• Title/Summary/Keyword: Silica($SiO_2$)

Search Result 668, Processing Time 0.025 seconds

Coating of ZnS phosphor by $SiO_2$ sol-gel

  • Lee, You-Hui;Han, Sang-Do;Han, Chi-Hwan;Yang, Hua;Singh, Ishwa
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2004.08a
    • /
    • pp.719-723
    • /
    • 2004
  • Silica coating on ZnS particles with buffer solution has been investigated. Diluted sodium silicate in water was used as the precursor material and it was diluted in water. Sodium silicate was added drop-wise in the continuously stirred suspension of ZnS in the buffer solution at room temperature. Smooth and evenly distributed silica coated ZnS phosphors has been obtained when the pH of buffer solution was 10, the concentration of sodium silicate in water was 20 wt%, firing temperature was 500 $^{\circ}C$.

  • PDF

Effects of Diluted Silica Slurry and Abrasives on the CMP Characteristics (실리카 슬러리의 희석과 연마제의 첨가가 CMP 특성에 미치는 영향)

  • 박창준;김상용;서용진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.15 no.10
    • /
    • pp.851-857
    • /
    • 2002
  • CMP(chemical mechanical polishing) process has been attracted as an essential technology of multi~level interconnection. However, the COO(cost of ownership) is very high, because of high consumable cost. Especially, among the consumables, slurry dominates more than 40%. So, we focused how to reduce the consumption of raw slurry In this paper, we presented the pH changes of diluted slurry and pH control as a function of KOH contents. Also, the removal rates of slurry with different dilution ratio were investigated. Finally, the CMP characteristics were discussed as a function of silica (SiO$_2$) abrasive contents.

Fabrication of Optical Fiber Preforms for Optical Communication by Centrifuge - Effects of Fine Particle Sizes and Traversing Injection Tube - (원심력을 이용한 광통신용 광섬유 모재제조 - 미세입자 크기 및 이동식 injection tube의 영향 -)

  • Min, Dong-Soo;Kim, Kyo-Seon;Lee, Kwang-Rae
    • Journal of Industrial Technology
    • /
    • v.12
    • /
    • pp.51-59
    • /
    • 1992
  • In this paper, the technique to fabricate the optical fiber preforms by centrifuge was investigated, using silica particles of different sizes. The injection tube was designed to traverse axially so that uniform coaling of tiny silica particles onto the substrate tube can be certified. The deposition efficiencies and deposition rates of $SiO_2$ particles were measured to elucidate the effects of process variables such as rotation speed of rotor, aqueous flow rate, suspension concentration, binder concentration and overflow weir diameter. This study shows dearly the merit of this technique by enhancing abruptly the deposition rates and deposition efficiencies, comparing to the conventional processes for optical fiber preforms.

  • PDF

Adsorption and separation behaviors of Y(III) and Sr(II) in acid solution by a porous silica based adsorbent

  • Wu, Hao;Kawamura, Taiga;Kim, Seong-Yun
    • Nuclear Engineering and Technology
    • /
    • v.53 no.10
    • /
    • pp.3352-3358
    • /
    • 2021
  • Aiming at selective adsorption and separation of Y(III) from the Y(III)-Sr(II) group in acid solution, a silica-based TODGA impregnated adsorbent [(TODGA+1-dodecanol)/SiO2-P-F600] has been prepared. Batch adsorption experiments were conducted under the effect of contact time, acid concentration, solution temperature, and adsorption capacity etc. Chromatography recovery of more than 90% Y(III) was successfully achieved under elution with 0.01 M DTPA solution in nitric acid adsorption system, and 0.1 M HCl solution in hydrochloride adsorption system, respectively.

Colored coating of SiO2-TiO2-MxOy(M = Cu, Co, Cr) thin films by the sol-gel process (졸-겔법에 의한 SiO2-TiO2-MxOy(M=Cu, CO, Cr)계 박막의 제조 및 색상에 관한 연구)

  • Kim, Sangmoon;Lim, Yongmu;Hwang, Kyuseog
    • Journal of Korean Ophthalmic Optics Society
    • /
    • v.3 no.1
    • /
    • pp.229-235
    • /
    • 1998
  • This paper reports the preparation and characterization of colored coatings of $SiO_2-TiO_2-M_xO_y$ (M = Co, Cr or Cu). Films of different compositions ranging from a molar content of transition metals of 5% to 20% have been prepared on soda-lime-silica slide glasses by the sol-gel process. The films have been characterized by a photospectroscopy. The color and reflectance of the films was expressed in Lab color chart and on spectra plot. 'L' as lightness and all reflectance decreased with increase of the content of transition metals. The coating of Co, Cu and Cr cotaining system showed light blue, green and lemon-yellowish color, respectively.

  • PDF

Element Dispersion and Wallrock Alteration of TA26 Seamount, Tonga Arc (통가열도 TA26 해저산의 모암변질과 원소분산)

  • Yoo, Bong-Chul;Choi, Hun-Soo;Koh, Sang-Mo
    • Economic and Environmental Geology
    • /
    • v.44 no.5
    • /
    • pp.359-372
    • /
    • 2011
  • TA26 seamount, which is located at south part of Tonga arc, occurs widely hydrothermal plume and is area that sampled hostrock, hydrothermal ore and hydrothermal alteration rock for this study. Hostrocks are basalt and basaltic andesite. Altered rocks by hydrothermal solution consists of plagioclase, pyroxene, pyrite, ilmenite, amorphous silica, barite, smectite, iron sulfates, Fe-Si sulfates and Fe silicates. Gains and losses of major, trace and rare earth elements during wallrock alteration suggest that $K_2O$(+0.04~+0.45 g), $SiO_2$(-6.52~+10.56 g), $H_2O$(-0.03~+6.04 g), $SO_4$(-0.46~+17.54 g), S(-0.46~+13.45 g), total S(-0.51~+16.93 g), Ba(-7.60~+185078.62 g), Sr(-36.18~+3033.08 g), Ag(+54.83 g), Au(+1467.49 g), As(-5.80~+1030.80 g), Cd(+249.78 g), Cu(-100.57~+1357.85 g), Pb(+4.91~+532.65 g), Sb(-0.32~+66.59 g), V(-113.58~+102.94 g) and Zn(-49.56~+14989.92 g) elements are enriched from hydrothermal solution. Therefore, gained(enriched) elements(($K_2O$, $H_2O$, $SO_4$, S, total S, Ba, Sr, Ag, Au, As, Cd, Cu, Pb, Sb, V, Zn) represent a potentially tools for exploration of sea-floor hydrothermal deposits from the Tonga arc.

Hydrophobic Polydimethylsiloxane Thin Films Prepared by Chemical Vapor Deposition: Application in Water Purification (화학적 증기 증착 방법을 통해 제조한 소수성 폴리디메틸실록산 박막: 수처리로의 응용)

  • Han, Sang Wook;Kim, Kwang-Dae;Kim, Ju Hwan;Uhm, Sunghyun;Kim, Young Dok
    • Applied Chemistry for Engineering
    • /
    • v.28 no.1
    • /
    • pp.1-7
    • /
    • 2017
  • Polydimethylsiloxane (PDMS) can be deposited on various substrates using chemical vapor deposition process, which results in the formation of PDMS thin films with thickness below 5 nm. PDMS layers can be evenly deposited on surfaces of nanoparticles composed of various chemical compositions such as $SiO_2$, $TiO_2$, ZnO, C, Ni, and NiO, and the PDMS-coated surface becomes completely hydrophobic. These hydrophobic layers are highly resistant towards degradation under acidic and basic environments and UV-exposures. Nanoparticles coated with PDMS can be used in various environmental applications: hydrophobic silica nanoparticles can selectively interact with oil from oil/water mixture, suppressing fast diffusion of spill-oil on water and allowing more facile physical separation of spill-oil from the water. Upon heat-treatments of PDMS-coated $TiO_2$ under vacuum conditions, $TiO_2$ surface becomes completely hydrophilic, accompanying formation oxygen vacancies responsible for visible-light absorption. The post-annealed $PDMS-TiO_2$ shows enhanced photocatalytic activity with respect to the bare $TiO_2$ for decomposition of organic dyes in water under visible light illumination. We show that the simple PDMS-coating process presented here can be useful in a variety of field of environmental science and technology.

Effect of Oxidation-reduction Pretreatment for the Hydrogenation of Caster Oil over Ni/SiO2 Catalyst (산화-환원 전처리에 따른 Ni/SiO2 촉매의 캐스터오일 수소화)

  • Choi, Yi Sun;Kim, Soo Young;Koh, Hyoung Lim
    • Applied Chemistry for Engineering
    • /
    • v.28 no.3
    • /
    • pp.326-331
    • /
    • 2017
  • Castor oil can be used as a useful raw material for chemical industries such as intermediates of surfactants through hydrogenation reaction. In this study, effects of the preparation method and pretreatment condition on the nickel catalyst for the hydrogenation of castor oil were investigated. The nickel catalyst was supported on the silica carrier by the precipitation method with different Ni contents, solution pH values, and precipitants. Repeated pretreatments of oxidation and reduction cycles were then carried out. The activity of the nickel catalyst was measured by comparing the iodine value of the castor oil. The dispersion of nickel on the catalyst was analyzed by X-ray diffraction (XRD), $N_2$ adsorption-desorption, and transmission electron microscopy (TEM). The activity of nickel catalyst was also compared by CO oxidation experiments. The redispersion of nickel occurred on the silica by repeated oxidation and reduction cycles, and this effect contributed to promoting the castor oil hydrogenation activity.

Identification of Secondary Metabolites from the Stems of Viburnum erosum (덜꿩나무(Viburnum erosum)줄기로부터 이차대사산물의 분리 및 동정)

  • In, Seo-Ji;Seo, Kyeong-Hwa;Song, Na-Young;Song, Myoung-Chong;Baek, Nam-In
    • Journal of Applied Biological Chemistry
    • /
    • v.57 no.2
    • /
    • pp.165-170
    • /
    • 2014
  • The stems of Viburnum erosum were extracted with 80% MeOH. The concentrated extract was partitioned with EtOAc, n-BuOH, and $H_2O$. From the EtOAc and n-BuOH fractions, four compounds were isolated through the repeated $SiO_2$, octadecyl silica gel, and Sephadex LH-20 column chromatographies. Based on NMR, MS, and IR spectroscopic data, the chemical structures were determined as betulinic aldehyde (1), koaburside (2), (6R,7E,9R)-9-hydroxymegastigma-4,7-dien-3-one-9-O-${\beta}$-D-glucopyranoside (3), and byzantionoside B (4). All the compounds were isolated for the first time from the stems of Viburnum erosum.

Strength Property of Ternary System Non-Cement Matrix according to the Curing Method (3성분계 무시멘트 경화체의 양생방법에 따른 강도특성)

  • Lee, Jin-Woo;Lee, Sang-Soo
    • The Journal of the Korea Contents Association
    • /
    • v.14 no.4
    • /
    • pp.389-396
    • /
    • 2014
  • This study was conducted as the basic research for the replacement of Blast Furnace Slag, Red Mud, Silica Fume, etc., with cement as a solution to the problems arising from the global warming caused by the generation of $CO_2$, and conducted the experimental review to examine the feasibility of matrix having properties identical to those of cement by using the Blast Furnace slag, Red mud, Silica fume, and alkali-activator. For this, by using the the inorganic binder, such as Blast Furnace Slag, Red Mud, Silica Fume, etc., and NaOH, $Na_2SiO_3$ and others as the cement substitute material, the strength characteristic according to the mixture time variation was performed in the tentative experiment. Based on the preceding experiment, this study performed the experiment to analyze the strength properties of hardener through the curing by air-dry temperature, curing by temperature in water, coating curing, and Korean paper curing. For the water curing at $80^{\circ}C$, the compressive strength and flexural strength were found to be the most excellent at the age of the 28th day, and furthermore, it was found that the non-cement hardener could be made, which is considered to affect the production of eco-friendly concrete.