• 호남수학학술지
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• 제43권4호
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• pp.701-715
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• 2021

In this paper, we study almost complex Norden Silver manifolds and Kaehler-Norden Silver manifolds. We define adapted connections of first, second and third type to an almost complex Norden Silver manifold and establish the necessary and sufficient conditions for the integrability of almost complex Norden Silver structure. Moreover, we investigate that a complex Norden Silver map is a harmonic map between Kaehler-Norden Silver manifolds.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.505-509
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• 2013

A low temperature ($65^{\circ}C$) thermal deposition process was developed for depositing a silver coating on thermally sensitive polymeric substrates. This low temperature deposition was achieved by chemical reduction of a silver alkylcarbamate complex with latent reducing agent. The effects of acetol as a latent reducing agent for the silver 2-ethylhexylcarbamate (Ag-EHCB) complex and their blend solutions were investigated in terms of reducing mechanism, and the size and shape of silver nanoparticles (Ag-NPs) as a function of reduced temperature and time, and PVP stabilizer concentration were determined. Low temperature deposition was achieved by combining chemical reduction with thermal heating at $65^{\circ}C$. A range of polymer film, sheet and molding product was coated with silver at thicknesses of 100 nm. The effect of process parameters and heat treatment on the properties of silver coatings was investigated.

• 한국표면공학회지
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• 제29권2호
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• pp.140-145
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• 1996

Silver deposits formed on copper substrates by replacement reactions show poor adhesion, and a silver film plated on such a deposit does not adhere. Silver ion makes a highly stable complex with cyanide ion, so that in a silver cyanide solution, the activity of silver ion is very small. This is one of the reasons for the universal use of cyanide baths in the industrial silver plating. However, the consideration of the difference between the values of the stability constants for bath the silver-iodide complex and the copper-iodide complex suggest that the rate of replacement deposition of silver on the copper substrate in si]ver-potassium iodide solution, could be comparatively low. To confirm this, the rate of replacement deposition of silver in both a silver-potassium iodide solution ($AgNO_3$0.10 mol/L, KI 2.00 mol/L ) and a strike silver plating bath (AgCN 0.028 mol/L, KCN 1.15 mol/L ) was estimated from the current density corresponding to the point of intersection of the anodic and the cathodic polarization curves. These estimated values were almost the same, and it is suggested that the silver-potassium iodide solution is not only a cyanide free silver plating bath capable of employing a copper substrate but a silver plating bath which requires no strike plating.

• Bulletin of the Korean Chemical Society
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• 제31권9호
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• pp.2575-2580
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• 2010

We present a method for chemically reducing silver alkylcarbamate complex with hydrazine to synthesize silver nanocolloids in an organic solvent using polyvinylpyrrolidone (PVP) as the stabilizer. To determine the optimal conditions for preparing stable silver colloids of controlled size and shape, the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, hydrazine, and 2-propanol solvent concentrations in the reaction mixture were varied. The initial colloid has a mean particle diameter of 5-80 nm, and it exhibits an absorption band with various shapes in the UV region with a maximum near 420 nm. UV-vis spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the formation and growth process of the metallic silver nanocolloids.

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.2979-2984
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• 2014

Silver nanoparticles have been synthesized by liquid-phase and alcohol reduction methods. Silver-doped silica-complex nanoparticles were prepared using a sol-gel process. The formation, structure, morphology, and particle size of the nanoparticles have been studied using several techniques. Silver nanoparticles of size of 30-40 nm were formed successfully by alcohol reduction. TEM images show that both the concentration and the molecular weight of polyvinyl pyrrolidone (PVP) considerably affect the size of the emerging silver nanoparticles. The number of silver-doped silica-complex particles increased by a mercapto-group treatment that showed a narrower size distribution than that of silica treated with amino groups. The silver/polyester and silver-doped silica/polyester masterbatch chips showed excellent antibacterial activity against Staphylococcus aureus and Escherichia coli.

• 자원환경지질
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• 제20권2호
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• pp.97-106
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• 1987

The geology of the Bupyeong mine area is consisted of Precambrian Gyeonggi gneiss complex and Mesozoic igneous rocks; i.e., pyroclastic rocks, intrusive breccia, granite and felsic porphyries which were formed during a Jurassic to early Cretaceous resurgent caldera evolution. Granites are not observed on the surface and in the underground of the mine. Bupyeong silver deposits occur as stockworks of base metal sulfides- minor silver minerals-quartz - carbonate veinlets, hosted by pyroclastic rocks and intrusive breccia at the southwestern margin of the caldera. Silver occurs mainly as native silver, and other silver minerals, minor in quantity, are argentite, tetrahedrite-freibergite, pyrargyrite, polybasite, canfieldite and dyscrasite. The average grade of silver ore is about 180g/t Ag. Discrimination of silver ore from the country rocks depends largely on the chemical analyses of rock samples taken every two meters from tunnels, diamond-drilling cores and mining stopes, because silver minerals are hardly observed in the ore by crude eye, and silver orebodies do not properly coincide with the concentrated zone of base metal sulfides which were precipitated at the earlier stage than the stage of precipitation of native silver. General characteristics of the loci of the silver orebodies are as follows; (1) The host rocks of orebodies are pyroclastic rocks and intrusive breccia. (2) Many of the orebodies are distributed around Gyeonggi gneiss complex. Especially where the paleotopography of gneiss complex shows a gradual slope, the basal stratigraphic horizon of the pyroclastic rocks unconformably overlying the gneiss complex offered a favorable loci of high grade ore. (3) $N5^{\circ}W$ to $N15^{\circ}$ E-striking faults played an important role in the localization of the orebodies. (4) Conduits of intrusive breccia within the gneiss complex, through which the intrusive breccia intruded into the upper pyroclastic rocks, exist beneath most of the main orebodies. This suggests that the conduits of intrusive breccia served as channelways for the migration of ore fluids.

• Korean Membrane Journal
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• 제8권1호
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• pp.43-49
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• 2006

Complex membranes consisting of silver salt ($AgBF_4,\;AgCF_3SO_3,\;AgSbF_6,\;AgNO_3$) and poly(vinyl alcohol) (PVA) or crosslinked PVA (CPVA) were prepared and tested for the separation of propylene/propane mixtures. For the tested membranes, the complex membranes containing $AgBF_4$ exhibited the highest separation properties, i.e., approximately 20 GPU ($1 GPU=10^{-6}cm^3 (STP)/(cm^2 sec cmHg)$) and 100 of selectivity at 0.2 of silver mole fraction. The CPVA membranes containing silver salt always showed higher selectivity than PVA membranes, presenting silver ions coordinated to -CHO are more effective than those to -OH groups. The threshold silver concentration of CPVA membranes was lower than that of PVA membranes, which might be due to stronger interaction of silver ions with -CHO than that with -OH. The composition at which the selectivity is the highest did not significantly depend on the crosslinking, but did on the kind of silver salt.

• Macromolecular Research
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• 제14권2호
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• pp.199-204
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• 2006

Remarkably high and stable separation performance for olefin/paraffin mixtures was previously reported by facilitated olefin transport through ${\pi}$-complex membranes consisting of silver ions dissolved in poly(hexamethylenevinylene) (PHMV). In this study, the ${\pi}$-complex formation of $AgBF_4,\;AgClO_4\;and\;AgCF_{3}SO_3$ with PHMV and their ionic interactions were investigated. FT-Raman spectroscopy showed that the C=C stretching bands of PHMV shifted to a lower frequency upon incorporation of silver salt, but the degree of peak shift depended on the counter-anions of salt due to different complexation strengths. The symmetric stretching modes of anions indicated the presence of only free ions up to [C=C]:[Ag]=1:1, demonstrating the unusually high solubility of silver salt in PHMV. Above the solubility limit, the ion pairs and higher-order ionic aggregates started to form. The coordination number of silver ion for C=C of PHMV was in the order $AgBF_4$ > $AgClO_4$ > $AgCF_{3}SO_3$, but became similar at [C=C]:[Ag]=1:1. The different coordination number was interpreted in terms of the different transient crosslinks of silver cations in the complex, which may be related to both the interaction strength of the polymer/silver ion and the bulkiness of the counteranion.

• Macromolecular Research
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• 제15권2호
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• pp.167-172
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• 2007

The reduction behavior of silver ions to silver nanoparticles is an important topic in polymer/silver salt complex membranes to facilitate olefin transport, as this has a significant effect on the long-term performance stability of the membrane. In this study, the effects ofthe solvent type on the formation of silver nanoparticles, as well as the long-term membrane performance of a solid polymer/silver salt complex membrane were investigated. These effects were assessed for solid complexes of poly(N-vinyl pyrrolidone) $(PVP)/AgBF_4$, using either an ionic liquid (IL), acetonitrile (ACN) or water as the solvent for the membrane preparation. The membrane performance test showed that long-term stability was strongly dependent on the solvent type, which increased in the following order: IL > ACN >> water. The formation of silver nanoparticles was more favorable with the solvent type in the reverse order, as supported by UV-visible spectroscopy. The poor stability of the $(PVP)/AgBF_4$ membrane when water was used as the solvent might have been due to the small amount of water present in the silver-polymer complex membranes actively participating in the reduction reaction of the silver ions into silver nanoparticles. Conversely, the higher stability of the $(PVP)/AgBF_4$, membrane when an IL was used as the solvent was attributable to the cooperative coordination of silver ions with the IL, as well as with the polymer matrix, as confirmed by FTIR spectroscopy.

• ETRI Journal
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• 제26권3호
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• pp.252-256
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• 2004

We formed silver nanocrystallites by the thermal decomposition of a $Ag^{+1}$-oleate complex, which was prepared by a reaction with $AgNO_{3}$ and sodium oleate in a water solution. The resulting monodispersed silver nanocrystallites were produced by controlling the temperature (290$^{\circ}$C). Transmission electron microscopic (TEM) images of the particles showed a 2-dimensional assembly of the particles with a diameter of $9.5{\pm}0.7nm$, demonstrating the uniformity of these nanocrystallites. An energy-dispersive X-ray (EDX) spectrum and X-ray diffraction (XRD) peaks of the nanocrystallites showed the highly crystalline nature of the silver structure. We analyzed the decomposition of the $Ag^{+1}$-oleate complex using a Thermo Gravimetric Analyzer (TGA) and observed the crystallization process using XRD.