• 반도체디스플레이기술학회지
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• 제9권2호
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• pp.103-109
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• 2010

An ink transfer is modeled and experimentally verified using roll-to-roll electric direct gravure printing process. The ink transfer model based on the physical mechanism for the maximum ink transfer rate is proposed, and experimented by the electric printing machine in FDRC for the relations of the maximum ink transfer rates to the printing pressure, the operating speed, the operating tension, the surface roughness of substrates, and the contact angle between substrate and silver ink. The free ink split coefficient and immobilized ink under the maximum ink transfer rate are calculated by the physical parameter in a printing process and contact angle between substrates and ink. Numerical simulations and experimental studies were carried out to verify performances of the proposed ink transfer model. Results showed that the proposed ink transfer model was effective for the prediction of the amount of transferred ink to the substrate in a direct gravure printing systems.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2007년도 춘계학술대회 논문집
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• pp.657-658
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• 2007

• 한국세라믹학회지
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• 제41권9호
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• pp.670-676
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• 2004

플라즈마 디스플레이(Plasma Display Panel)의 도전성 전극 성형에 필요한 잉크젯용 은 나노 졸을 합성하고자, 액상 환원법에 의해 고농도의 은 나노 졸의 입자크기 및 입도분포와 분산성을 제어하였다 이를 위하여 생성된 입자에 분산성을 부여하는 고분자 전해질의 착체형성 비율과 함께 은 나노 졸의 고농도화를 진행하였다. 합성된 졸은 XRD, 입도분포측정기, TEM을 사용하여 상분석 및 입자의 크기와 형상을 관찰하였다 그 결과 분산성이 우수하고, 약 10nm의 입자크기를 갖는 은 나노 졸인 것을 확인할 수 있었으며, 10-40wt% 범위의 고농도 은 나노 졸을 합성할 수 있었다.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
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• pp.913-918
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• 2005

It is expected that the inkjet technology offers prospect for reliable and low cost manufacturing of FPD (Flat Panel Display). This inkjet technology also offers a more simplified manufacturing process for various part of the FPD than conventional process. For example, recently the novel manufacturing processes of color filter (C/F) in LCD, or RGB patterning in OLED by inkjet printing method have been developed. This elaborates will be considered as the precious point of manufacturing process for the mass production of enlarged-display panel with a low price. On this point of view, we would like to review the status of inkjet technology in FPD, with some results on forming micro line by inkjet patterning of suspension type silver nano ink as below. We have studied the inkjet patterning of synthesized aqueous silver nano-sol on interface-controlled ITO glass substrate. Furthermore, we designed the conductive ink for direct inkjet patterning on bare ITO glass substrate. The first, the highly concentrated polymeric dispersant-assisted silver nano sol was prepared. The high concentration of batch-synthesized silver nano sol was possible to 40 wt%. At the same time the particle size of silver nanoparticles was below $10{\sim}20nm$. The second, the synthesized silver nano sol was inkjet - patterned on ITO glass substrate. The connectivity and width of fine line depended largely on the wettability of silver nano sol on ITO glass substrate, which was controlled by surfactant. The relationship was understood by wetting angle. The line of silver electrode as fine as $50{\sim}100\;{\mu}m$ was successfully formed on ITO glass substrate. The last, the direct inkjet-patternable silver nano sol on bare ITO glass substrate was designed also.

• 한국정밀공학회지
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• 제24권5호
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• pp.89-96
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• 2007

Inkjet printing has become one of the most attractive manufacturing techniques in industry. Especially inkjet printing technology will soon be part of the PCB (Printed Circuit Board) fabrication processes. Traditional printing on PCB includes screen printing and photolithography. These technologies involve high costs, time-consuming procedures and several process steps. However, by inkjet technology manufacturing time and production costs can be reduced, and procedures can be more efficient. PCB manufacturers therefore willingly accept this inkjet technology to the PCB industry, and are quickly shifting from conventional to inkjet printing. To produce the printed circuit board by the inkjet technology, it must be harmonized with conductive nano ink, printing process, system, and inkjet printhead. In this study, micro patterning of conductive line has been investigated using the piezoelectric printhead driven by a bipolar voltage signal is used to dispense 20-40 ${\mu}m$ diameter droplets and silver nano ink which consists of 1 to 50 nm silver particles that are homogeneously suspended in an organic carrier. To fabricate a conductive line used in PCB with high precision, a printed line width was calculated and compared with printing results.

• 대한기계학회논문집B
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• 제34권11호
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• pp.975-982
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• 2010

잉크젯으로 인쇄된 실버 도선의 레이저 소결에 관한 연구를 수행하였다. 요구적출(DOD) 방식의 잉크젯 프린터를 이용하여 서로 다른 두께의 유리와 PET 기판에 실버 나노 잉크를 이용한 미세 도선을 인쇄하였으며, 인쇄된 실버 도선에 집광된 레이저 빔을 조사하여 소결하였다. 레이저 강도와 조사 시간을 달리하여 소결된 실버 도선의 비저항을 측정하였으며, 오븐을 이용한 소결 처리 결과와 비교하였다. 단순화된 이론식으로부터 레이저 강도, 조사 시간, 표면 반사율 및 기판의 물성에 따른 온도 증가를 추산하였으며, 추산된 온도 증가와 레이저 소결에 의한 전기전도도 향상의 관계에 대하여 논의하였다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2011년도 제42회 하계학술대회
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• pp.1712-1713
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• 2011

Inkjet technology have many merits in plenty of industrial applications. However, deposited droplet has a very critical issue that is coffee ring effect, for the application to an industrial manufacturing process. To remove the coffee ring effect, the effect of thermal treatment conditions on shapes of inkjet printed silver patterns were investigated in various surface condition. The surface changes were characterized by the contact angle measurement. Droplets from a 50 ${\mu}m$ nozzle were printed on the substrate after optimizing the ejection of individual droplets. Ink with a high boiling point of main solvent results in coffee ring effect. This result implies that the dominant factor that determines the shape of droplet is the drying conditions of main solvent of silver nanoparticle colloidal ink. As a results, selecting a proper thermal treatment conditions is very crucial for better shapes of inkjet printed silver nanoparticle colloidal patterns.

• 한국재료학회지
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• 제17권9호
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• pp.453-457
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• 2007

Interest in use of ink-jet printing for pattern-on-demand fabrication of metal interconnects without complicated and wasteful etching process has been on rapid increase. However, ink-jet printing is a wet process and needs an additional thermal treatment such as an annealing process. Since a metal ink is a suspension containing metal nanoparticles and organic capping molecules to prevent aggregation of them, the microstructure of an ink-jet printed metal interconnect 'as dried' can be characterized as a stack of loosely packed nanoparticles. Therefore, during being treated thermally, an inkjet-printed interconnect is likely to evolve a characteristic microstructure, different from that of the conventionally vacuum-deposited metal films. Microstructure characteristics can significantly affect the corresponding electrical and mechanical properties. The characteristics of change in microstructure and electrical resistivity of inkjet-printed silver (Ag) films when annealed isothermally at a temperature between 170 and $240^{\circ}C$ were analyzed. The change in electrical resistivity was described using the first-order exponential decay kinetics. The corresponding activation energy of 0.44 eV was explained in terms of a thermally-activated mechanism, i.e., migration of point defects such as vacancy-oxygen pairs, rather than microstructure evolution such as grain growth or change in porosity.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.142-144
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• 2009

We demonstrated narrow and good aspect-ratio inkjet-printed silver lines with multi-time over-printing methods. By using this strategy, narrow silver lines were obtained with 200 nm thickness and their width and gap between printed lines of uniform narrow silver lines were 30 ${\mu}m$ and 17 ${\mu}m$, respectively. It also had good conductivity, sheet resistacne of 0.36 ${\Omega}/{\square}$ and specific resistance of $8{\mu}{\Omega}{\cdot}cm$. In current stress test, narrow silver line with 30 ${\mu}m$ width was able to a current flow up to 50 mA (2.1A/$cm^2$). Using surface treatment on poly-arylate substrate with $UVO_3$, we obtained clean-edge narrow line without any edge waviness.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.1600-1603
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• 2009

In this work, we have fabricated inverted staggered ZnO TFTs with 1-${\mu}m$ resolution channel length by micro contact printing (${\mu}$-CP) method. Patterning of micro scale source/drain electrodes without etching is successfully achieved by micro contact printing method by using silver ink and polydimethylsiloxane (PDMS) stamp. And the time dependent characteristics of the sheet resistance show that Ag inklayer could be used as source and drain electrodes for ZnO TFTs.