• Title/Summary/Keyword: Silica-on-silicon

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Effect of Si on Corrosion of Fe-Cr and Fe-Cr-Ni Alloys in wet CO2 Gas

  • Nguyen, T.D.;Zhang, J.;Young, D.J.
    • Corrosion Science and Technology
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    • v.14 no.3
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    • pp.127-131
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    • 2015
  • Model alloys Fe-9Cr, Fe-20Cr and Fe-20Cr-20Ni (wt. %) with 0.1 and 0.2 % Si were exposed to $Ar-20CO_2-20H_2O$ gas at $818^{\circ}C$. The undoped alloys formed a thick iron-rich oxide scale. The additions of Si reduced scaling rates of Fe-9Cr to some extent but significantly suppressed the formation of iron oxide scales on Fe-20Cr and Fe-20Cr-20Ni. Carburisation also occurred in all undoped alloys, but not in Si-containing Fe-20Cr and Fe-20Cr-20Ni. Protection against carburisation was a result of the formation of an inner scale layer of silica.

Vibration analysis of silica nanoparticles-reinforced concrete beams considering agglomeration effects

  • Shokravi, Maryam
    • Computers and Concrete
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    • v.19 no.3
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    • pp.333-338
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    • 2017
  • In this paper, nonlinear vibration of embedded nanocomposite concrete is investigated based on Timoshenko beam model. The beam is reinforced by with agglomerated silicon dioxide (SiO2) nanoparticles. Mori-Tanaka model is used for considering agglomeration effects and calculating the equivalent characteristics of the structure. The surrounding foundation is simulated with Pasternak medium. Energy method and Hamilton's principal are used for deriving the motion equations. Differential quadrature method (DQM) is applied in order to obtain the frequency of structure. The effects of different parameters such as volume percent of SiO2 nanoparticles, nanoparticles agglomeration, elastic medium, boundary conditions and geometrical parameters of beam are shown on the frequency of system. Numerical results indicate that with increasing the SiO2 nanoparticles, the frequency of structure increases. In addition, considering agglomeration effects leads to decrease in frequency of system.

Fabrication and Characteristics of $Ta_2O_5/Al/SiO_2/p-Si$ MIS Solar Cells ($Ta_2O_5/Al/SiO_2/P-Si$ MIS형(形) 태양전지(太陽電池)의 제작(製作)과 특성(特性))

  • Noh, Kyung-Suk;Sohn, Yeon-Kyu
    • Solar Energy
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    • v.6 no.2
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    • pp.70-75
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    • 1986
  • The fabrication procedure and characteristics of $Ta_2O_5/Al/SiO_2/p-Si$ MIS solar cells forming a fine grating pattern of aluminum evaporated on to p-type silicon crystal are discribed. The proper temperature for oxide growing of these cells was found to be about $450^{\circ}C$ for 20 minutes with oxygen flow. The conversion efficiency increased about 3% after $750{\AA}$ thickness of tantalium silica film spin on anti-reflective coating. The best results showed that $V_{oc}=0.545V,\;J_{sc}=34mA$ and F.F = 0.65, which represent that the conversion efficiency is 12%.

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Effects of Initial Sol Parameters on Optical Transparency of $TiO_2$-$SiO_2$ Bainary Aerogels in TMOS-based System (TMOS를 사용한 $TiO_2$-$SiO_2$ 이성분계 Aerogel의 광학적 투명성에 초기 졸조건이 미치는 영향)

  • Lee, Jong-Hyeok;Choe, Su-Yeong;Kim, Chang-Eun;Kim, Gu-Dae
    • Korean Journal of Materials Research
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    • v.6 no.1
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    • pp.29-39
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    • 1996
  • silica의 precursor로 TMOS를 사용하여 autoclave 내에서 supersritical drying으로 투명한 TiO2-SiO2 이성분계 aerogle을 얻을 수 있었다. 반응성이 뛰어난 titanium alkoxide의 중축합반응을 억제할 수 있는 강한 산성 영역에서 투명한 Aerogel을 얻을 수 있었으며, 물을 직접 첨가하지 않고 silicon alkoxide의 축합반응의 부산물인 물을 이용하여 titanium alkoxide의 반응성을 제어했을 때 투명성이 더욱 증진되었다.

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Electrostatic Electrification Properties due to Square of Silicone Rubber (실리콘 고무의 면적 변화에 따른 정전기 대전 특성)

  • Lee, Sung-Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.9
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    • pp.732-737
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    • 2012
  • This study made a specimen (contact surface size: $45\;mm{\times}0.02\;mm{\times}45{\sim}55\;mm$) with silicon rubber for low voltage cable with 50 phr silica filler. The electrification voltage of electrostatics were measured for different sizes of contact surface with the applied voltage of 10kV and the environmental settings of temperature ($25{\sim}40^{\circ}C$) and humidity (40~80%). The following conclusions were made. The electrification voltage of electrostatics decreased as the humidity increased. The electrification voltage of electrostatics increased as the temperature increased. The larger the surface size, the higher the electrification voltage of electrostatics. The property of the material had more effect on the relaxation time than the humidity.

Synthesis of Lauric Acid Based Phase Change Materials Via Sol-gel Route (졸겔 법을 통한 라우르산 기반의 상변화 물질의 합성)

  • Ishak, Shafiq;Lee, Han Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.42-43
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    • 2020
  • Lauric acid (LA) which is also known as dodecanoic acid has been selected as the phase change material (PCM) owing to eco-friendly in nature. A systematic study has been conducted for encapsulation of LA (core) with silicon dioxide (SiO2) as shell material. Different core-shell ratio was chosen to microencapsulate the LA with 10 ml of tetraethyl orthosilicate (TEOS) as the precursor solution for the formation of SiO2. The synthesis of microencapsulated LA was carried out at 2.5 pH of precursor solution. The synthesized microencapsulated LA are characterized by Fourier transform infrared spectroscope (FT-IR) and X-Ray Diffraction (XRD) which confirmed the presence of SiO2 shell on the surface of LA.

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A Study on the Application of Aluminosilicate Sols in Shell Mold for Investment Casting ( I ) (정밀주조용 쉘 몰드에 알루미노실리케이트계 졸의 응용에 관한 연구 ( I ))

  • Kim, Jae-Won;Kim, Du-Hyeon;Seo, Seong-Mun;Jo, Chang-Yong;Choe, Seung-Ju;Kim, Jae-Cheol;Park, Yeong-Gyu
    • Korean Journal of Materials Research
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    • v.9 no.12
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    • pp.1188-1195
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    • 1999
  • The effect of aluminosilicate sol on the formation of mullite layer in zircon shell mold was investigated. Aluminosilicate sol was prepared by mixing of colloidal silica(NALCO(R) 1130) and an aqueous solution of aluminium nitrate at room temperature. The sol gelled at 50$^{\circ}C$ for 48 hrs. It was identified that the gel consists of aluminosilicate complexes and gibbsite. The coordination number of all aluminium ion bonded with silicon ion was four. Mullite phase formed by sintering above 1300$^{\circ}C$. XRD peak of mullite sharpened with increasing sintering temperature and the content of aluminium nitrate. Mullite phase displayed whisker-like 0.5~5${\mu}m $ particles. Separation between 1st and 3rd layers during sintering and the difference in thermal expansion coefficient between residual silica and mullite.

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A study on the structure of Si-O-C thin films with films size pore by ICPCVD (ICPCVD방법에 의한 나노기공을 갖는 Si-O-C 박막의 형성에 관한 연구)

  • Oh, Teresa
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.477-480
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    • 2002
  • Si-O-C(-H) thin film with a tow dielectric constant were deposited on a P-type Si(100) substrate by an inductively coupled plasma chemical vapor deposition (ICPCVD). Bis-trimethylsilymethane (BTMSM, H$_{9}$C$_3$-Si-CH$_2$-Si-C$_3$H$_{9}$) and oxygen gas were used as Precursor. Hybrid type Si-O-C(-H) thin films with organic material have been generated many voids after annealing. Consequently, the Si-O-C(-H) films can be made a low dielectric material by the effect of void. The surface characterization of Si-O-C(-H) thin films were performed by SEM(scanning electron microscope). The characteristic analysis of Si-O-C(-H) thin films were performed by X-ray photoelectron spectroscopy (XPS).

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Effect of the Addition of Si and Alkali Metal on the Viscosity and Molecular Behavior of Water Glass (Si와 알칼리 금속의 첨가에 따른 물유리의 점도 및 분자결합구조 특성변화)

  • Ryu, Young Bok;Lee, Man Sig
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.112-116
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    • 2018
  • In this study, the mixing characteristics of water glass and additives (Si, alkali metal), which are one of the main raw materials of silicate based binder used in the production of molds during casting process, were examined. Molecular structures of water glass, additives and mixtures were analyzed FT-IR and viscosity measurements and their correlation were compared. The addition of Si source to the water glass accelerated the Si networking in the material and increased the viscosity. When the alkali metal was added, the viscosity of the water glass decreased by suppressing the Si networking of the water glass. Viscosities of the water glass and lithium silicate (LS) mixtures increased when the content of LS was less than 20 wt% and gradually decreased when the content was more than 20 wt%. By adding KOH to the water glass, the viscosity could be lowered and it could be used effectively to mix with colloidal silica (CS) or potassium methyl siliconate (PMS).

Analysis of Laser-beam Thermal Effects In an Infrared Camera and Laser Common-path Optical System (적외선 카메라-레이저 공통광학계의 레이저빔 열 영향성 분석)

  • Kim, Sung-Jae
    • Korean Journal of Optics and Photonics
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    • v.28 no.4
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    • pp.153-157
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    • 2017
  • An infrared camera and laser common-path optical system is applied to DIRCM (directional infrared countermeasures), to increase boresighting accuracy and decrease weight. Thermal effects of a laser beam in a common-path optical system are analyzed and evaluated, to predict any degradation in image quality. A laser beam with high energy density is absorbed by and heats the optical components, and then the surface temperature of the optical components increases. The heated optical components of the common-path optical system decrease system transmittance, which can degrade image quality. For analysis, the assumed simulation condition is that the laser is incident for 10 seconds on the mirror (aluminum, silica glass, silicon) and lens (sapphire, zinc selenide, silicon, germanium) materials, and the surface temperature distribution of each material is calculated. The wavelength of the laser beam is $4{\mu}m$ and its output power is 3 W. According to the results of the calculations, the surface temperature of silica glass for the mirror material and sapphire for the lens material is higher than for other materials; the main reason for the temperature increase is the absorption coefficient and thermal conductivity of the material. Consequently, materials for the optical components with high thermal conductivity and low absorption coefficient can reduce the image-quality degradation due to laser-beam thermal effects in an infrared camera and laser common-path optical system.