[KSCI] Korea Science Citation Index Service

http://dx.doi.org/10.5012/bkcs.2010.31.9.2575

Preparation of Silver Nanocolloids Using Silver Alkylcarbamate Complex in Organic Medium with PVP Stabilizer

Park, Hyung-Seok (Department of Nanobiomedical Science and WCU Research Center of Nanobiomedical Science)
Park, Heon-Su (Department of Nanobiomedical Science and WCU Research Center of Nanobiomedical Science)
Gong, Myoung-Seon (Department of Nanobiomedical Science and WCU Research Center of Nanobiomedical Science)

Publication Information

Bulletin of the Korean Chemical Society / v.31, no.9, 2010 , pp. 2575-2580 More about this Journal

Abstract

We present a method for chemically reducing silver alkylcarbamate complex with hydrazine to synthesize silver nanocolloids in an organic solvent using polyvinylpyrrolidone (PVP) as the stabilizer. To determine the optimal conditions for preparing stable silver colloids of controlled size and shape, the silver 2-ethylhexylcarbamate (Ag-EHCB) complex, PVP, hydrazine, and 2-propanol solvent concentrations in the reaction mixture were varied. The initial colloid has a mean particle diameter of 5-80 nm, and it exhibits an absorption band with various shapes in the UV region with a maximum near 420 nm. UV-vis spectroscopy, TEM, and X-ray diffraction techniques were used to investigate the formation and growth process of the metallic silver nanocolloids.

Keywords

Silver nanocolloid; Polyvinylpyrrolidone; Silver alkylcarbamate; Organic solvent; Hydrazine;

Citations & Related Records

Times Cited By KSCI : 7 (Citation Analysis)
Times Cited By Web Of Science : 3 (Related Records In Web of Science)
Times Cited By SCOPUS : 5

1	Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. Sens. Actuators B 2008, 133, 166. DOI
2	Hong, H. K.; Gong, M. S.; Park, C. K. Bull. Korean Chem. Soc. 2009, 30, 2669. DOI
3	Park, H. S.; Park, H. S.; Gong, M. S. Polymer(Korea) 2010, 34, 144.
4	Park, H. S.; Park, H. S.; Gong, M. S. Macromol. Res. 2010, 18, 897. DOI
5	Grodzicki, A.; Lakomska, I.; Piszczek, P.; Szymanska, I.; Szlyk, E. Coord. Chem. Rev. 2005, 249, 2232. DOI
6	Cavicchioli, M.; Varanda, L. C.; Massabni, A. C.; Melnikov, P. Mater. Lett. 2005, 59, 3585. DOI
7	Yang, N.; Aoki, K. Electrochim. Acta 2005, 50, 4868. DOI
8	Kashiwagi, Y.; Yamamoto, M.; Nakamoto, M. J. Colloid Interface Sci. 2006, 300, 169. DOI
9	Abe, K.; Hanada, T.; Yoshida, Y.; Tanigaki, N.; Takiguchi, H.; Nagasawa, H.; Nakamoto, M.; Yamaguchi, T.; Yase, K. Thin Solid Film 1998, 327, 524. DOI
10	Yamamoto, M.; Nakamoto, M. J. Mater. Chem. 2003, 13, 2064. DOI
11	Kashiwagi, Y.; Yamamoto, M.; Nakamoto, M. J. Colloid Interface Sci. 2006, 300, 169. DOI
12	Szymanska, I.; Piszczek, P.; Szczesny, R.; Szłyk, E. Polyhedron 2007, 26, 2440. DOI
13	Liu, X.; Luc, S.; Zhang, J.; Cao, W. Thermochimica Acta 2006, 440, 1. DOI
14	Hong, H. K.; Park, C. K.; Gong, M. S. Bull. Korean Chem. Soc. 2010, 31, 1252. DOI
15	Nie, S.; Emory, S. R. Science 1997, 275, 1102. DOI ScienceOn
16	Monti, O. L. A.; Fourkas, J. T.; Nesbitt, D. J. J. Phys. Chem. B 2004, 108, 1604. DOI
17	Singh, N.; Khanna, P. K. Mater. Chem. Phys. 2007, 104, 367. DOI
18	Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. Macromol. Res. 2008, 16, 308. DOI
19	Park, M. S.; Lim, T. H.; Jeon, Y. M.; Kim, J. G.; Joo, S. W.; Gong, M. S. J. Colloid Interface Sci. 2008, 321, 60. DOI
20	Steiner, E. C.; Gilbert, J. M. J. Am. Chem. Soc. 1965, 87, 382. DOI
21	Jeon, Y. M.; Cho, H. N.; Gong, M. S. Macromol. Res. 2009, 17, 2. DOI
22	Lim, T. H.; Jeon, Y. M.; Kim, Gong, M. S. Polymer (Korea) 2009, 33, 33.
23	Loginova, T. P.; Bronstein, L. M.; Mirzoeva, E. S.; Ezernitskaya, M. G.; Lokshin, B. V.; Genin, Y. V.; Valetsky, P. M. Polym. Sci. 1993, 35, 21.
24	Hirai, H.; Chawanya, H.; Toshima, N. Reactive Polym. 1985, 3, 127.
25	Fendler, J. H. Nanoparticles and Nanostructured Films. Preparation, Characterization and Applications; Wiley: Weinheim, VCH, 1998.
26	Hirai, H.; Nakao, Y.; Toshima, N. J. Macromol. Sci. Chem. 1979, A13, 727.
27	Mayer, A. B. R.; Mark, J. E. J. Polym. Sci. A: Polym. Chem. 1998, 35, 197. DOI
28	Mayer, A. B. R. Mater. Sci. Eng, C: Biomimetic Mater., Sensors and Systems 1998, 6, 155. DOI
29	Maillard, M.; Giorgio, S.; Pileni, M. P. Adv. Mater. 2002, 14, 1084. DOI
30	Nickel, U.; Castell, A.; Pöppl, K.; Shirtcliffe, N. Langmuir 2000, 16, 9087. DOI
31	Evanoff, D. D.; Chumanov, G., Jr. J. Phys. Chem. B 2004, 108, 13948. DOI
32	Van Hyning, D. L.; Zukoski, C. F. Langmuir 1998, 14, 7034. DOI
33	Toshima, N.; Harada, M.; Yonezawa, T.; Kushihashi, K.; Asakura, K. J. Phys. Chem. 1991, 95, 7448. DOI
34	Lee, P. C.; Miesel, D. J. Phys. Chem. 1982, 86, 3391. DOI
35	Creigton, J.; Blatchford, C.; Albrecht, M. J. Chem. Soc. Faraday Trans. 1979, 75, 790. DOI
36	Shirtcliffe, N.; Nickel, U.; Schneider, S. J. Colloid Interface Sci. 1999, 211, 122. DOI
37	Pastoriza-Santos, I.; Liz-Marzan, L. M. Langmuir 1999, 15, 948-951. DOI
38	Rodriguez-Gattorno, G.; Diaz, D.; Rendon, L.; Hernandez-Segura, G. O. J. Phys. Chem. B 2002, 106, 2482. DOI
39	Vasan, H. N.; Rao, C. N. R. J. Mater. Chem. 1995, 5, 1755. DOI
40	Ayyappan, S.; Srinivasan Gopalan, R.; Subbana, G. N.; Rao, C. N. R. J. Mater. Res. 1997, 12, 398. DOI

10	Hyung-Seok Park. (2011) Bulletin of the Korean Chemical Society Positively Charged Silver Nanoparticles Threaded on Carbon Nanotube for the Efficient Delivery of Negatively Charged Biomolecules / 32 (10) , 3581
2	Heon-Soo Park. (2012) Bulletin of the Korean Chemical Society Facile Preparation of Nanosilver-decorated MWNTs Using Silver Carbamate Complex and Their Polymer Composites / 33 (2) , 483
6	Wan-Gyu Kwak. (2015) Macromolecular Research Silver loading on poly(ethylene terephthalate) fabrics using silver carbamate via thermal reduction / 23 (6) , 509
1746-7748	Tae-Sung Kim. (2017) Textile Research Journal Investigation of the antimicrobial and wound healing properties of silver nanoparticle-loaded cotton prepared using silver carbamate / (1746-7748) , 004051751668863
1	Heon-Soo Park. (2011) Bulletin of the Korean Chemical Society Preparation and Stabilization of Ag Nanoparticles in 1-Amino-4-methylpiperazine / 32 (1) , 273
12	Kyoung-Young Kim. (2010) Bulletin of the Korean Chemical Society Preparation of Highly Stabilized Silver Nanopowders by the Thermal Reduction and Their Properties / 33 (12) , 3987
2	Kyung-A Kim. (2010) Bulletin of the Korean Chemical Society Facile Preparation of Silver Nanoparticles and Application to Silver Coating Using Latent Reductant from a Silver Carbamate Complex / 34 (2) , 505
8	Wan-Gyu Kwak. (2010) Fibers and polymers Surface Modification of Polyester Fibers by Thermal Reduction with Silver Carbamate Complexes / 17 (8) , 1146

1	Positively Charged Silver Nanoparticles Threaded on Carbon Nanotube for the Efficient Delivery of Negatively Charged Biomolecules / [Park, Hyung-Seok;Hwang, Ji-Young;Shin, Ueon-Sang;Kim, Hae-Won;Gong, Myoung-Seon;] / Bulletin of the Korean Chemical Society
2	Preparation and Stabilization of Ag Nanoparticles in 1-Amino-4-methylpiperazine / [Park, Heon-Soo;Shin, Ueon-Sang;Kim, Hae-Won;Gong, Myoung-Seon;] / Bulletin of the Korean Chemical Society
3	Facile Preparation of Nanosilver-decorated MWNTs Using Silver Carbamate Complex and Their Polymer Composites / [Park, Heon-Soo;Gong, Myoung-Seon;] / Bulletin of the Korean Chemical Society
4	Preparation of Highly Stabilized Silver Nanopowders by the Thermal Reduction and Their Properties / [Kim, Kyoung-Young;Gong, Myoung-Seon;Park, Chan-Kyo;] / Bulletin of the Korean Chemical Society
5	Facile Preparation of Silver Nanoparticles and Application to Silver Coating Using Latent Reductant from a Silver Carbamate Complex / [Kim, Kyung-A;Cha, Jae-Ryung;Gong, Myoung-Seon;] / Bulletin of the Korean Chemical Society

1	/ Bulletin of the Korean Chemical Society
2	/ Bulletin of the Korean Chemical Society