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고신율 금형주조용 Al-9wt%Si-Mg계 합금의 주조특성에 미치는 Fe, Mn함량의 영향 (Effect of Fe, Mn Content on the Castability in Al-9wt%Si-Mg System Alloys for High Elongation)

  • 김헌주;정창열
    • 한국주조공학회지
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    • 제33권6호
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    • pp.233-241
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    • 2013
  • Effect of Fe and Mn contents on the castability of Al-9wt%Si-xMg-yFe-zMn alloy has been studied. The alloy was composed of ${\alpha}$-Al phase, Al+eutectic Si phase, ${\beta}$-Al5FeSi compound and chinese script ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compound. ${\beta}$-$Al_5FeSi$ and ${\alpha}$-$Al_{15}(Mn,Fe)_3Si_2$ compounds assumed to effect the fluidity and shrinkage behaviors of the alloy during solidification due to the crystallization of ${\alpha}$-$Al_{15}(Fe,Mn)_3Si_2$ and ${\beta}$-$Al_5FeSi$ compounds above eutectic temperature. As Fe and Mn contents of Al-9wt%Si-0.3wt%Mg system alloy increased from 0.15wt% to 0.6wt% and from 0.3wt% to 0.7wt%, fluidity of the alloy decreased by 5.7% and 3.3%, respectively. And as Mg content of Al-9wt%Si-0.45wt%Fe-0.5wt%Mn system alloy increased from 0.3wt% to 0.4wt%, fluidity of the alloy decreased by 8.6%. When Fe content of the alloy increased from 0.15wt% to 0.6wt%, macro shrinkage ratio decreased from 6.1% to 4.1%, and micro shrinkage ratio increased from 0.04% to 0.24%. Similarly, Mn content of the alloy increased from 0.3wt% to 0.7wt%, macro shrinkage ratio decreased from 6.0% to 4.5% and micro shrinkage ratio increased from 0.12% to 0.18%. Judging from the castability of the alloy, Al-9wt%Si-0.3wt%Mg alloy with low content of Fe and Mn, 0.1wt% Fe and 0.3wt% Mn, is recommendable.

3C-SiC 버퍼층위에 증착된 M/NEMS용 다결정 AlN 박막의 특성 (Characteristics of polycrystalline AlN thin films deposited on 3C-SiC buffer layers for M/NEMS applications)

  • 정귀상;이태원
    • 센서학회지
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    • 제16권6호
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    • pp.462-466
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    • 2007
  • Aluminum nitride (AlN) thin films were deposited on Si substrates by using polycrystalline (poly) 3C-SiC buffer layers, in which the AlN film was grown by pulsed reactive magnetron sputtering. Characteristics of grown AlN films were investigated experimentally by means of FE-SEM, X-ray diffraction, and FT-IR, respectively. The columnar structure of AlN thin films was observed by FE-SEM. X-ray diffraction pattern proved that the grown AlN film on 3C-SiC layers had highly (002) orientation with low value of FWHM (${\Theta}=1.3^{\circ}$) in the rocking curve around (002) reflections. These results were shown that almost free residual stress existed in the grown AlN film on 3C-SiC buffer layers from the infrared absorbance spectrum. Therefore, the presented results showed that AlN thin films grown on 3C-SiC buffer layers can be used for various piezoelectric fields and M/NEMS applications.

Ti underlayer를 갖는 AI-1%Si 박막배선에서의 일렉트로마이그레이션 현상에 관한 연구 (A study on the electromigration phenomena in Al-1%Si thin film interconnections with Ti underlayers)

  • 유희영;김진영
    • 한국진공학회지
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    • 제8권1호
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    • pp.31-35
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    • 1999
  • 본 연구에서는 반도체 소자에서 일렉트로마이그레이션에 기인하는 Al-1%Si 박막배선의 길이 변화에 따른 수명시간 의존도를 조사하였다. 사용된 Al-1%Si 박막배선은 표준 사진식각 공정(standard photolithography process)을 사용하여 제작된 직선형 패턴이다. 직선형 패턴은 100에서 1600 $mu extrm{m}$ 범위의 길이 변화를 갖도록 제작하였다. Ti underlayer가 없는 시편보다 Ti underlayer가 있는 시편에서 Al-1%Si 박막배선의 수명시간이 더 길게 나타났다. Ti underlayer를 갖는 시편에서 electromigration에 대한 저항성을 향상시키는 것으로 사료되어진다. Al-1%Si 박막배선의 길이에 의존하는 수명시간은 800$\mu\textrm{m}$ 이하에서 포화되는 경향을 나타내었다.

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미세 Si 입자를 고려한 Al-1%Si 본딩 와이어의 신선공정해석 (FE-simulation of Drawing Process for Al-1%Si Bonding Wire Considering Fine Si Particle)

  • 고대철;황원호;이상곤;김병민
    • 소성∙가공
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    • 제15권6호
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    • pp.421-427
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    • 2006
  • Drawing process of Al-1%Si bonding wire considering fine Si particle is analyzed in this study using FE-simulation. Al-1%Si boding wire requires electric conductivity because Al-1%Si bonding wire is used for interconnection in semiconductor device. About 1% of Si is added to Al wire for dispersion-strengthening. Distribution and shape of fine Si particle have strongly influence on the wire drawing process. In this study, therefore, the finite-element model based on the observation of wire by continuous casting is used to analyze the effect of various parameters, such as the reduction in area, the semi-die angle, the aspect ratio, the inter-particle spacing and orientation angle of the fine Si particle on wire drawing processes. The effect of each parameter on the wire drawing process is investigated from the aspect of ductility and defects of wire. From the results of the analysis, it is possible to obtain the important basic data which can be guaranteed in the fracture prevention of Al-1 %Si wire.

Effects of Sr Additions on the Interfacial Reaction Layers Formed between Liquid Al-Si-Cu Alloy and Cast Iron

  • Kyoung-Min Min;Je-Sik Shin;Jeong-Min Kim
    • 한국재료학회지
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    • 제33권9호
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    • pp.353-359
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    • 2023
  • This study investigated the growth behavior and characteristics of compounds formed at the interface between a liquid Al-Si-Cu alloy and solid cast iron. Through microstructural analyses, it was observed that various AlFe and AlFeSi phases are formed at the interface, and the relative proportion of each phase changes when small amounts of strontium are added to the Al alloy. The results of the microstructural analysis indicate that the primary phases of the interfacial compounds in the Al-Si-Cu base alloy are Al8Fe2Si and Al4.5FeSi. However, in the Sr-added alloys, significant amounts of binary AlFe intermetallic compounds such as Al5Fe2 and Al13Fe4 formed, in addition to the AlFeSi phases. The inclusion of Sr has a slight diminishing effect on the rate at which the interfacial compounds layer thickens during the time the liquid Al alloy is in contact with the cast iron. The study also discusses the nano-indentation hardness and micro-hardness of the interfacial phases.

금속-치환 $AlPO_4-5$ 분자체에서 가교 $T_1-OH-T_2(T_1$=Al,B 그리고 $T_2$= P, Si)에 대한 성질 : MNDO (Properties of $T_1-OH-T_2$(T1 = Al, B and T2 = P, Si) Bridges on Metal-Substituted $AlPO_4-5$ Molecular Sieves : MNDO Calculations)

  • 손만식;백우현
    • 대한화학회지
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    • 제38권1호
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    • pp.1-7
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    • 1994
  • 알루미노인산염 족($AlPO_4-5$, BAPO-5, 그리고 SAPO-5)분자체의 구조 골격인 가교 $$T_1-OH-T_2$(T_1$ = Al, B 그리고 $T_2=$ P, Si) 안정성 및 가교 OH 그룹 이온성을 연구하기 위하여 반경험적 MNDO 계산 방법으로 연구하였다. 이러한 계산은 Al-OH-P, B-OH-P 그리고 Al-OH-Si덩어리 모델로써 실행하였다. Al-OH-P가교 모델에서 Al대신에 B원자를 치환할 때 B-OH-Si가교에서는 변형이 우선적으로 일어났으나, P 대신에 Si원자를 치환한 Al-OH-Si가교에서는 회전이 우선적으로 일어났다. 이러한 모델 덩어리에서 OH그룹 이온성 및 가교 안정성은 B-OH-P < Al-OH-P < Al-OH-Si 가교 순서로 증가하였다.

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제조방법에 따른 Al2O3-SiCw 복합체의 특성 (Properties of Al2O3-SiCw Composites Fabricated by Three Preparation Methods)

  • 이대엽;윤당혁
    • 한국세라믹학회지
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    • 제51권5호
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    • pp.392-398
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    • 2014
  • $Al_2O_3$-SiC composites reinforced with SiC whisker ($SiC_w$) were fabricated using three different methods. In the first, $Al_2O_3-SiC_w$ starting materials were used. In the second, $Al_2O_3-SiC_w$-SiC particles ($SiC_p$) were used, which was intended to enhance the mechanical properties by $SiC_p$ reinforcement. In the third method, reaction-sintering was used with mullite-Al-C-$SiC_w$ starting materials. After hot-pressing at $1750^{\circ}C$ and 30 MPa for 1 h, the composites fabricated using $Al_2O_3-SiC_w$ and $Al_2O_3-SiC_w-SiC_p$ showed strong mechanical properties, by which the effects of reinforcement by $SiC_w$ and $SiC_p$ were confirmed. On the other hand, the mechanical properties of the composite fabricated by reaction-sintering were found to be inferior to those of the other $Al_2O_3$-SiC composites owing to its relatively lower density and the presence of ${\gamma}-Al_2O_3$ and ${\gamma}-Al_{2.67}O_4$. The greatest hardness and $K_{1C}$ were 20.37 GPa for the composite fabricated using $Al_2O_3-SiC_w$, and $4.9MPa{\cdot}m^{1/2}$ using $Al_2O_3-SiC_w-SiC_p$, respectively, which were much improved over those from the monolithic $Al_2O_3$.

금형주조한 Al-Si 과공정합금의 초정 Si 입자거동에 따른 기계적 성질 변화 (Effect of Primary Si on Mechanical Properties in Hypereutectic Al-Si Alloy Produced by Gravity Die Casting)

  • 김억수
    • 소성∙가공
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    • 제13권7호
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    • pp.608-613
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    • 2004
  • Mechanical properties of hypereutectic Al-Si alloy are influenced by the size and distribution of primary Si. To investigate the effects of P addition and holding time, hypereutectic Al-Si alloys with various amount of P content were produced in the lab. Then, the size and distribution of primary Si were examined respectively. Mechanical properties of hardness, tensile strength and wear resistance were analyzed in conjunction with the microstructural variations in alloys.

Al/SiCp 복합재료에서 보강재 표면의 금속 피복층이 젖음성과 계면 강도에 미치는 영향 (Effects of Metal Coating on SiCp on Wettability and Interfacial Strength of Al/SiCp Composites)

  • 이경구;이도재
    • 한국주조공학회지
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    • 제15권4호
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    • pp.360-367
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    • 1995
  • Effects of metal coating treatment on SiC particle on wetting behavior and interfacial strength were studied. Experimental variables are included types of coated metallic films such as Cu and Ni-P, and temperatures of heat-treatment under vacuum. The experimental results concerning wetting phenomena of liquid Al on SiC, showed that coating treatment of metallic film on SiC particles remarkably improves the wetting behavior of liquid Al on SiC, especially in the case of Ni-P coating. The interfacial strength of Al/SiC composites made of coated SiC plate was higher than that of the composite with non-coated SiC plate although the coating treatment was not perfect.

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불순 Fe를 함유한 A356 주조합금에서 미세조직 형성에 관한 Mn과 Cr의 효과 (The Effects of Mn and Cr Additions on the Microstructure of A356 Alloys Containing Impure Fe)

  • 한상원
    • 한국주조공학회지
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    • 제25권3호
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    • pp.128-133
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    • 2005
  • The effects of Mn and Cr on the crystallization behaviors of Fe-bearing intennetallics in A356 alloy were studied. Coarse and acicular ${\beta}-Al_{5}$FeSi phase in A356-0.20wt.%Fe alloy was modified into small ${\alpha}$-Al(Fe,Mn)Si and ${\alpha}$-Al(Fe,Cr)Si phases in response to Mn and Cr addition, respectively. Increasing of Mn addition amount elevates the crystallizing temperature of ${\alpha}$-Al(Fe,Mn)Si and the Mn/Fe ratio in the ${\alpha}$-Al(Fe,Mn)Si. Cr is more effective to modify ${\beta}-Al_{5}$FeSi in comparison with Mn. ${\alpha}$-Al(Fe,Mn)Si phase had BCC/SC dual structure.