• Title/Summary/Keyword: Side-chain effect

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Origin of Green Emission in Extremely Pure Oligofluorene Films: Effect of Molecular Packing

  • Kang, Ji-Hoon;Shin, Na-Yool;Jo Jung-Ho;Keivanidis Panagiotis E.;Laquai Frederic;Wegner Gerhard;Yoon, Do-Y.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.236-236
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    • 2006
  • Time-resolved photoluminescence spectroscopy measurements of oligofluorenes with various side chains were studied. With extremely pure oligofluorenes, two kinds of red-shifted green emission were observed which have different origins; aggregate formation and on-chain chemical defect. The green emission around 490 nm was largely dependent upon the intermolecular interaction of oliglfuorene molecules. Moreover, by using oligofluorene with high-order liquid crystalline phase, we observed that the green emission was strongly dependent upon the molecular packing in solid films.

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Novel Photoresponsive Polymer Materials Functionalized with Spirobenzopyran

  • Sumaru, Kimio;Takagi, Toshiyuki;Szilagyi, Andras;Sugiura, Shinji;Kanamori, Toshiyuki;Shinbo, Toshio
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.244-244
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    • 2006
  • We developed novel polymer materials composed of thermoresponsive pNIPAAm main chain and photo-resnposive side chains of spirobenzopyran, and analyzed the photoresponsive characteristrics of the aqueous solutions of these copolymers. Further, we prepared various photoresponsive hydrogels composed of the copolymer, and investigated the effect of light irradiation on their properties. As a result, the copolymer exhibited quite unique response to light irradiation and the change in temperature and pH. Especially the drastic photo-induced dehydration was observed in low pH conditions, and photo-induced micro-relief formation was demonstrated using the hydrogel layer composed of the polymer.

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Inhibitory Effect of Simazine on Photosynthetic Electron Transport Activity in Anabaena inequalis (Anabaena의 광합성 전자전달 활성에 미치는 Simazine의 억제효과)

  • 권벽동
    • Journal of Plant Biology
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    • v.31 no.3
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    • pp.217-226
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    • 1988
  • Effects of simazine [2-chloro-4,6-bis(methylamino)-s-triazine] on the photochemical reactions of isolaed spinach chloroplasts and crude thylakoids of Anabaena inequalis UTEX B-381 were compared. Simazine inhibited photosynthetic O2 evolution and increased the chlorophyll fluorescence in whole cells of Anabaena. The electron transfer from diphenylcarbazide to 2,6-dichlorophenolindophenol was inhibited by simazine treatment in spinach chloroplasts, but not in crude thylakoids of Anabaena. In spinach chloroplasts, the chlorophyll fluorescence was increased by simazine treatment in the presence of diphenylcarbazide and ferricyanide, but not in the presence of diphenylcarbazide and silicomolybdate. In crude thylakoids of Anabaena, simazine treatment did not increase the chlorophyll fluorescence in the presence of either diphenylcarbazide and silicomolybdate, or diphenylcarbazide and ferricyanide. There results suggest that the inhibitory site of simazine on photosynthetic electron transport chain of anabaena is different from that of spinach chloroplasts. And there may be a possiblity that the inhibition site of simazine in Anabaena lies on the donor side of photosystem II, before the site of electron donation by diphenylcarbazide.

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Liquid crystal alignment and EO performance of TN-LCD fabricated by transcription alignment method on polymer surface (양면 전사배향법을 이용한 TN-LCD의 액정배향과 전기광학특성)

  • Seo, Dae-Shik;Kim, Jin-Ho;Lee, Chang-Hoon
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1388-1390
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    • 1998
  • In this paper, we investigated the monodomain alignment of nematic liquid crystal(NLC) in the cell fabricated by transcription alignment method on polyimide(PI) surface with side chain. The LC alignment produced by the transcription alignment method is attributed to a memory effect of the NLC on PI surfaces. We observed that the pretilt angle of NLC is generated about $3.7^{\circ}$ with transcription alignment on PI surface. Also, we obtained the good electro-optical(EO) performance of twisted nematic(TN)-liquid crystal display(LCD) by transcription alignment method on PI surface.

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제품 다양화가 시장 점유율에 미치는 영향

  • Lee Ho Chang
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2003.05a
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    • pp.548-555
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    • 2003
  • Customer satisfaction level is usually measured in terms of price, quality, customization, after-sale-service, product variety etc. Each finn sets up a distinctive production/marketing strategy to gain competitive advantage by prioritizing the customer satisfaction measures. The market differentiation strategy directly results in supply chain performance such as lead time, inventory, customer fill rate and market share. Product proliferation desirable in customization sense often conflicts the economies of scale effect in production side. This paper focuses the relationship between product variety and market share. Specifically, we investigate how introduction of new product affects the current market share, i.e.,) formation of customer preference and provide some insight into the optimal range of product variety.

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Hormonal Effect and Cytokinin Autonomy in callus Culture of Phaseolus vulgaris L. (식물 Hormone의 영향과 Cytokinin Autonomy)

  • 김상구
    • Journal of Plant Biology
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    • v.25 no.4
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    • pp.161-168
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    • 1982
  • The activities of auxins and cytokinins have been examined in the growth of callus tissue derived from Phaseolus vulgaris L. cv. Damyang. The synthetic auxin, picloram was the most effective in promoting callus growth and the range of effective concentrations (0.1$\mu{M}$ to 32$\mu{M}$) was broad. 2, 4-D also enhanced callus growth at the optimal concentration of 3.2$\mu{M}$. NAA promoted callus growth at relatively higher concentrations than other auxins tested. IAA was less effective in supporting callus growth. Cytokinin bearing saturated side chain ($N^6$-isopentyladenine) was approximately 30 times more active than the corresponding unsaturated compound, $N^6$-($\D^2$-isopentenyl) adenine. The abilities of cytokinin-autonomous growth were also examined. Callus tissues previously grown on concentrations lower and/or higher than optimal concentrations of cytokinins were better habituated in the subsequent passage. It was suggested that the development of cytokinin autonomy may be related to dosage-concentrations of cytokinin in the previous passage.

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A Preliminary Analysis of Secreted Proteins from Bifidobacterium pseudocatanulatum BP1 by Two-Dimensional Gel Electrophoresis

  • Moon, Gi-Seong
    • Preventive Nutrition and Food Science
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    • v.13 no.4
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    • pp.366-369
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    • 2008
  • Proteins secreted from bifidobacteria are believed to play important roles in human intestines via interacting with different host cells. In this respect, proteins secreted from Bifidobacterium pseudocatanulatum BP1, which has been rarely studied, were analyzed by two-dimensional gel electrophoresis (2DE). Using this approach, approx-imately 21 protein spots on a 2DE gel were detected and 10 of these spots were identified by mass spectrometry. Five spots were identified as hypothetical proteins and the remaining 5 spots were identified as a putative iron-side-rophore binding lipoprotein, a short-chain dehydrogenase/reductase SDR, an exonuclease, cytochrome P450 hydroxylase, and a putative dehydrogenase. The identification of secreted putative iron-siderophore binding lipoprotein was highly interesting since it is an important protein that is involved in ferric iron uptake in pathogenic bacteria. This finding could accelerate studies on the probiotic effect of Bifidobacterium by explaining the competition between bifidobacteria and intestinal pathogens for ferric iron.

Effect of Long-term Corona-discharge on RTV Silicone Rubber (장기 코로나 처리에 따른 RTV 실리콘 절연재료의 특성변화)

  • Youn, Bok-Hee;Ahn, Jong-Sik;Huh, Chang-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.266-269
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    • 2001
  • This paper investigated the aging characteristic under long-term corona discharge on roan temperature vulcanized silicone rubber, which has been using as a protective coating material for solving the contaminant problem. The applied electrical field is 10kV/cm ac and corona discharge treatment was applied on RTV silicone rubber sheet for maximum 250 hours. With the duration of corona discharge. the diffusible low molecular weight species increased, which was determined the usage of n-hexane extraction method. In addition, the contaminant layer was formed on the treated surface, and then measured the contact angle. We investigated the relation of contact angle and diffusible low molecular weight species. It is found that scissor of main chain PDMS and side chains $(CH_3)$ and the generation of LMW species were occurred by a corona discharge. The improvement of hydrophobicity rate is thought due to the increase of diffusible LMW species.

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Synthesis of New 6-(4-Fluorophenyl)-5-(2-substituted pyrimidin-4-yl)imidazo[2,1-b] thiazole Derivatives and their Antiproliferative Activity against Melanoma Cell Line

  • Park, Jin-Hun;Oh, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2854-2860
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    • 2010
  • Synthesis of a new series of pyrimidinyl-imidazo[2,1-b]thiazole derivatives is described. Their antiproliferative activity against A375 human melanoma cell line was tested and the effect of substituents on the pyrimidinyl ring side chain was investigated. The biological results indicated that most of the newly synthesized compounds showed moderate activity against A375, compared with Sorafenib. Among all of these derivatives, the cyclic sulfamide derivatives IIIa, IIIb, and IIIe showed the most potent antiproliferative activity against A375 human melanoma cell line. The IC50 values of compounds IIIa,b were in nanomolar scale. In addition, compound IIIe ($IC_{50}=1.9\;{\mu}M$) also demonstrated more potent antiproliferative activity compared with Sorafenib ($IC_{50}=5.6\;{\mu}M$).

Liquid Crystal Alignment Using a In-situ Photoalignment Metho (In-situ 광배향법을 이용한 액정 배향)

  • 서대식;김형규;김재형;한은주
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.10
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    • pp.871-875
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    • 2000
  • Effects of liquid crystal (LC) alignment using a in-situ photoalignment method by polarized UV exposure on a polyimide (PI) surface with medium side chain were studied. The generated pretilt angle in nematic(N) LC using a in-situ photoalignment method was smaller than that of a conventional photoalignment method for short UV exposure time. Also, the pretilt angle of NLC using a in-situ photoalignment method increases with increasing UV exposure time on the PI surfaces. Finally, the pretilt angle of NLC can be improved by annealing treatment.

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