• 한국가스학회지
• /
• 제8권3호
• /
• pp.43-51
• /
• 2004

GMS(generalized Maxwell Stefan) 모형을 이용하여 나노기공성 TPABr (Tetrapropylammoniumbromide) templating 실리카/알루미나 복합막에서 $CO_2$와 $N_2$의 투과 및 분리 특성을 해석하였다. 담체로 쓰이는 메조포러스 알루미나 지지체에서의 기체 투과는 누슨 확산 (Knudsen diffusion) 및 점성 확산 (viscous diffusion 혹은 Poiseuille flow)에 의존하였으며, 이러한 투과메커니즘은 DGM (dusty gas model)을 통하여 규명할 수 있었다. 본 연구에 사용한 복합막의 분리 특성을 결정 짖는 TPABr templating silica layer의 경우 강한 흡착 특성으로 인하여, 기공 확산보다는 표면 확산(surface diffusion)을 나타내었다. 따라서 GMS 모형을 통해 다성분계의 표면 확산 투과/분리 메커니즘을 성공적으로 해석할 수 있었다. 본 연구에서 사용된 복합무기막에서는 흡착량과 표면 확산 현상이 복합적으로 일어나기 때문에, 강흡착질인 $CO_2$와 비교적 약흡착질인 $N_2$ 혼합물 분리에 있어, $CO_2$의 pore-blocking 현상으로 인해 $CO_2$가 투과 농축되었다.

• Bulletin of the Korean Chemical Society
• /
• 제33권7호
• /
• pp.2369-2377
• /
• 2012

The gas-phase dehydration of glycerol to acrolein was carried out over silicotungstic acid ($H_4SiW_{12}O_{40}{\cdot}xH_2O$, HSiW) catalysts supported on $SiO_2$, ${\eta}-Al_2O_3$, and silica-aluminas with different Al contents. The HSiW catalysts supported on silica-aluminas showed higher glycerol conversions and acrolein yields during the initial 2 h at $315^{\circ}C$ than did $SiO_2$- and ${\eta}-Al_2O_3$-supported HSiW catalysts. Among the tested catalysts, HSiW/$Si_{0.9}Al_{0.1}O_x$ exhibited the highest space-time yield during the initial 2 h. The loaded HSiW species can change the acid types and suppress the formation of carbonaceous species on Al-rich silica-aluminas. The deactivated HSiW supported on silica-aluminas can be fully regenerated after calcination in air at $500^{\circ}C$. As long as the molar ratio between water and glycerol was in the range of 2-11, the acrolein selectivity increased significantly with increasing water content in the feed, while the surface carbon content decreased owing to the suppression of heavy compounds.

• Composites Research
• /
• 제18권6호
• /
• pp.40-47
• /
• 2005

본 연구에서는 세라믹 방탄재료개발을 위해 가장 경제적이고 방탄물성이 높은 알루미나를 기본으로 하여 압축-팽창률이 높은 실리카를 첨가하여 방탄물성이 우수한 세라믹 방탄재료를 개발하고자 하였다. 3가지 조성을 선정하였으며 각각 조성에 적합한 소결온도를 설정하였다. 물리/기계적 물성을 측정한 후 K215 자탄을 기폭시켜 성형 작약(HEAT)탄에 대한 방탄물성을 측정하였으며, 30mm 고체추진포에서 10.7의 L/D비를 갖는 팅스텐 긴 관통자를 비행시켜 운동에너지(KE)탄에 대한 방탄물성을 측정하여 분석하였다. 그 결과 $46\%\;Al_2O_3\;-\;51\%\;SiO_2$가 가장 높은 방탄물성을 나타내었으며 알루미나에 비해 매우 우수한 방탄재료로 평가되었다.

• 한국세라믹학회지
• /
• 제32권8호
• /
• pp.909-914
• /
• 1995

From alumina powder and TEOS, $\alpha$-Al2O3/SiO2 composite powder for reaction-sintered mullite was synthesized by heterogeneous coagulation and surface coating, and investigated the mullitization reaction and sintering behavor of these powders. In $\alpha$-Al2O3/SiO2 composite powder prepared by heterogeneous coagulation, each alumina particles were surrounded by silica particles of 50~60 nm in size. And the alumina particles in composite powder prepared by surface coating were coated by uniform silica layer with thickness of 50 nm. In both methods, mullitization reaction was completed at 1$650^{\circ}C$ for 3h, and specimen sintered above 145$0^{\circ}C$ was about 95% fo the theoretical relative density. Mullite grains formed from the reaction with composite powders showed spherical shape with a size of 1~2${\mu}{\textrm}{m}$.

• 대한화학회지
• /
• 제55권5호
• /
• pp.812-818
• /
• 2011

[ $V_{0.9}Sb_{0.1}O_x$ ]systems, bulk and deposited on different supports (five types of ${\gamma}$-aluminas, ${\alpha}$-alumina, silica-alumina, silica gel, magnesium oxide), have been tested in the oxidative dehydrogenation (ODH) of iso-butane. This statement is derived from the data obtained by a set of characterisation techniques(specific surface area measurements, X-ray diffraction, X-ray photoelectron spectroscopy, laser Raman spectroscopy, in situ differential scanning calorimetry and in situ diffuse reflectance-absorption infrared Fourier transform spectroscopy).

• 전기학회논문지
• /
• 제67권10호
• /
• pp.1330-1337
• /
• 2018

In this study, 40, 50, 60, and 70 wt% filler dispersed samples were prepared for the current GIS Spacer or environmentally friendly GIS. In the AC electrical breakdown, EMSC and EMAC decreased with increasing filler content, and EMSC showed better breakdown strength than EMAC. The mechanical properties such as tensile strength and flexural strength of EMSC and EMAC were also increased with increasing filler content. In addition, EMSC results in better mechanical properties than EMAC. The reason for this is considered to be one in which the influence of the interface is important.

• 대한치과기공학회지
• /
• 제32권4호
• /
• pp.297-305
• /
• 2010

Purpose: The purpose of this study was to observe the change of metal-mold reaction and surface roughness in titanium casting specimens for phosphate-silica alumina bonded investment with mold temperatures. Methods: The metal-phosphate silica alumina bonded mold interface reaction and surface roughness of titanium casting specimens according to mold temperatures were investigated. The Specimens were analysed by scanning electron microscopy and surface roughness tester. Results: The oxidation behavior indicated by the growth of oxide thickness. The titanium-oxide layer were consisted two layer of a porous external and a dense internal one. The reaction layer and surface roughness increased with increasing investment material temperature. Conclusion: In this work, The most suitable mold temperature in casting of pure titanium was $200^{\circ}C$.

• 한국산학기술학회:학술대회논문집
• /
• 한국산학기술학회 2008년도 추계학술발표논문집
• /
• pp.354-357
• /
• 2008

본 연구는 광전자촉매 시스템(PECS) 적용을 위하여 광촉매 금속판과 코팅비드를 제조하여 특성을 고찰하였다. 광촉매 물질의 회수가 용이하고, 실용화하기 위하여 티타늄 금속판을 $400^{\circ}C$에서 $700^{\circ}C$까지 $50^{\circ}C$에서 $100^{\circ}C$간격으로 토치를 사용하여 산화처리 하였으며, 비드의 경우 alumina, glass, silica gel beads에 TTIP([Ti$(OC_3H_7)_4$], Aldrich)을 전구체로 사용하여, 유동층 화학기상증착공정(Fluidized Bed Chemical Vapor Deposition, FB-CVD)으로 박막코팅을 하였다. 광촉매 금속판의 경우 산화처리 후 외관상태와 성분분석 시 최적조건은 $400^{\circ}C{\sim}500^{\circ}C$ 60분간 토치로 산화하였을 때였으며, 광촉매 코팅비드의 경우 silica gel beads가 본연의 다공구조를 나타내며 박막코팅이 되어, 상대적으로 alumina, glass beads에 비해 반응표면적이 크게 나타났다.

• 한국세라믹학회지
• /
• 제53권5호
• /
• pp.535-540
• /
• 2016

Effects of compositions and sintering conditions on glaze properties are shown in the diagram constructed by using the unity molecular formula (UMF) method in this study. Glossy characteristics of glaze were clearly differentiated by compositional area in the diagram and sintering process. As alumina and silica contents were increased, texture of the glaze became rough and opaque, akin to having been devitrified or underfired. The correlation between glossiness and surface roughness was found to be non-linear and inversely proportionate. Crystalline phases formed in the glaze were also influenced by the compositional area. Due to the high concentration of CaO, anorthite and wollastonite were formed depending on the compositions. Hardness was increased with an increase of alumina and silica concentrations in the glaze.

• Bulletin of the Korean Chemical Society
• /
• 제9권4호
• /
• pp.244-248
• /
• 1988

Multilayer adsorption isotherms of nitrogen on hexagonal boron nitride, ${\gamma}$-alumina, and silica-gel powders are determined at the liquid nitrogen temperature using a gravimetric adsorption apparatus. The volume (V) of the adsorbed gas are plotted against the statistical thickness(t) of the adsorbed layer, and the t-method area are calculated from the slope of these V-t plots to compare with the BET area. A number of universal adsorption isotherms and the Frenkel-Halsey-Hill equation are used one after another in calculating the statistical thickness. The appropriateness of the FHH equation as an universal adsorption isotherm is discussed finally.