• Title/Summary/Keyword: Silicic

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EFFECTS OF DIETARY SILICIC ACID AND CADMIUM ON SHORT-TERM MINERAL BALANCES IN SHEEP

  • Bruce, L.B.
    • Asian-Australasian Journal of Animal Sciences
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    • v.2 no.4
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    • pp.579-582
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    • 1989
  • Previous experiments have shown that aqueous sodium silicate ingested in drinking water may modify the gastrointestinal uptake and(or) tissue retention of certain trace elements, including heavy metals. The present experiment tested, with a mineral balance trial using sheep, the hypothesis that dietary silicic acid could modify uptake, retention and(or) biological effects of dietary Cd. Twenty-four wethers were fed a fibrous diet of ground alfalfa hay and cottonseed hulls to which either 0 or 150 ppm Cd was added as $CdCl_2$ and 0, .5 or 1% silicic acid (as dry matter of the diet). Body weight, feed intake, excretion of urine (volume) and feces (weight), digestibility of dry and organic matter, retention of nitrogen, and packed cell volumes of blood were not affected by either Cd or silicic acid (P<.10). Cadmium decreased (P<.05) Ca retention and increased (P<.01) Mg retention. Silicic acid decreased (P<.05) K retention. Silicic acid failed (P<.01) to modify the retention of added dietary Cd. Body retention of K, Mn and Ni in response to silicic acid varied with Cd levels. If Cd is interfering with mineral retention, silicic acid may be effective in preventing this interference.

Mechanical Properties of Concrete Containing Silicic Wastes (규사성분의 산업폐기물을 혼입한 콘크리트의 역학적 특성)

  • 박제선;김태경;이주형;백민경
    • Proceedings of the Korea Concrete Institute Conference
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    • 1996.04a
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    • pp.192-197
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    • 1996
  • An experimental study was performed to examine the feasibility of using silicic wastes as construction materials for civil structures, and investigate its utility as a replacement for the favored nature resource to prevent the economic loss. In order to achieve this objective, mechnical properties of concrete containing silicic wastes is tested by investigating the strength development through parameters of water-binder ratios replacement 10 percent ratio with respect to curting conditions. The effect of stringth development is investigated for curing conditions when silicic wastes of 10 percent of cement-binder ratios is containde. Comparision on compressive strength of normal concrete and concrete containing silicic wastes at 28 day is conducted. The concrete with silicic wastes have larger compressive strength than of normal concrete by about 20 percent, when cured at 80 degree. The wastes concrete using silica sand shows increased strength, fracture toughness, elastic modulus and strain than the normal concrete, although the silicic wastes concrete could be able to satisfy the generally required strength for conventional concrete structures.

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DIETARY SILICA EFFECTS ON MINERAL METABOLISM IN LAMBS

  • Prabowo, Akhmad;Spears, J.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.5 no.2
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    • pp.279-283
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    • 1992
  • Eighteen wether lambs averaging 32 kg were used to determine the effects of dietary silica, added as silicic acid, on mineral metabolism. Lambs were fed 1200 g daily of a coastal Bermuda grass based diet supplemented with either 0, .5 or 1.5% silicic acid. A 7-d total collection of urine and feces was conducted after lambs had adjusted to the dietary treatments for 19 days. Urinary excretion of silica was higher (p<.01) in lambs fed added silicic acid. Ruminal soluble concentrations of manganese tended to be lower (p<.10) and apparent absorption and retention of manganese were lower (p<.05) in lambs supplemented with silicic acid compared to control lambs. Apparent absorption and retention of calcium were slightly lower (p<.10) in silicic acid fed lambs. No differences in urinary between lambs fed .5 and those given 1.5% silicic acid. Phosphorus, magnesium, iron, zinc and copper absorption and retention were not affected by treatment.

Preparation of Mullite Precursor Using Silicic Acid Extracted by Tetrahydrofuran from Sodium Silicate (규산나트륨으로부터 Tetrahydrofuran으로 추출된 규산을 이용한 Mullite 전구체 제조)

  • 노재성;홍성수;이범재;이병기;박은희;정홍호
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.915-920
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    • 1996
  • Fine mullite precursor was prepared by colloidal sol-gel processes. Aluminum isopropoxide $[Al(i-OC_3H_7)_3]$ as a starting material of $Al_2O_3$ and silicic acid extracted by THF from sodium silicate as a starting material of $SiO_2$ were used. Sodium silicate was first acidified by dilute sulfuric acid to form silicic acid. ; followed by extraction using THF, Mullite precursor was synthesized by sol-gel processes from aluminum isopropoxide and sillicic acid considering the degree of extraction of Si and the removal efficiency of Na. The impurity content of silicic acid extracted by THF was below 0.04% Synthetic mullite precursor consisted of $3Al_2O_3{\cdot}2SiO_2$ and showd spherical particles of $0.05{\mu}m$ diameter and below 0.462% of impurites. The mullite precursor was characterized by EDS, XRD, TG/DSC SEM, FT-IR spectroscopy ICP and TEM.

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Preparation of Nanoporous Silica Particles containing Various Pore Sizes from Silicic Acid by Spray Pyrolysis (분무열분해 공정에 의한 규산수용액으로부터 다양한 미세기공을 갖는 실리카 나노다공체 제조)

  • Kim, Sun Kyung;Lee, Chongmin;Chang, Hankwon;Jang, Hee Dong
    • Particle and aerosol research
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    • v.12 no.3
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    • pp.65-72
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    • 2016
  • Nanoporous $SiO_2$ particles containing different pore volume and size were prepared from silicic acid by a spray pyrolysis. The pore size, pore volume and particle size could be controlled with varying the precursor concentration, reaction temperature, and amount of organic templates such as Urea and poly ethylene glycol (PEG). The pore size distribution, pore volume and specific surface area of as-prepared particles were analyzed by BET and BJH methods, and the average particle sizes were measured by a laser diffraction method. The nanoporous $SiO_2$ particles ranged $0.6-0.9{\mu}m$ in diameter were successfully synthesized and the average particle size increased as the silicic acid concentration increased. The morphology of nanoporous $SiO_2$ particles was spherical and pores ranged 1 - 40 nm in diameter were measured in the particles. In case of Urea added into silicic acid, it showed no much difference in the morphology, pore size and pore volume at different Urea concentration. On the other hand, when PEG was added, it was clearly observed that pore diameter and pore volume of the particles surface increased with respect to PEG concentration.

Isolation of Pure $\alpha$-Linolenic Acid from Perilla Seed Oil (들깨유로부터 $\alpha$-Linolenic Acid의 순수분리)

  • 정보영;류수노;허한순
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.6
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    • pp.1028-1032
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    • 1997
  • Low-temperature crystallization method silver nitrate-impregnated silicic acid column chromatography were applied for the isolation of pure $\alpha$-linolenic acid(ALA) from perilla seed oil. ALA or 78% in purity(HALA; yield, 83%) was obtained from the fatty acid mixture(ALA, 65.7%) derived from perilla oil by the low-temperature crystallization method, when the mixture was frozen at -8$0^{\circ}C$ for 210min. ALA over 90% in purity(yield, 71%) was also obtained from HALA ethyl esters(ALA, 78%) by the silver nitrate-impregnated silicic acid column(100cm$\times$10cm, i.d.) chromatography. In addition, the silver nitrate-impregnated silicic acid could be semipermanently used for isolation of ALA, because $Ag^{+}$ ion was not dissociated from the stationary phase.

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Relations between Brown Planthopper (BPH) Resistance and Sucking Inhibitors of BPH in Rice

  • Kim, Sung-Eun;Kim, Young-Doo;Nam, Jeong-Kwon;Kim, Bo-Kyeoung;Ko, Jae-Kwon;Kim, Jung-Gon;Lee, Jin-Ho;Chun, Jae-Chul
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.6
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    • pp.513-518
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    • 2006
  • This study was conducted to investigate the relations between brown planthopper (BPH, Nilapavata lugens) resistance and specific organic acids (oxalic acid, silicic acid, and trans-aconitic acid) known as BPH sucking inhibitors on different rice varieties and/or lines. There were no specific relations between BPH resistance and the contents of oxalic and silicic acids in the rice plant tissues. However, the stronger the BPH resistance was occurred, the higher the content of trans-aconitic acid was contained in the rice plants. The relations between the injury rate of rice plant by BPH and the content of trans-aconitic acid in the rice plants were negatively correlated, which were -0.84 and -0.82 at 30 and 60 days after seeding, respectively. Therefore, the content of trans-aconitic acid in rice plant tissues might be utilized as an index for improving BPH resistance of rice varieties.

Effect of Catalysts on Preparation of Mullite Precursor Using Silicic Acid Extracted by THF from Sodium Silicate (규산 나트륨으로부터 THF에 의해 추출된 규산을 이용한 Mullite 전구체 제조시 촉매에 대한 영향)

  • 정흥호;박은희;김도수;정호승;노재성
    • Journal of the Korean Ceramic Society
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    • v.37 no.6
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    • pp.517-523
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    • 2000
  • Effect of catalysts, which was catalyzed by acid(HCl and HNO3) and base(NH4OH), on characteristics of the mullite powders prepared by sol-gel methdo wa sinvestigated by XRD, TGA, SEm AND BET. As a result, weight loss as a function of catalysts was in order of HCl=32.6%>HNO3=25.44%>Non=24.0%>NH4OH=22.5%. The mullite powder dried at 100$^{\circ}C$ appeared spherical shape in acid catalyst and different shape in base catalyst, but sintering powder at 1400$^{\circ}C$ appeared very fine particle of 0.05∼0.1$\mu\textrm{m}$ regardless of catalysts. In all cae, the pore quantity, which was capable to adsoprtion, was decreased with increasing temperature. In base catalyst, no change of special surface area in mullite appeared.

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Isolation and Identification of Free Phenolic Acids in Korean Ginseng (인삼의 유리 페놀성 분획중 phenolic acid의 순수분리 동정)

  • Kim, Man-Wook;Wee, Jae-Joon;Park, Jong-Dae
    • Korean Journal of Food Science and Technology
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    • v.19 no.5
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    • pp.392-396
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    • 1987
  • A method for isolation of some phenolic acids from Korean ginseng(Panax ginseng C.A.Meyer)was studied using silicic acid column chromatography. preparative thin layer chromatography and high performance liquid chromatography. Two phenolic compounds were isolated and identified as ferulic acid, mp $156-157^{\circ}C$ and vanillic acid. mp $154-156^{\circ}C$ by spectral data of Mass and NMR spectroscopy.

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Comparisons of inorganic amounts in paddy fields, rice straw and seed with varying severity of brown spot caused by Cochliobolus miyabeanus

  • Yeh, Wan-Hae;Park, Yang-Ho;Kim, I-Yeol;Kim, Yong-Ki;Shim, Hong-Sik
    • Proceedings of the Korean Society of Plant Pathology Conference
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    • 2003.10a
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    • pp.91.2-92
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    • 2003
  • In order to elucidate influence of nutritional status on rice brown spot caused by Cochliobolus miyabeanus, rice cultivation soils and rice straws were collected from paddy fields where ice brown spot occurred severely, moderately, a little and none respectively. Rice plant materials were analyzed to measure inorganic nutrients in rice straws and rice seeds. Analysis of chemical properties of rice paddy soil showed that EC and contents of available phosphate, cation and silicic acid in soil with severe infections were lower than those in healthy soil. This result suggests that amount and holding capacity of nutrient contents in soils collected from paddy field with infection of C. miyabeanus are relatively low compared to those in soils collected from healthy paddy field. Analysis of inorganic nutrients in rice straws showed that amount of macronutrient elements such as silicic acids, available phosphate and total nitrogen, and micronutrients such as copper, iron and zinc in rice straws from paddy field with infection were lower than those in healthy soil. Especially amount of iron and silicic acid were very low in rice straws from paddy field soils with infection Amount of inorganic nutrients such as iron and zinc in rice seeds was the same trend as those of rice straws. These results showed that one of major factors affecting rice brown spot was amount of nutrient contents in soil and rice straw.

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