• 한국염색가공학회지
• /
• 제6권2호
• /
• pp.1-9
• /
• 1994

In order to study the effect of mordanting on silk fabrics treated with tannin, those fabrics were treated with Al, Cu, Cr, Fe, Sn by pre and post mordanting. It was studied about color change, weighting effect, dgree of photodegradation by pre and post mordanting. The results are as fallows ; 1. On the addition of mordants into mimosa and tannic acid solution, &{\lambda}_{max}& of the former was slightly blue-shifted, on the other hand, &{\lambda}_{max}& of the latter was obviously Red-shifted. 2. In case of Cu, Cr, Pre mordanting, weighting effect were appeared. Weighting effect of silk fabrics treated with Tannic acid increased higher than mimosa by mordanting. 3. In color change, Silk fabrics treated with Mimosa and Tannic acid generally changed to red direction and fabrics treated with tannic acid changed to yellow direction by pre and post mordanting. 4. In the photodegradation, the degree of photodegradation on mordanted fabrics increased. Its degree was slack in Cu, Cr, Post mordanting. On the other hand, Al, Fe, Sn were greate. Silk fabrics treated with Mimosa and Tannic acid got inhibiting effect on photodegradation.

• 한국잠사곤충학회지
• /
• 제34권1호
• /
• pp.49-56
• /
• 1992

반응개시제로 potassium persulfate를 사용하여 견섬유에 MAA를 처리하였을 때의 반응 mechanism을 구명하기 위하여, 열분석과 일련의 기구분석을 행하였으며, 이 중 열분석에 의해 얻어진 결과는 다음과 같다. Differential scanning calorimeter 관찰로부터는 metharcrylamide에 의한 가공견섬유는 견 fibroin과 methacrylamide polymer의 열분석에 의한 peak가 뚜렷하게 분리되어 나타났으며, 가공율이 증가함에 따라 두 peak가 모두 고온측으로 이동하는 것으로 나타났다. 가공견섬유의 흡습율은 가공율이 증가함에 따라 증가하였다.

• 한국잠사곤충학회지
• /
• 제36권1호
• /
• pp.53-57
• /
• 1994

견방사와 PET로 구성된 혼섬유 재료에 대해 여러가지 조건에서 알칼리 감량을 실시하여 감량율을 조사하고, 감량촉진제가 정련, 감량에 미치는 영향에 대해 검토한 결과를 요약하면 다음과 같다. 1) 감량촉진제와 농도 증가에 따라 견방사의 감량은 감소하여 강알칼리욕에서도 적당한 정도의 감량율을 얻을 수 있었다. 2) PET "A", "B"와 견방사로 된 혼섬유의 감량에서 견방사는 피브로인의 손상이 없는 정도의 적당한 감량이 얻어졌고, PET의 감량도 동시에 이루어 질 수 있었다. 3) PET "D", "E"와 견방사로 된 혼섬유의 감량에서, 견방사는 적당한 감량이 이루어 질 수 있었으나 PET의 감량율은 미미하였다. 4) 견방사와 PET로 된 교직물의 감량에 있어서, 견방사 분분은 전형적인 연감곡선 형태를 나타내 감량평형을 보였으나 PET는 처리시간의 경과에 따라 감량율이 계속해서 증가하였다. 보였으나 PET는 처리시간의 경과에 따라 감량율이 계속해서 증가하였다.

• 한국잠사곤충학회지
• /
• 제35권1호
• /
• pp.52-59
• /
• 1993

비누 정련 견사와 효소 정련 견사의 결정 구조는 정련 구조 중 처리온도의 차이에 의하여 효소 정련 견사의 결정성이 비누 견사의 결정성 보다 높다고 전보(김·남, 1992)에서 보고하였는데 이와같은 정련 견사의 결정성의 차이가 정련 견사를 열처리를 하였을 때 어떻게 변화하는지를 밝히기 위하여 두가지 방법으로 정련한 견사에 대하여 습열 처리와 동결 처리한 후 특성을 분석한 결과는 다음과 같다. 1. 정련 견사를 습열 처리한 경우 강력과 신도는 모두 저하되었으며 비누 정련 견사는 습열 처리온도의 상승과 함께 열 분해 온도도 고온측으로 이동하고 IR crystallinity도 증가하였으나 효소 정련 견사는 습열 처리에 의하여 열 분해 온도와 IR crystallinity의 큰 변화가 없었다. 이와 같은 결정 구조의 차이는 비누 정련 견사는 습열 처리로 재배향 결정화가 일어나 결정화도는 증가되었으나 효소 정련 견사는 습열 처리에 의한 재배향 결정화보다 습열 처리에 의하여 팽윤되어 수축하는 과정에서 배향성이 저하되기 때문에 결정성은 더 이상 증가되지 않은 것으로 추측된다. 2. 정련 견사를 동결 처리하였을 때 강력과 신도는 약간씩 감소하는 경향이었으나 열 분해 온도와 IR crystallinity는 비누 정련 견사와 효소 정련 견사 모두 큰 변화가 없었다.

• International Journal of Industrial Entomology and Biomaterials
• /
• 제12권2호
• /
• pp.87-93
• /
• 2006

Multiplication and spore production of three microsporidia viz., Nosema bombycis, Nosema sp. 1 and Nosema sp. 2 in fifth instar larval tissues of silkworm, Bombyx mori L. in two seasons with distinct temperature regimes were studied. Nosema sp. 2 produced significantly (P < 0.01) higher number of spores in various tissues. Among the tissues, spore production was highest in silk gland, followed by fat body and gut. Spore production was significantly (P < 0.01) higher in season-II (Average temperature $29.4{\pm}1.1^{\circ}C$). Maximum spore production was observed 25 days post inoculation (p. i.) in season-I (Average temperature $18.9{\pm}1.1^{\circ}C$), whereas in season-II, it was 14 days p. i. In season-I, spore production was low up to 21 days p. i., then increased sharply. In season-II, there was a steady increase in spore production. The results indicate that the microsporidian multiplication is tissue specific and extremely sensitive to temperature at which the host is reared. It also reveals that, silk gland, fat body and gut are the most appropriate tissues for microscopic identification of microsporidia in the larval stage.

• 한국염색가공학회지
• /
• 제2권3호
• /
• pp.36-42
• /
• 1990

The effect of urea and its derivatives, which are known as structure breakers of water, in the dyeing of silk with acid dyes was investigated. Without ureas the maximum dye uptake was observed at $60^{\circ}C$ when dyed with Milling Cyanine 5R, but in the presence of ureas the maximum dye uptake was decreased and its temperature also shifted to lower regin in the order of urea >N-methyl urea > N,N-dimethyl urea>tetramethyl urea. These tendencies were more marked in the dyeing of silk fiber with Orange II, a typical levelling type acid dye. These can be interpreted as the decrease in the hydropholic interaction between fiber molecules which results in the broadening of the inter micelie spacing. The increased partition coefficient of dye molecules in the bath by the action of ureas also contributes to dyeing results, and it can be seen from the spectral characteristics of dyes in aqueous urea solution.

• 한국염색가공학회지
• /
• 제7권4호
• /
• pp.16-24
• /
• 1995

Traditionally dyeing fabric with dyestuff extracted from Indigo was a popular method of obtaining blue color in the world before synthetic dyestuff was developed in the 1890's. As the Korean traditional process of dyeing extracted from Indigo, there are two kinds of dyeing process; The deposite dyeing of muddy Indigo and the leaf dyeing of Indigo plant. In order to study the properties of leaf dyeing of Indigo, the dyeing properties, color difference on cotton and silk fabrics under several dyeing conditions were investigated. In the dyeing of cotton and silk fabrics with leaf dyeing of Indigo, the dyeing affinity of silk was higher than that of cotton, the cotton and silk fabrics were dyed dark yellowish Green and dark Blue, respectively. the dye uptake increased with the increase of dyeing temperature and of the unmber of dyeing times. When cotton and silk fabrics dyed with leaf dyeing of Indigo at 6$0^{\circ}C$ for six number of times, the K/S value of dyed cotton and silk were calculated 1.286, 2.613 respectively.

• 한국염색가공학회지
• /
• 제5권2호
• /
• pp.99-108
• /
• 1993

In one dyeing system of silk/synthetic blend fabrics (polyester, nylon, acetate) with acid dyes/disperse dyes, dyeability and desorptibility of disperse dyes on silk fabric and transfer from dyed silk fabrics to synthetic fabrics by color difference were examined. When silk dyed with C.I. Disperse Red 19 and C.I. Disperse Red 60 at 10$0^{\circ}C$ for 60 minutes, color difference of dyed silk were $\Delta$E=56.72, $\Delta$E=47.65 for blank silk, respectively. The desorption rate of the dyed silks were measured in boiling bath with and without dye-free synthetic fibers. The desorption rate of dyed silk was effected by affinity of synthetic fabrics contained. When silk dyed with Red 19 and Red 60 was reduced at 10$0^{\circ}C$ for 60 minutes, the decolouration rates of dyed silk were 75% and 40%, respecdtively.

• 한국잠사곤충학회지
• /
• 제4권
• /
• pp.63-68
• /
• 1965

본 연구는 견사 lousiness와 유전관련성을 구명하여 도태가능성 여부를 조사하는 반면, 그 외 도태가능성이 불완전하였으므로 정련방법의 개량으로 인하여 lousiness의 개선을 기도하였던 바 얻어진 결론은 다음과 같았다. (A) lousiness의 유전관계문제 1. 교잡에 의한 lousiness 감소는 11.0%이었다. 2. lousiness의 유전은 불완전우성으로 유전한다. 3. lousiness를 발생하는 유전은 누적적으로 작용하고2종 이상의 유전자가 lousiness 발생에 작용하는 것으로 고찰된다. 4. 잠견의 실용형질과 lousiness와는 유전상관관계가 없다. 5. 다계량계통의 잠품종에서 반드시 lousiness의 발생이 많다고 할 수 없다. 6. 본 실험에서의 lousiness 검경은 생계의 exforiation 시험결과와 동일하였다. (B) 정련에 의한 lousiness 개선문제 1. 양 ion계 화학연화제 0.2% 용액을 95$^{\circ}C$ 하에서 30분간 처리할 때 lousiness 발생을 억제하면서 정련할 수 있었다. 2. 음 ion계 화학연화제는 생사정련에 불합격하였다. 3. 양 ion계 연화제를 상기조건하에 처리할 때 견사의 물리적성질에 변화가 없었다. 4. 석검정련은 lousiness 발생을 용이하게 시킨다.

• 한국염색가공학회지
• /
• 제12권3호
• /
• pp.199-206
• /
• 2000

Silk fabric was dyed using methanol extract of Chrysanthemum boreale at $60^\circ{C}$ for 40min. The K/S value of the silk fabric was highest in the premordanting method, while the amount of absorbed mordant was largest in the Cu-mordanting. The surface colors of the dyed fabric highly depended upon mordants or mordanting methods. For all cases, the value of the dyed fabric was dark. The chroma was high by using the Cr-mordant and the color difference was distinct by using the Fe-mordant. Cu-mordanted silk showed highest fastness to light. Dyed silk fabrics by mordanting method showed good antimicrobial activity ad deodorization property.