs for the 23 structures were 0.042 nm for backbone atoms and 0.316 nm for all heavy atoms, respectively. The Ramachandran plot indicates that the $\Phi$, Ψ angles of the 23 final structures are properly distributed in energetically acceptable regions. Solution structure of Dna2$\^$pep/ showed a single unique turn spanning residues of Asn$\^$503/ Val$\^$506/.

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Netlist Partitioning Genetic Algorithm for 4-Layer Channel Routing (4-레이어 채널 배선을 위한 네트리스트 분할 유전자 알고리즘)

  • 송호정;송기용
    • Journal of the Institute of Convergence Signal Processing
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    • v.4 no.1
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    • pp.64-70
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    • 2003
  • Current growth of VLSI design depends critically on the research and development (If automatic layout tool. Automatic layout is composed of placement assigning a specific shape to a block and arranging the block on the layout surface and routing finding the interconnection of all the nets. Algorithms Performing placement and routing impact on Performance and area of VLSI design. Channel routing is a problem assigning each net to a track after global routing and minimizing the track that assigned each net. In this paper we propose a genetic algorithm searching solution space for the netlist partitioning problem for 4-layer channel routing. We compare the performance of proposed genetic algorithm(GA) for channel routing with that of simulated annealing(SA) algorithm by analyzing the results which are the solution of given problems. Consequently experimental results show that out proposed algorithm reduce area over the SA algorithm.

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Experimental Study on the Corrosion Behavior of Al Coatings Applied by Plasma Thermal Arc Spray under Simulated Environmental Conditions (모사 부식 환경에서 플라즈마 아크용사에 의한 Al 코팅의 부식특성에 관한 실험적 연구)

  • Jeong, Hwa-Rang
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.5
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    • pp.559-570
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    • 2023
  • The corrosion of structural steel used in the construction industry is increasing due to the industrialization where many aggressive ions released in the atmosphere. Therefore, in the present study Al coating was deposited by arc and plasma arc thermal spray process and compared their effectiveness in simulated weathering condition i.e. Society of Automotive Engineers(SAE) J2334 solution which mostly contain Cl- and CO32- ions. Different analytical techniques have been used to characterize the coating and draw the corrosion mechanism. The Al coating deposited by plasma arc thermal spray process exhibited uniform, dense and layer by layer deposition resulting higher bond adhesion values. The open circuit potential(OCP) of Al coating deposited this process is exhibited more electropositive values than arc thermal spray process in SAE J2334 solution with immersion periods. The total impedance of plasma arc thermal spray process exhibited higher than arc thermal spray process. The corrosion rate of the plasma arc thermal sprayed Al coating is reduced by 20% compared to arc thermal spray process after 23 days of immersion in SAE J2334 solution.

Improved Simulated-Annealing Technique for Sequence-Pair based Floorplan (Sequence-Pair 기반의 플로어플랜을 위한 개선된 Simulated-Annealing 기법)

  • Sung, Young-Tae;Hur, Sung-Woo
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.46 no.4
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    • pp.28-36
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    • 2009
  • Sequence-Pair(SP) model represents the topological relation between modules. In general, SP model based floorplanners search solutions using Simulated-Annealing(SA) algorithm. Several SA based floorplanning techniques using SP model have been published. To improve the performance of those techniques they tried to improve the speed for evaluation function for SP model, to find better scheduling methods and perturb functions for SA. In this paper we propose a two phase SA based algorithm. In the first phase, white space between modules is reduced by applying compaction technique to the floorplan obtained by an SP. From the compacted floorplan, the corresponding SP is determined. Solution space has been searched by changing the SP in the SA framework. When solutions converge to some threshold value, the first phase of the SA based search stops. Then using the typical SA based algorithm, ie, without using the compaction technique, the second phase of our algorithm continues to find optimal solutions. Experimental results with MCNC benchmark circuits show that how the proposed technique affects to the procedure for SA based floorplainning algorithm and that the results obtained by our technique is better than those obtained by existing SA-based algorithms.